本論文主要討論鉑嵌入金屬有機骨架（MOF）的製備和性質，以評估析氫反應（HER）之效率，並將該催化劑應用於能源開發。氫燃料電池是具潛力的乾淨能源發電系統，但由於觸媒白金昂貴且稀有，造成實際應用的瓶頸。因此使用少量鉑的催化劑去降低成本是目前的方向。
沸石咪唑酯骨架-8（ZIF-8）是一種金屬有機骨架材料，能夠快速生產具低成本。它可以在高容量結構中嵌入各種活性化合物，並且具有高比表面積和高孔隙率，可以提供活性反應點是一種良好的穩定劑，嵌入觸媒後可以促進析氫反應活性。
在析氫反應中，鉑是最好的觸媒。然而，由於其稀有性和高成本，我們只能選擇替代電催化劑或減少使用的鉑使用量。在本論文中，我們選擇後者製備一種高活性複合材料，用於析氫反應的電催化劑。
本工作中使用的三種方法是直接混合方法，一步合成法和雙溶劑法。因此將鉑奈米粒子嵌入MOF（Pt @ ZIF-8）中。評估每種複合材料的析氫反應效率，過電位和塔菲爾斜率。其中雙溶劑法的Pt@ZIF-8的析氫反應催化效果與商業催化劑Pt/C相當。顯著的減少白金使用量達到降低成本，使得乾淨能源發展更容易去實踐。

This thesis mainly discusses the preparation and properties of platinum to embed in metal-organic framework (MOF) to evaluate the efficiency of hydrogen evolution reaction (HER), and applies this catalyst to energy development. Fuel cell is a potential clean energy generation system, but catalyst platinum is expensive and rare, and makes the actual application bottleneck. Thus using a small amount of platinum can reduce the cost in the current direction.
Zeolitic Imidazolate Framework-8 (ZIF-8) is one of the metal organic framework materials which are easy to obtain at low cost and can be rapidly produced. It can embed various active compounds in a high-capacity structure, and has a large specific surface area and high porosity. It has high degree of crystallinity and can provide active reaction points. It is a good stabilizer and can promote hydrogen evolution reaction activity, if catalyst was embedded.
In the hydrogen evolution reaction, platinum is the best catalyst. However, due to its rarity and high cost, we can only choose alternative electrocatalysts or reduce the amount of platinum used. In this thesis we chose the latter to make a highly active composite material for electrocatalysts of hydrogen evolution reaction.
The three methods used in this work are the direct mixing method, and the one-step synthesis method and the double solvent method. Thus platinum nanoparticles were embedded in the MOF (Pt@ZIF-8). Efficiency of hydrogen evolution reaction, overpotential and Tafel slope of each composite were evaluated. The hydrogen evolution reaction catalytic effect of Pt@ZIF-8 from the double solvent method was equivalent to the commercial catalyst Pt/C. The use of small amount of platinum significantly reduces costs, which make the clean energy development easier in practice.

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