研究生: |
陳柏均 Bo-Jyun Chen |
---|---|
論文名稱: |
銅-鋯-銀三元系統非晶區域之判定與銅-鋯-銀、銅-鋁-銀三元系統於500oC之相平衡 Determination of the amorphous regions of the Cu-Zr-Ag ternary system and the phase equilibria of Cu-Zr-Ag, Cu-Al-Ag ternary systems at 500oC |
指導教授: |
顏怡文
Yee-wen Yen |
口試委員: |
吳子嘉
Albert T. Wu 陳志銘 C. M. Chen 施劭儒 Shao-Ju Shih |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2012 |
畢業學年度: | 100 |
語文別: | 中文 |
論文頁數: | 155 |
中文關鍵詞: | 金屬玻璃 、非晶質合金 、玻璃形成能力 、相平衡 、三元相圖 |
外文關鍵詞: | metallic glasses, amorphous alloys, glass-forming ability, phase equilibria, ternary phase diagrams |
相關次數: | 點閱:373 下載:2 |
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塊材金屬玻璃由於強韌的機械性質、特殊的磁性質與優良的抗腐蝕性,因此近年來獲得廣泛的研究興趣。銅-鋯基的塊材金屬玻璃經研究後發現擁有較高的金屬玻璃形成能力,銀則容易取得,因此本研究配置不同組成之銅-鋯-銀三元合金,並利用電弧熔煉爐搭配銅模冷卻法製備塊材金屬玻璃。另外,進行銅-鋯-銀與銅-鋁-銀三元系統在500oC下之相平衡,將此平衡結果與非晶合金進行比較。
研究結果顯示,組成為Cu45Zr45Ag10的合金擁有最好的玻璃形成能力,且合金成份位於Cu35-50Zr40-55Ag10-20區域的銅-鋯-銀三元合金可以形成非晶質合金,而在合金組成Cu30-50Zr30-55Ag0-30區域中則會形成非晶質合金與結晶顆粒共存。由相平衡結果發現,銅-鋯-銀三元合金在500oC下存在9個單相區、15個兩相區、7個三相區,並無發現三元介金屬相的存在。銅-鋁-銀三元合金在500oC下則存在8個單相區、13個兩相區、6個三相區,同樣並無發現三元介金屬相。
Bulk metallic glasses (BMGs) have attracted many interests in recent years because their strong mechanical properties, excellent corrosion resistance and good permeability. Zr-Cu based systems have high glass-forming ability (GFA)while Ag is easy to obtain. In this study, Cu-Zr-Ag alloys with different compositions were prepared, and the BMGs were produced by arc melting and copper mold. For comparison, the phase equilibria of Cu-Zr-Ag and Cu-Al-Ag ternary systems was investigated at 500oC.
As the result, the best glass-forming ability (GFA) was obtained by the Cu45Zr45Ag10 alloy. In general, the amorphous region of Cu-Zr-Ag ternary system is Cu35-50Zr40-55Ag10-20. While amorphous and crystalline structures existed simultaneously in the region of Cu30-50Zr30-55Ag0-30.
According to the results of phase equilibria, there were 9 single-phase regions, 15 two-phase regions and 7 three-phase regions in Cu-Zr-Ag ternary system at 500oC, and no ternary compound was found. On the other hand, in the Cu-Al-Ag ternary system, there were 8 single-phase regions, 13 two-phase regions and 6 three-phase regions but there was no ternary compound at 500oC.
參考文獻
[1] A. Inoue, Tohoku University, Sendai, Japan (1999)
[2] J. P. Chu, C. L. Chiang, T. G. Nieh, Y. Kawamura , Intermetallics, 10 (2002) 1191-1195.
[3] W. Zhang, A. Inoue, Mater. Trans., 45 (2004) 1210-1213.
[4] N. Nishiyama, K. Amiya, A. Inoue, Mater. Trans., 45 (2004) 1245-1250.
[5] A. Inoue, Acta Mater., 48 (2000) 279-306.
[6] A. Inoue, T. Zhang and T. Masumoto, Mater. Trans. JIM, 36 (1995) 391-398.
[7] Y.C. Kim, J.C. Lee, P.R. Cha, J.P. Ahn, E. Fleury, Mater. Sci. Eng., A 437 (2006) 248-253.
[8] J. Kramer, Annln Phys., 37 (1934) 19.
