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研究生: 蔡佳燕
Jia-yan Tsai
論文名稱: 光硬化高分子/鈦酸鋇複合材料在快速原型系統中熱性質與機械性質之研究
The Investigation of thermal and mechanical properties of photopolymer/BaTiO3 nanocomposite applied on Rapid Prototyping system
指導教授: 邱士軒
Shih-Hsuan Chiu
口試委員: 邱智瑋
none
邱顯堂
none
游進陽
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2013
畢業學年度: 101
語文別: 英文
論文頁數: 53
中文關鍵詞: 快速原型奈米覆合材料鈦酸鋇機械性質熱性質
外文關鍵詞: Rapid Prototyping, Nano-composites, BaTiO3, Mechanical properties, Thermal properties
相關次數: 點閱:239下載:0
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快速原型系統為一種產品製造的系統,藉由此系統快速開發新的展品,並且降低製造成本。在過往的研究中,快速原型系統主要的加工材料為光硬化樹脂,以光做為能量來源,照射至光硬化樹脂來硬化成型,但材料成型後成脆性,為了克服此問題,本次研究的複合材料中以TPA為主要基材,此材料具有環保特性,不含揮發性有機化合物的排放,且低能量消耗,1,6 - 己二醇丙烯酸酯(HDDA)作為反應稀釋劑,降低樹脂黏度,並添加奈米鈦酸鋇粉末(Nano BaTiO3),增強機械性質和熱性質。


Rapid Prototyping system is a product manufacturing system using light as main energy source. It can reduce cost of developing new product from the initial idea to production. A major drawback of Rapid Prototyping technology is the photopolymer, material uses in this system, are brittle. In order to overcome this problem, a composite system of nano Barium Titanate (nano BaTiO3) and Tetra-function Polyacrylate (TPA) was investigated. TPA is UV-curing acrylate resin that suitable for rapid prototyping system. It also has environment-friendly aspect (no VOC emission and low energy consumption). As reactive diluents, 1,6 Hexanediol Acrylate (HDDA) was added. As result, Addition BaTiO3 can increase mechanical properties and thermal properties .

摘要 I ABSTRACT II CONTENTS III FIGURES INDEX V TABLES INDEX VI Chapter1、 Introduction 7 1.1 Introduction 7 1.2 Background and literature 8 1.3 Composite 12 1.4 Nanocomposite 13 1.4.1 Polymer matrix 15 1.4.2 Interfacial interactions 16 1.5 Classification of reinforced composite 17 1.5.1 Nanoparticle-reinforced composites 17 1.5.2 Nanoplatelet-reinforced composites 18 1.5.3 Nanofiber-reinforced composites: 19 1.5.4 Carbon nanotube-reinforced composites 19 1.6 Outline of the thesis 21 Chapter2、 Fundamental theory 22 2.1 Titanate barium (BaTiO3) 22 2.2 Photo-initiator 22 2.3 Photopolymerization Reaction 23 2.4 The principle of rapid prototyping process 24 Chapter3、 Experiment 25 3.1 Reagents 25 1 . Tetrafunction Polyester Acrylate(TPA) 25 2 . 1,6-Hexanediol Diacrylate (HDDA) 25 3 . Nano Barium Titanate (Nano-BaTiO3) 26 4 . Photo-initiator 26 3.2 Equipment 27 3.3 Experiment process 32 3.3.2 Rapid prototyping Processing 34 3.4 Experiment result 38 3.4.1 Mechanical properties of TPA BaTiO3 composite 38 3.4.2 Thermal properties of TPA BaTiO3 composite 41 Chapter4、 Conclusion 47 Chapter5、 Reference 49

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