恆溫下寡聚物與醇類混合物之汽液相平衡研究｜國立臺灣科技大學博碩士論文系統

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研究生：	何安娜 Ianatul - Khoiroh
論文名稱：	恆溫下寡聚物與醇類混合物之汽液相平衡研究 Isothermal Vapor-Liquid Equilibrium for Mixtures of Oligomeric Materials with Alcohols
指導教授：	李明哲 Ming-Jer Lee 林河木 Ho-Mu Lin
口試委員:	李夢輝 Meng-Hui Le
學位類別：	碩士 Master
系所名稱：	工程學院 - 化學工程系 Department of Chemical Engineering
論文出版年：	2009
畢業學年度：	97
語文別：	英文
論文頁數：	108
中文關鍵詞：	寡聚物、相平衡、醇類
外文關鍵詞：	Isothermal Vapor-Liquid Equilibrium, Oligomeric Materials, Alcohols
相關次數：	點閱：246 下載：0
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A vapor pressure apparatus was installed to measure isothermal vapor-liquid
equilibrium (VLE) data for seven binary systems of polybutadiene + methylene chloride
(341.1 to 409.0) K, polyethylene glycol mono-4-octylphenyl ether (PEGOPE) + methanol
at (341.0 to 403.1) K, PEGOPE + ethanol at (342.6 to 454.1) K, PEGOPE + 2-propanol at
(350.1 to 453.3) K, polyethylene glycol mono-4-nonylphenyl ether (PEGNPE) + methanol
at (340.6 to 414.7) K, PEGNPE + ethanol at (341.9 to 414.1) K, and PEGNPE +
2-propanol at (351.5 to 454.5) K. Equilibrium pressure measurements were conducted to
obtain P-T-x data. The experimental data were correlated by using the Antoine equation to
regress the Antoine constants. These VLE data were further treated using the Barker’s
method and correlated with the UNIQUAC and the Polymer NRTL activity coefficient
models, respectively. The correlation results showed good agreement between the
calculated values and the experimental data. The solvent activities of the experimental
results are also reported and agree fairly well with the calculated values from the
UNIQUAC equation.

Figure	Page
1-1	Plot of benzene activity, a1, versus volume fraction of rubber 	3
1-2	Schematic diagram of vapor pressure measurement apparatus	8
1-3	Schematic diagram of quartz crystal microbalance method	8
1-4	Schematic diagram of gas chromatography apparatus	9
1-5	Schematic diagram of simple membrane osmometry method	9
2-1	Molecular structure of polybutadiene	16
2-2	Molecular structure of PEGOPE	16
2-3	Molecular structure of PEGNPE	16
2-4	Schematic diagram of vapor pressure measurement apparatus	20
2-5	HP/HT 4576 Parr reactor (before modification)	21
2-6	Bottom drain valve	22
3-1	Vapor pressures of methylene chloride in comparison
	with literature data	32
3-2	Vapor pressures of methanol in comparison with literature data	33
3-3	Vapor pressures of ethanol in comparison with literature data	34
3-4	Vapor pressures of 2-propanol in comparison with literature data	35
3-5	Vapor pressures of polybutadiene (1) + methylene chloride (2)	50
3-6	Vapor pressures of PEGOPE (1) + methanol (2)	51
3-7	Vapor pressures of PEGOPE (1) + ethanol (2)	52
3-8	Vapor pressures of PEGOPE (1) + 2-propanol (2)	53
3-9	Vapor pressures of PEGNPE (1) + methanol (2)	54
3-10	Vapor pressures of PEGNPE (1) + ethanol (2)	55
3-11	Vapor pressures of PEGNPE (1) + 2-propanol (2)	56
4-1	Representation of lattice model containing solvent molecules and
	low molecular weight solute	57
4-2	Lattice model for a polymer chain in solution	58
4-3	Comparison between experimental and calculated results of
	equilibrium pressures of polybutadiene (1) + methylene chloride (2)	72
4-4	Comparison between experimental and calculated results of
	equilibrium pressures of PEGOPE (1) + methanol (2)	73
4-5	Comparison between experimental and calculated results of
	equilibrium pressures of PEGOPE (1) + ethanol (2)	74
4-6	Comparison between experimental and calculated results of
	equilibrium pressures of PEGOPE (1) + 2-propanol (2)	75
4-7	Comparison between experimental and calculated results of
	equilibrium pressures of PEGNPE (1) + methanol (2)	76
4-8	Comparison between experimental and calculated results of
	equilibrium pressures of PEGNPE (1) + ethanol (2)	77
4-9	Comparison between experimental and calculated results of
	equilibrium pressures of PEGNPE (1) + 2-propanol (2)	78
4-10	Activities of methanol in PEGOPE at various temperatures	82
4-11	Activities of ethanol in PEGOPE at various temperatures	83
4-12	Activities of 2-propanol in PEGOPE at various temperatures	84
4-13	Activities of methanol in PEGNPE at various temperatures	85
4-14	Activities of ethanol in PEGNPE at various temperatures	86
4-15	Activities of 2-propanol in PEGNPE at various temperatures	87
4-16	Activities of methanol in PEGOPE and PEGNPE at 353.2 K	88
4-17	Activities of ethanol in PEGOPE and PEGNPE at 353.2 K	89
4-18	Activities of 2-propanol in PEGOPE and PEGNPE at 353.2 K	90

                                

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