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研究生: 黃筠婷
Yun-Ting Huang
論文名稱: 新的特定吸光範圍之丙烯酸衍生物單體合成與特殊功能性濾光片製備
Synthesis of New Acrylic Acid Derivative Monomers with Specific Absorption Ranges and Preparation of Specialized Functional Filters
指導教授: 何郡軒
Jinn-Hsuan Ho
口試委員: 王孟菊
Meng-Jiy Wang
林文賓
Wen-Bin Lin
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 132
中文關鍵詞: 甲基丙烯酸縮水甘油酯甲基丙烯酸羥乙酯有機染料開環反應酯化反應
外文關鍵詞: glycidyl methacrylate, 2-hydroxyethyl methacrylate, organic dye, ring-opening reaction, esterification reaction
相關次數: 點閱:236下載:0
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摘要 I Abstract II 誌謝 III 目錄 IV 符號索引 VII 圖目錄 IX 表目錄 XII 流程圖目錄 XIII 附錄目錄 XIV 第一章 緒論 1 1.1 前言 1 1.2 文獻回顧 3 1.2.1有機染料(Organic dye) 3 1.2.2 甲基丙烯酸縮水甘油酯(Glycidyl methacrylate, GMA) 5 1.3 研究動機與目標 10 第二章 實驗部分 11 2.1實驗原理 11 2.1.1 鈴木反應(Suzuki reaction) 11 2.1.2 環氧基團開環與丙烯酸進行酯化反應 12 2.2實驗儀器與器材 13 2.3儀器原理 14 2.3.1 核磁共振光譜法(Nuclear magnetic resonance spectroscopy, NMR) 14 2.3.2 紫外-可見光分光光譜儀(UV-Vis spectrophotometer) 14 2.3.3 質譜分析法(Mass spectrometry, MS) 15 2.4 實驗藥品與溶劑 16 2.4.1 實驗藥品 16 2.4.2 實驗溶劑 17 2.5 化合物結構、分子式、分子量與命名 18 2.6 單體合成方法 21 2.6.1 製備TPATTAc 21 2.6.2 製備丙烯酸衍生物 22 2.6.3 製備GMA衍生物 23 2.7 單體合成步驟 25 2.8 製備紫外光固化試片 37 2.9 物性量測方法 39 2.9.1 凝膠率(Gel fraction)量測方法 39 2.9.2 吸收/穿透光譜量測方法 39 2.9.3 溶脹比(Swelling)量測方法 40 2.9.4 掉色測試量測方法 41 第三章 結果與討論 42 3.1 產物鑑定 42 3.1.1 DMACA與DMA-GMA的1H與13C NMR分析 42 3.1.2 TPAT、TPATTAc、TPATTCA與TPATT-GMA的1H NMR分析 46 3.1.3 TCA與TCA-GMA的1H NMR分析 51 3.1.4 TPAA與TPAA-GMA的1H NMR分析 54 3.1.5 RdB-GMA的1H NMR分析 57 3.1.6 DAB-GMA的1H NMR分析 59 3.2 凝膠率(Gel fraction)分析 61 3.3 溶脹比(Swelling)分析 64 3.4 高分子聚合物的吸收與穿透光譜 70 3.5 混色高分子聚合物 75 3.5.1 吸收度公式 75 3.5.2 掉色測試 79 第四章 結論 88 4.1 結論 88 4.2 未來展望 89 第五章 參考文獻 90 附錄 94

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