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| 研究生： |
陳秉彥 Ping-Yen Chen |
|---|---|
| 論文名稱： |
含有巨大側基之新型聚苯并咪唑之合成與特性及在高溫型質子交換膜燃料電池之應用 Synthesis and Properties of Novel Polybenzimidazoles Containing Bulky Side Groups for High Temperature Proton Exchange Membrane Fuel Cell Applications |
| 指導教授： |
陳志堅
Jyh-Chien Chen |
| 口試委員: |
陳燿騰
Yaw-Terng Chern 劉貴生 none 蕭勝輝 Sheng-Huei Hsiao |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
| 論文出版年： | 2014 |
| 畢業學年度： | 102 |
| 語文別： | 中文 |
| 論文頁數： | 77 |
| 中文關鍵詞： | 聚苯并咪唑 、質子交換膜 、質子傳導率 |
| 外文關鍵詞： | polybenzimidazole, proton exchange membrane, proton conductivity |
| 相關次數： | 點閱：260 下載：8 |
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本研究合成三種含有巨大側基之新型四胺單體 (7)、(10)及(13)。聚合成新型聚苯并咪唑P1~P3。P1~P3皆已成功以溶液澆鑄法塗佈成可撓性之薄膜。擁有良好的熱穩定性。呈現良好的氧化穩定性。
Three novel tetraamines containing bulky side groups,(7), (10) and(13) were successfully synthesized. Novel polybenzimidazoles P1~P3 were polymerized. The structures of P1~P3 were characterized by 1H-NMR and FTIR. P1~P3 could be prepared as transparent, flexible, and tough membranes by solution casting. P1~P3 exhibited outstanding thermal stabilities and excellent oxidative stability.
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