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研究生: 葉旭翔
Hsu-Shiang Yeh
論文名稱: 以固相觸媒合成丙二醇甲醚醋酸酯之反應動力行為研究
Study on Reaction Kinetics of Synthesis of Propylene Glycol Methyl Ether Acetate with Using Heterogeneous Catalyst
指導教授: 曾堯宣
Yao-Hsuan Tseng
口試委員: 曾堯宣
蘇子森
何郡軒
胡哲嘉
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2023
畢業學年度: 112
語文別: 中文
論文頁數: 66
中文關鍵詞: 丙二醇甲醚醋酸酯酯化反應固體酸性觸媒
外文關鍵詞: Propylene glycol methyl ether acetate, Esterification, Heterogeneous acidic catalyst
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  • 摘要 IV Abstract VI 致謝 VIII 目錄 X 第一章 緒論 1 1.1 前言 1 1.2 液相觸媒與固相觸媒 2 1.3 丙二醇甲醚簡介 3 1.4 醋酸簡介 3 1.5 丙二醇甲醚醋酸酯簡介 4 1.6 研究動機 4 第二章 文獻回顧 6 2.1 酯化反應 6 2.2 反應性蒸餾 11 第三章 實驗方法與步驟 13 3.1 實驗設計 13 3.2 實驗藥品與實驗觸媒 15 3.2.1 實驗藥品 15 3.3 實驗設備與分析儀器 16 3.3.1 實驗設備 16 3.3.2 分析儀器 17 3.3.3 GC-FID結果 19 3.3.4 震盪恆溫系統 21 3.3.5 三頸瓶批式系統 22 3.3.6 連續式系統 23 3.4 實驗步驟 24 3.4.1 震盪恆溫實驗 24 3.4.2 三頸瓶批式實驗 24 3.4.3 連續式固定床實驗 25 第四章 結果與討論 26 4.1 震盪恆溫實驗 26 4.1.1 觸媒耐受性測試 26 4.1.2 副產物生成機制推導 31 4.1.3 觸媒活性 33 4.2 批式系統 34 4.2.1 溫度對反應速率的影響 34 4.2.2 觸媒用量對反應速率的影響 36 4.2.3 平衡常數 37 4.3 連續式固定床系統 38 4.3.1 莫耳進料比對產率的影響 38 4.3.2 進料流速對產率的影響 40 4.3.3 熱力學動力模式 41 第五章 結論與未來展望 46 5.1 結論 46 5.1.1 震盪恆溫實驗 46 5.1.2 批式系統 46 5.1.3 連續式固定床系統 47 5.2 未來展望 48 參考文獻 50

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