[9] A. Bremer, D. E. Couch and E. K. Williams, J. Res. Natn. Bur. Stand., 44 (1950) 109-122.
[10] W. Klement, R. H. Wilens and P. Duwez, Nature, 187 (1960) 869.
[11] H. S. Chen and C.E. Miller, Rev. Sci. Instrum, 41 (1970) 1237-1970.
[12] A. Ioune, T. Zhang and T. Masumoto, Mater. Trans. JIM 30 (1989) 965-972.
[13] A. Ioune, T. Zhang and T. Masumoto, Mater. Trans. JIM 30 (1989) 722-725.
[14] A. Ioune, A. Kato, T. Zhang, S.G. Kim and T. Masumoto, Mater. Trans. JIM 30 (1991) 609-616.
[15] A. Ioune, W. Zhang, Trans. JIM 45 (2004) 584.
[16] W.L. Johnson, MRS Bull. 24 (1999) 42-56.
[17] A. Inoue, W. Zhang, T. Zhang, K, Kurosaka, Journal of Non Crystalline Solids. 304 (2002) 200-209.
[18] A. Peker, W.L. Johnson, Appl. Phys. Lett. 63 (1993) 2342-2344
[19] T. Zhang, A. Inoue, T. Masumoto, Mater. Trans. JIM 32 (1991) 1005-1010
[20] G.Q. Zhang, X.J. Li, M. Shao, L.N. Wang, J.L. Yang, L.P. Gao, L.Y. Chen, C.X. Liu, Mater. Sci. Eng. A 475 (2008) 124-127
[21] A. Inoue, W. Zhang, T. Zhang, K. Kurosaka, Acta Mater. 49 (2001) 2645-2652
[22] A. Inoue, W. Zhang, Mater. Trans. 43 (2002) 2921-2925
[23] X.H. Lin, W.L. Johnson, J. Appl. Phys. 78 (1995) 5619-6514
[24] V. Ponnambalam, S.J. Poon, G.J.Shiflet, J. Mater Res. 19 (2004) 1320.
[25] A. Inoue, Wei Zhang, Tao Zhang, Kei Kurosaka. Journal of Non-Crystalline Solids, 304 (2002) 200-209.
[26] X. Wang, I. Yoshii, A. Inoue, Y.H. Kim I.B. Kim, Mater. Trans. JIM 40 (1999) 1130-1136.
[27] S. Yi, T.G. Park, D.H. Kim, J. Mater. Res. 15 (2000) 2425-2430.
[28] I.B. Kin, Mater. Trans. JIM 40 (1999) 1130-1136.
[29] D. Wang, H. Tan, Y. Li, Acta Mater. 53 (2005) 2969-2979.
[30] E.S.Park, H.J. Chang, D.-H. Kim, T. OhkuBo, K. Hono, Scr. Mater. 54 (2006) 1569-1573.
[31] J.C. Oh, T. OhkuBo, Y.-C. Kim, E. Fleury, K. Hono, Scr. Mater. 53 (2005) 165-169.
[32] 吳學陞,新興材料-塊狀非晶質金屬材料,工業材料,149期,1999。
[33] L. I. Naissel and R. Glanz, “Handbook of Thin Film Technology”, McGraw-Hill, New York, 1970.
[34] G. N. Jackson, “Thin Solid Films”, Champman and Hall, (1970) 209.
[35] R. W. Cahn, P. Hassen and E. J. Kramer(ed), Materials Science and Technology Vol. 9, New York, USA, 1991.
[36] K. L. Chapra, Thin Film Phenomena, McGraw-Hill, (1985) 1969-1972.
[37] B. Li, N. Nordstrom and E. J. Lavernia, Mater. Sci. Eng., A237 (1997) 207-215.
[38] C. R. M. Afonso, C. Bolfarini, C. S. Kiminami, N. D. Bassim, M. J. Kaufman, M. F. Amateau, T. J. Eden and J. M. Galbraith, J. Non-Cryst. Solids, 284 (2001) 134-138.
[39] R. Liu, J. Li, K. Dong, C. Zheng and H. Liu, Mater. Sci. Eng., B94 (2002) 141-148.
[40] J. Lee, F. Zhou, K. H. Chung, N. J. Kim and E. J. Lavernia, Metall. Mater. Trans., A32 (2001) 3109-3115.
