簡易檢索 / 詳目顯示
| 研究生： |
林祖薇 Tzu-Wei Lin |
|---|---|
| 論文名稱： |
用在有機光伏電池含D-π-A結構之低能隙共軛高分子其合成及鑑定 Synthesis and Characterization of Low Band-Gap π-Conjugated Polymers Containing D-π-A Structure for Organic Photovoltaics |
| 指導教授： |
陳錦地
Chin-Ti Chen |
| 口試委員: |
林建村
Jiann-T'suen Lin 戴龑 Yian Tai |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 化學工程系 Department of Chemical Engineering |
| 論文出版年： | 2015 |
| 畢業學年度： | 103 |
| 語文別： | 中文 |
| 論文頁數： | 234 |
| 中文關鍵詞： | 有機光伏電池 |
| 外文關鍵詞： | Organic Photovoltaics |
| 相關次數： | 點閱：168 下載：1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本篇研究藉由導入具立體規則性的3,4',4'',4'''-四己基-2,2':5',2'':5'',2'''-四噻吩 (H4T)作為電子予體，希望能增加共軛高分子的排列性，並與不同的電子受體︰咯併咯二酮衍生物 (DPP)、苯并噻二唑 (BT)、苯并硒二唑 (BS)、2,2’-二噻吩-3,3’-二醯亞胺 (BTDI)進行聚合。
In this work, we have synthesized thirteen different π-conjugated donor-acceptor (D-A) copolymers (C6C10DPP-H4, C4C8DPP-H4T, C2C6DPP-H4T, C16DPP-H4T, C12DPP-H4T, C8DPP-H4T, BT-H4T, BT2F-H4T, BT2CN-H4T, BS-H4T, BS2F-H4T, BS2CN-H4T and BTDI-H4T) bearing regioregular 3,4',4'',4'''-tetrahexyl-2,2':5',2'':5'',2'''-quaterthiophene (H4T) as the electron donor with various electron acceptors via Stillie coupling reaction.
[1] M. Z. Jacobson and G. M. Masters, Science 2001, 293, 1438.
[2] R. Perez and M. Perez, A fundamental look at energy reserves for the planet, The IEA SHC Solar Update 2009, 50, 2.
[3] A. E. Becquerel, C. R. Hebd. Seances Acad. Sci. 1839, 561.
[4] D. Kearns, M. Calvin, J.Chem.Phys. 1958, 29, 950.
[5] J. Tsukamoto, H. Ohigashi, K. Matsumura, A. Takahashi, Jpn. J. Appl. Phys. 1981, 20, 127.
[6] G. Yu, C. Zhang, A. J Heeger, Appl.Phys.Lett. 1994, 64, 1540.
[7] S. E Shaheen, C. J Brabec, N. S. Sariciftci, Appl. Phys Lett. 2001 , 78, 841
[8] F. Padinger, R.S Rittberger and N.S Sariciftci, Adv. Funct. Mater. 2003, 13, 85.
[9] D. Chirvase, J. Parisi, J. C. Hummelen, V. Dyakonov, Nanotechnology 2004, 15, 1317.
[10] J. Huang, G. Li and Y. Yang, Appl, Phys. Lett. 2005, 87, 112105.
[11] G. Li, V. Shortriya, Y. Yao and Y. Yang, J. Appl. Phys. 2005, 98, 43704.
[12] Y.Yang...etl, Chem.Phys.Lett. 2005, 411, 138.
[13] M. Green, K. Emery, Y. Hishikawa, W. Watra, Prog. Photovolt: Res. Appl. 2015, 23, 1.
[14] C. W. Tang, Appl. Phys. Lett. 1986, 48, 183.
[15] N. S. Sariciftci, L. Smilowitz, A. J. Heeger, F. Wudl, Science 1992, 27, 1474.
[16] G. Yu, J. Gao, J. C. Hummelen, F. Wudl, and A. J. Heeger, Science 1995, 270, 1789.
[17] P. W. Atkins, Kurzlehrbuch Physikalische Chemie, 2001, 454.
