研究生: |
湯偉立 Wei-Li Tang |
---|---|
論文名稱: |
熱真空蒸鍍法製備氯化硼亞酞菁薄膜及其太陽能電池應用之研究 The study of thermal evaporated SubPc thin films and SubPc/C60 bilayer solar cell |
指導教授: |
劉進興
Chin-Hsin J. Liu |
口試委員: |
陳貴賢
Kuei-Hsien Chen 何國川 Kuo-Chuan Ho 戴龑 Yian Tai |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2008 |
畢業學年度: | 96 |
語文別: | 中文 |
論文頁數: | 164 |
中文關鍵詞: | 太陽能電池 、亞酞菁 |
外文關鍵詞: | Subphthalocyanine, solar cell |
相關次數: | 點閱:512 下載:2 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究論文係以利用熱真空蒸鍍法,製備不同厚度與表面型態之氯化硼亞酞菁(SubPc-BCl)薄膜。並以UV/Vis、SEM、AFM、XRD觀察其吸收光譜與表面晶體型態之改變。再將薄膜製備結構為Glass/ITO/PEDOT-PSS/SubPc-BCl/C60/BCP/Al之太陽能元件,並加以研究不同成長模式之SubPc-BCl薄膜對太陽能表現行為之影響。
SubPc薄膜研究中發現,(1)薄膜沉積於室溫基板時,薄膜晶體出現差排缺陷之臨界厚度為大於150nm。(2)當薄膜以0.5Å/sec鍍率、室溫基板溫度的條件成長時,薄膜的成長趨於平面方向(2D growth mode);若以70oC或100oC基板溫度的條件成長時,薄膜的成長同時具有平面與立體方向(2D+3D growth mode);若薄膜沉積在120oC基板溫度時,薄膜的成長趨於立體方向(3D growth mode)。
以XRD分析430nm SubPc薄膜,觀察到兩種晶面,分別為(221)與(122)。並描述此兩種晶面之分子排列。
從太陽能元件研究中發現,以0.5Å/sec鍍率、室溫基板成長之SubPc薄膜所製備的太陽能元件,其光電轉換效率為0.71%,而以0.5Å/sec鍍率、120oC基板之SubPc薄膜製備之元件可達1.48%。
關鍵字: 亞酞菁、太陽能電池
In this thesis, Boron subphthalocyanine chloride (SubPc-BCl) thin film was deposited by vacuum thermal evaporation technique. The films were characterized by UV/Vis spectrum analyzer, X-ray diffraction (XRD), atomic force microscopy (AFM) and field emission scanning electron microscope (FESEM). Next, to study the grown-mode effects in I-V measurement for the device of ITO(100nm)/PEDOT(60nm)/SubPc (10nm)/C60(40nm)/BCP(7nm)/Al(100nm).
In the study of SubPc films, We fine that:(1) Dislocation-appeared critical thickness of RT substrate-deposited SubPc film is thicker than 150nm; (2) SubPc film deposited on RT substrate and 0.5Å/sec evaporation condition is tend to 2D growth mode, 70oC and 100oC is 2D+3D and 120oC is 3D.
From XRD, (221) and (122) diffraction peak can be observed in 430nm SubPc film. Then, we describe molecular orientation of such films.
The solar cell base on SubPc/C60 shows an average power efficiency of 0.71% while the SubPc film is deposited by RT substrate and 0.5Å/sec evaporation condition. The average efficiency enhanced to 1.48% by 120oC substrate and 0.5Å/sec condition.
Keyword: Subphthalocyanine, Solar cell.
[1] 林堅楊,「矽晶太陽電池技術之發展與應用」。電機月刊,第十一卷第十二期,pp. 204-210。
[2] 馬小康、唐敏,「我國太陽光電技術之評估及建議」。機械月刊,第三十一卷第十一期,pp. 58-75。
[3] 中華民國九十五年臺灣能源統計手冊-經濟部能源局編印
[4] N. B. McKeown, “Phthalocyanine Materials”.