[41] M. S. El-Eskandarany and A. Inoue, Metall. Mater. Trans., A33 (2002) 135-143.
[42] Z. P. Xing, S. B. Kang and H. W. Kim, Metall. Mater. Trans., A33 (2002) 1521-1530.
[43] L. B. Davies and P. J. Grundy, J. Non-cryst. Solids, 11 (1972) p.747.
[44] 田弘宇,“鐵基與鎳基非晶塊狀材料之開發”,碩士論文, (2005) ,p.60。
[45] R. W. Cahn, P. Hassen and E. J. Kramer (ed.), Materials Science and Technology. vol.9 (VCH, New York, 1991).
[46] 吳學陞,鎂銅釔合金非晶質化動力學,結晶化及性能之研究,1996,p.18。
[47] E. S. Park, H. G. Kang, W. T. Kim, et al., Journal of Non Crystalline Solids, 279 (2001) 154-160.
[48] 楊政翰,“鎂基非晶/奈米結構複合合金 合成製作之研究”,碩士論文 (2005),p.60。
[49] 葉銘騏,“以水冷銅模鑄造銅基塊狀非晶質合金與血液相容性評估”,碩士論文,2005,p.30。
[50] T. Zhang, K. kurosuka, A. Inoue, Mater. Trans. 42 (2001) 2042-2045
[51] A. Inoue, Mater. Sci. Eng., A226-228 (1997) 357-363.
[52] A. Inoue, H. Koshiba, T. Zhang and A. Makino, J. Appl. Phys., 83 (1998) 1967-1974.
[53] A. Inoue, M. Koshiba, T. Itoi and A. Makino, Appl. Phys. Lett., 73 (1998) 744.
[54] C. Zhang, N. Li, J. Pan, S.F. Guo, M. Zhang, L. Liu, J. Alloys Compd. 504S (2010) S163-S167
[55] 應用科學:可彎的玻璃(SciScape -- 科景全球新聞報導) http://www.sciscape.org/news_detail.php?news_id=2207。
[56] 陳丹,堅硬似鋼鐵柔軟如流水的金屬玻璃,中小企業科技,2005,第6期。
[57] 吳再豐,神奇的“金屬玻璃”,百科知識,2011。
[58] NanoGlobe Pte. Ltd. Emerging Nanotechnology Power (2009)
http://www.nanotech-now.com/columns/?article=386
[59] A. Inoue, B. L. Shen, H. Koshiba, H. Kato, A. R. Yavari, Acta Materialia, 52 (2004) 1631~1637.
[60] K. M. Flores, and R. H. Dauskardt. Scripta Materialia, 41 (1999) 937-943.
[61] R. D. Conner, R. B. Dandliker, V. Scruggs, W.L. Johnson. International Journal of Impact Engineering, 24 (2000) 435.
[62] A. Inoue, Mater. Sci. Eng., A 226-228 (1997) 357-363.
[63] A. Inoue, A. Takeuchi and T. Zhang, Metall. Mater. Trans. A 29 (1998) 1779-1785.
[64] A. Inoue, Buck Amorphous Alloys. Trans Tech Publications, Zurich, Swiss, 1998.
[65] R. E. Reed-Hill, Physical Metallurgy Principles, PWS, Boston, USA, 1994.
[66] 惠希東,陳國良,塊體非晶質合金,化學工業出版社,2007,40.
[67] Turnbull D. Contemp. Phys., 10 (1969) 473.
[68] Z.P. Lu et al. Journal of Non-Crystalline Solids, 270 (2000) 103-114.
[69] Z. P. Lu, C.T. Liu Acta. Materialia, 50 (2002)3501~3512.
[70] Weinberg MC. J. Non-cryst. Solids, 167 (1994) 81-88.
[71] W. L. Johnson, MRS Bull. 24 (1999) 42-56.
[72] A. Inoue, W. Zhang, T. Zhang, K. Kurosaka, Acta Mater., 49 (2001) 2645-2652.
[73] A. Inoue, W. Zhang, Mater. Trans. 43 (2002) 2921-2925.
[74] A. Inoue, W. Zhang, J. Mater. Res. 18 (2003) 1435-1440.
[75] A. Inoue, D. Kawase, A. P. Tai, T. Zhangand T. Masumoto. Mater. Sci. Eng. A 178 (1994) 255.
