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研究生: 謝超恩
Chao-en Hsieh
論文名稱: 光電污泥中稀有金屬元素結合型態與生物有效性分析之研究
The analysis of associated state and bioavailability of rare metal elements in TFT-LCD waste sludge
指導教授: 劉志成
Jhy-chern Liu
口試委員: 李奇旺
Chi-wang Li
宋孟浩
Meng-hau Sung
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2011
畢業學年度: 99
語文別: 英文
論文頁數: 112
中文關鍵詞: 連續萃取污泥生物有效性薄膜液晶顯示器稀有元素
外文關鍵詞: Bioavailability, rare metal, sequential extraction, sludge, TFT-LCD
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薄膜液晶顯示器工業產生的汙泥中含有一定量的稀有元素,如鉭、鉬、鍶、銦等。這些稀有元素具有特殊特性與毒性,於污泥的再利用或最終處置過程中可能造成環境與人體危害。此研究的目的為透過連續萃取實驗與生物有效性分析來了解稀有元素在污泥中的型態,並評估其在環境中的釋放行為。連續萃取實驗結果顯示鉬與鍶在汙泥中屬於不易流動型態,而銦與鉭則是趨向於流動型態。而生物有效性分析結果也顯示鉬與鍶屬於低生物可利用性,而銦具有生物可利用性。而在鉭的部份,則是發現二乙烯三胺五乙酸(DTPA)與乙二胺四乙酸(EDTA)對與鉭之萃取效率不佳。硝酸萃取實驗結果顯示,鍶與銦的萃取率達80%,鉬為50%,鉭約10%。


The inorganic sludge from thin-film transistor liquid crystal display (TFT-LCD) industry contains significant levels of rare elements, such as tantalum, molybdenum, strontium and indium. This study investigated the associated speciation and bioavailability of rare elements in TFT-LCD inorganic sludge. The sequential extraction results indicated that strontium and molybdenum were of immobile form, while tantalum and indium were relatively mobile. The bioavailability analysis results also showed that strontium and molybdenum were not bioavailable, and indium was potentially available for plant uptake. However, the bioavailability of tantalum by DTPA/EDTA method may not be suitable, and it deserves further research to find appropriate chemicals for tantalum. The nitric acid extraction results showed that leaching percentage of strontium and indium were nearly 80%, 50% for molybdenum, and 10% for tantalum.

中文摘要 I ABSTRACT III ACKNOWLEDGEMENT IV Chapter 1 1 1.1 Background 1 1.2 Objectives 2 Chapter 2 3 2.1 TFT-LCD industry 3 2.1.1 Rare metals in TFT-LCD industry 5 2.1.2 TFT-LCD waste water and sludge 12 2.2 Bioavailability of metals 12 2.3 Sequential extraction procedure 16 Chapter 3 22 3.1 Source of TFT-LCD sludge 22 3.2 Materials 22 3.3 Equipments and instruments 25 3.4 Experiment procedure 26 3.4.1 Pretreatment of TFT-LCD sludge 27 3.5 Characterization analysis of sludge 27 3.5.1 Total metal content - Aqua-regia digestion (NIEA S321.63B) 27 3.5.2 Water content-weight method (NIEA S280.61C) 28 3.5.3 Standard method - organic carbon 28 3.5.4 Total solid (TS), Fixed Solid (FS) and Volatile solid (VS) (NIEA R212.00C) 29 3.5.5 X-ray diffraction 30 3.5.6 Field emission scanning electron microscopy (FESEM) and energy dispersive X-ray spectrometer (EDX) analysis 30 3.6 Sequential Extraction procedure 31 3.7 Bioavailability analysis 32 3.7.1 Diethylenetriamine pentaacetic acid (DTPA) extraction test 32 3.7.2 Ethylene diamine tetraacetic acid (EDTA) extraction test 32 3.8 Acid extraction test 32 Chapter 4 34 4.1 The characteristic of TFT-LCD sludge 34 4.1.1 Total metal content 34 4.1.2 XRF results 35 4.1.3 SEM-EDX results 36 4.1.4 XRD results 36 4.2 Sequential extraction results 47 4.2.1 Chemical speciation of rare metals in first sludge sample 47 4.2.2 Chemical speciation of rare metals in second sludge sample 49 4.2.3 Chemical speciation of rare metals in third sludge sample 50 4.3 Bioavailability of rare metals in TFT-LCD sludge 59 4.4 Nitric acid extraction test 62 Chapter 5 68 5.1 Conclusions 68 5.2 Suggestions 69 Reference 71 Appendix A 84 Appendix B 90 Appendix C 93

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