[5] 江文彥,「太陽能及其應用」。化工技術,第七卷第八期,pp. 211-216。
[6] 許嘉文,高效率有機/無機異質結構太陽能電池之探索,國立海洋大學(2006)。
[7] F. Yakuphanoglu, M. E. Aydin, T. Kilicoglu, J. Phys. Chem. B 110 (2006) pp. 9782-9784
[8] L. J. A. Koster, V. D. Mihailetchi, R. Ramaker, P. W. M. Blom, APPLIED PHYSICS LETTERS 86 (2005) 123509
[9] H. Bayhan, A. S. Kavasoglu, Turk J Phys 31 (2007) pp. 7-10.
[10] 王耀諄,“太陽能電池發電系統部分遮蔽故障之解析模型",95 年度節約能源論文發表會論文集,pp.237-250.
[11] J. W. Matthews, A. E. Blakeslee, J. Cryst. Growth 27 (1974) pp. 118.
[12] http://www.iue.tuwien.ac.at/phd/smirnov/node68.html
[13] S. R. Forrest, Chem. Rev. 97 (1997) pp. 1793-1896.
[14] P. E. Burrows, Y. Zhang, E. I. Haskal, S. R. Forrest, Appl. Phys. Lett. 61 (1992) pp. 2417.
[15] C. G. Claessens, D. González-Rodríguez, T. Tomás, Chem. Rev. 102 (2002) pp. 835-853.
[16] B. Maennig, M. Pfeiffer, Phys. Rev. B , 64 (2001) pp. 195-208.
[17] A. Meller, A. Ossko, Monatshefte fur chemie, 103 (1972) pp. 150-155.
[18] H. Kietaibl, Monatshefte fur chemie, 105 (1974) pp. 405-418.
[19] G. C. Christian, David González-Rodríguez, Tomás Torres, Chem. Rev. 102 (2002) pp. 835-853.
[20] A. Sastre, T. Torres, M.A. Díaz-García, F. Agulló-López, C. Dhenaut, S. Brasselet, I. Ledoux, J. Zyss, Journal of the American Chemical Society 118 (1996) pp. 2746-2747.
[21] N. Kobayashi, T. Ishizaki, K. Ishii, H. Konami, Journal of the American Chemical Society 121 (1999) pp. 9096-9110.
[22] M. Geyer, F. Plenzig, J. Rauschnabel, M. Hanack, B. Del Rey, A. Sastre, T. Torres, Synthesis (1999) pp. 1139-1151.
[23] D. González-Rodríguez, T. Torres, D.M. Guldi, J. Rivera, M.Á. Herranz, L. Echegoyen, Journal of the American Chemical Society 126 (2004) pp. 6301-6313.
[24] N. Kobayashi, Journal of Porphyrins and Phthalocyanines 3 (1999) pp. 453-467.
[25] C. G. Claessens, T. Torres, Angewandte Chemie - International Edition 41 (2002) pp. 2561-2565.
[26] N. Kobayashi, T. Ishizaki, K. Ishii, H. Konami, J. Am. Chem. Soc. 120 (1999) pp. 9096-9110.
[27] N. Kobayashi, J. Chem. Soc., Chem. Commun. (1991) pp. 1203-1205.
[28] B. Del Rey, U. Keller, T. Torres, G. Rojo, F. Agulló-López, S. Nonell, C. Marti, S. Brasselet, I. Ledoux, J. Zyss, J. Am. Chem. Soc. 120 (1998) pp. 12808-12817.
[29] M. Hanack, J. Rauschnabel, Tetrahedron Lett. 36 (1995) pp. 1629-1632.
[30] M. K. Engel, J. Yao, H. Maki, H. Takeuchi, H. Yonehara, C. Pac, Rep. Kawamura Inst. Chem. Res. 9 (1997) pp. 53-65.
[31] M. Geyer, F. Plenzig, J. Rauschnabel, M. Hanack, B. del Rey, A. Sastre, T. Torres, Synthesis (1996) pp. 1139-1151.
[32] M. Hanack, M. Geyer, J. Chem. Soc., Chem. Commun. (1994) pp. 2253-2254.
[33] K. Anke, M. Eckert, S. Rodríguez-Morgade, T. Torres, Chem. Commun. (2007) pp. 4104–4106.
[34] H. Yanagi, Phys. Rev. 61 (2000) pp. 1959-1964.