[76] L. Q. Xing, G. P. Gorler, D. M. Herlach. Mater. Sci. Eng. A 226-228 (1997) 429-433.
[77] Gang Duan, Katrien De Blauwe, Mary Laura Lind, Joseph P. Schramm. Scripta Mater. 58 (2008) 159–162.
[78] F.R.Niessen, Cohesion in Metals, Elsevier Science Publishers, Amsterdam, (1988) p. 244.
[79] G.Q. Zhang, X. J. Li, M. Shao, L. N. Whang, J. L. Yang, L. P. Gao, L. Y. Chen, C.X. Liu, Mater. Sci. Eng. A 475 (2008) 124-127
[80] W. J. Ma, Y. R. Wang, B. C. Wei, Y. F. Sun, Trans. Nonferrous Met. Soc. China 17 (2007) 929-933
[81] W. Zhang, Q. Zhang, A. Inoue, Mater. Sci. Eng. B 148 (2008) 92-96
[82] L. Liu, C.L. Qiu, C.Y. Huang, Y. Yu, H.Huang, S.M. Zhang, Int. 17 (2009) 235-240
[83] K. J. H. Buschow. J. Appl. Phys, 52 (1981) 3319.
[84] C. Li, J. Saida, M. Kiminami, A. Inoue, J. Non-cryst. Solids, 261 (2000) 108-114.
[85] A. Inoue: Mater. Sci. Forum 269-272 (1998) 855-864.
[86] A. Inoue: Acta Mater. 297 (2000) 279-306.
[87] A. Inoue, W. Zhang, T. Zhang and K. Kurosaka, JIM 42 (2001) 1149-1151.
[88] M.B. Tang, D.Q. Zhao, M.X. Pan, W.H. Wang, Chinese Physics Letters, 52 (2004) 2621-2624.
[89] H. Men, S.J. Pang, T. Zhang, Mater. Sci. Eng. A 408 (2005) 326-329
[90] W. Zhang, F. Jia, Q. Zhang, A. Inoue, Mater. Sci. Eng. A 459 (2007) 330-336
[91] X. F. Wu, Z. Y. Suo, Y. Si, L. K. Meng, K. Q. Qiu, J. Alloys Compd 452 (2008) 268-272
[92] T. B. Massalski, H. Okamoto, P. R. Subramanian and L. Kacprzak, “Cu-Zr phase diagram”, Binary Alloy Phase Diagrams, second edition, ASM Internaitional, Materials Park, Ohio, Vol. 1, (1992) 1512.
[93] T. B. Massalski, H. Okamoto, P. R. Subramanian and L. kacprzak, “ Ag-Zr phase diagram”, Binary Alloy Phase Diagrams, second edition, ASM Internaitional, Materials Park, Ohio,Vol. 1, (1990) 119.
[94] T. B. Massalski, H. Okamoto, P. R. Subramanian and L. Kacprzak, “Cu-Ag phase diagram”, Binary Alloy Phase Diagrams, second edition, ASM Internaitional, Materials Park, Ohio, Vol. 1, (1992) 30.
[95] T. B. Massalski, H. Okamoto, P. R. Subramanian and L. Kacprzak, “Cu-Al phase diagram”, Binary Alloy Phase Diagrams, second edition, ASM Internaitional, Materials Park, Ohio, Vol. 1, (1992) 142.
[96] T. B. Massalski, H. Okamoto, P. R. Subramanian and L. Kacprzak, “Ag-Al phase diagram”, Binary Alloy Phase Diagrams, second edition, ASM Internaitional, Materials Park, Ohio, Vol. 1, (1990) 9.
[97] T. B. Massalski, H. Okamoto, P. R. Subramanian and L. kacprzak, “ Al-Zr phase diagram”, Binary Alloy Phase Diagrams, second edition, ASM Internaitional, Materials Park, Ohio, Vol. 1, (1990) 241 -242.
[98] P. Villars, A. Prince, H. Okamoto, “Ag-Al-Cu phase diagram”, Handbook of Ternary Alloy Phase Diagram, ASM International, Vol. 3, (1995) 2001-2006.
[99] V. T. Witusiewicz, U. Hecht, S.G. Fries, S. Rex, J.Alloys Compd. 387 (2005) 217-227
[100] V. Raghavan, J. phase Equilib. Diffusion, 29 (2008) 256-258