[18] T. Yamamoto, K. Sanechika and A. Yamamoto, J. Polym. Sci., Polym. Lett. Ed. 1980, 18, 9.
[19] J. W. P. Lin and L. P. Dudek, J. Polym. Sci., Polym. Chem. Ed. 1980, 18, 9.
[20] K. Y. Jen, R. Obodi and R. L. Elsenbaumer, Polym. Mater. Sci. Eng. 1985, 53, 79.
[21] R. C. Nieuwendaal, C. R. Snyder, D. M. DeLongchamp, Macro Lett. 2014, 3, 130.
[22] H. Sirringhaus, P. J. Brown, R. H. Friend, M. M. Nielsen, K. Bechgaard, B. M. W. Langeveld-Voss, A. J. H. Spiering, R. A. J. Janssen, E. W. Meijer, P. Herwig and D. M. De Leeuw, Nature 1999, 401, 685.
[23] X. Jiang, R. Patil, Y. Harima, J. Ohshita and A. Kunai, J. Phys. Chem. B 2005, 109, 221.
[24] W. Luzny and A. Pron, Synth. Met. 1997, 84, 573.
[25] M. Trznadel, A. Pron, M. Zagorska, R. Chrzaszcz and J. Pielichowski, Macromolecules 1998, 31, 5051.
[26] Y. Kim, S. Cook, S. M. Tuladhar, S. A. Choulis, J. Nelson, J. R. Durrant, D. D. C. Bradley, M. Giles, I. McCulloch, C.-S. Ha and M. Ree, Nat. Mater. 2006, 5, 197.
[27] M. Urien, L. Bailly, L. Vignau, E. Cloutet, A. de Cuendias, G. Wantz, H. Cramail, L. Hirsch and J.-P. Parneix, Polym. Int. 2008, 57, 764.
[28] Schilinsky P. Schilinsky, U. Asawapirom, U. Scherf, M. Biele and C. J. Brabec, Chem. Mater. 2005, 17, 2175.
[29] K. Sivula, C. K. Luscombe, B. C. Thompson, and J. M. J. Fréchet, J. Am. Chem. Soc. 2006, 128, 13988.
[30] L. J. A. Koster, V. D. Mihailetchi, P. W. M. Blom, Appl, Phys. Lett. 2006, 88, 93511.
[31] E. Bundgaard, F. C. Krebs, Solar Energy Materials & Solar Cells 2007, 91, 954.
[32] M. C. Scharber, D. Muhlbacher, M. Koppe, P. Denk, C. Waldauf, A. J. Heeger, C. J. Brabec, Adv. Mater. 2006, 18, 789.
[33] Y. Li, P. Sonar, L. Murphy, W. Hong, Energy Environ. Sci. 2013, 6, 1684.
[34] D. Mühlbacher, M. Scharber, M. Morana, Z. Zhu, D. Waller, R. Gaudiana,C. Brabec, Adv. Mater. 2006, 18, 2884.
[35] J. Peet, J. Y. Kim, N. E. Coates, W. L. Ma, D. Moses, A. J. Heeger, G. C. Bazan Nat. Mater. 2007, 65, 497.
[36] (a) F. Zhang, K. G. Jespersen, C. Björström, M. Svensson, M. R. Andersson, V. Sundström, K. Magnusson, E. Moons, A. Yartsev, O. Inganäs, Adv. Funct. Mater. 2006, 16, 667. (b) S. Admassie, O. Inganäs, W. Mammo, E.Perzon, M. R. Andersson, Syn. Met. 2006, 156, 614.
[37] N. Blouin, A. Michaud, M. Leclerc, Adv, Mater. 2007, 19, 2295.
[38] S. H. Park, A. Roy, S. Beaupre, S. Cho, N. Coates, J. S. Moon, Da. Moses,
M. Leclerc, K. Lee, Alan J. Heeger, Nat. Photonics. 2009, 3, 297.
全文公開日期 2020/07/27 (校內網路)全文公開日期 本全文未授權公開 (校外網路)
全文公開日期 本全文未授權公開 (國家圖書館：臺灣博碩士論文系統)