[35] S. Berner, M. de Wild, L. Ramoino, S. Ivan, A. Baratoff, H.-J. Güntherodt, H. Suzuki, D. Schlettwein, T. A. Jung, PHYSICAL REVIEW B 68 (2003) pp. 115410 1-11.
[36] S. Hitoshi, Y. Toshiki, M. Hideki, M. Shinro, Thin Solid Films 499 (2006) pp. 143 – 146.
[37] C.C. Mattheusa, W. Michaelisb, C. Keltinga, W.S. Durfeec, D. Wöhrleb, D. Schlettwein, Synthetic Metals 146 (2004) pp. 335–339.
[38] H. Yanagi, K. Ikuta, Surface Science 581 (2005) pp. 9–16.
[39] K. L. Mutolo, E. I. Mayo, B. P. Rand, S. R. Forrest, M. E. Thompson, J. AM. CHEM. SOC. 128 (2006) pp. 8108-8109.
[40] R. D. Webster, G. A. Heath, Phys. Chem. Chem. Phys. 3 (2001) pp. 2588-2594.
[41] S. Verlaak, S. Steudel, P. Heremans, D. Janssen, M. S. Deleuze, Phys. Rev. B 68 (2003) pp. 195-409.
[42] http://www.ndl.org.tw/cht/doc/3-1-1-4/se023_01.doc
[43] 統計生活網http://home.educities.edu.tw/rebecca0924/stat/index.htm
[44] A. Weitemeyer, H. Kliesch, and D. Wöhrle, J. Org. Chem. 60 (1996) pp. 4900-4904.
[45] 許樹恩、吳泰伯,”X光繞射原理與材料結構分析”
[46] L. Edwards, M. Gouterman, J. Mol. Spectros. 33 (1970) pp. 292.
[47] G. Martín, G. Rojo, F. Agulló-López, V. R. Ferro, J. M. García de la Vega, M. V. Martínez-Díaz, T. Torres, I. Ledoux, J. Zyss, J. Phys. Chem. B 106 (2002) pp. 13139-13145.
[48] V.R. Ferroa, J.M. GarcõÂa de la Vegab, R.H. GonzaÂlez-Jonteb, L.A. Povedaa, Journal of Molecular Structure (Theochem) 537 (2001) pp. 223-234.
[49] G. Hans, C. David, A. Tom, G. Claudio, P. Jef, H. Paul, Adv. Funct. Mater. 17 (2007) pp. 2653-2658.
[50] S. R. Forrest, Chem. Rev. 97 (1997) pp. 1793-1896.
[51] J. A. Venables, G. D. T. Spiller, M. Hanbücken, Rep. Prog. Phys. 47 (1984) pp. 399-459.
[52] P. Fenter, F. Schreiber, L. Zhou, P. E. Eisenberger, S. R. Forrest, Phys. Rev. B 56 (1997) pp. 3046.
[53] I.P.M. Bouchoms, W.A. Schoonveld, J. Vrijmoeth, T.M. Klapwijk, Synthetic Metals 104 (1999) pp. 175–178.
[54] T. M. Brown, J. S. Kim, R. H. Friend, F. Cacialli, R. Daik, W. J. Feast, APPLIED PHYSICS LETTERS 75 (1999) pp. 1679-1681.
[55] P. Peumans, S. Uchida, S. R. Forrest, Nature 425 (2003) pp. 158.
[56] M. Reyes-Reyes, K. Kim, D. L. Carroll, Appl. Phys. Lett. 87 (2005) pp. 083506.
[57] D.J. Gundlach, Y.Y. Lin, T.N. Jackson, S.F. Nelson, D.G. Schlom, IEEE Electron Dev. Lett. 18 (1997) pp. 87.
[58] J.G. Laquindanum, H.E. Katz, A.J. Lovinger, A. Dodabalapur, Chem. Mater. 8 (1996) pp. 2542.
[59] L. A. Koster, V. D. mihailetchi, R. Ramaker, P. W. M. Blom, APPLIED PHYSICS LETTERS 86 (2005) pp. 123509-1.
[60] I. Riedel, J. Parisi, V. Dyakonov, L. Lutsen, D. Vanderzande, J. C. Hummelen, Adv. Funct. Mater. 14 (2004) pp. 38-44.
[61] 統計生活館http://home.educities.edu.tw/rebecca0924/