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研究生: 陳奕愷
Yi-Kai Chen
論文名稱: 由2,2'-bis(2,2'-bipyridinyl)-4,4'-oxydianiline合成聚醯亞胺及其性質探討
Synthesis and Properties of Polyimides Derived from 2,2'-bis(2,2'-bipyridinyl)-4,4'-oxydianiline
指導教授: 陳志堅
Jyh-Chien Chen
口試委員: 陳志堅
Jyh-Chien Chen
游進陽
Chin-Yang Yu
李世偉
Shih-Wei Lee
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 73
中文關鍵詞: 聚醯亞胺合成溶解度
外文關鍵詞: polyimide, synthesis, solubility
相關次數: 點閱:379下載:0
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摘要 I Abstract II 目錄 III Figure 索引 V Scheme 索引 VII Table 索引 VIII 一、緒論 1 1.1 前言 1 1.2 聚醯亞胺簡介 2 1.3 聚醯亞胺軟性印刷電路板 4 1.3.1 聚醯亞胺軟性印刷電路板簡介 4 1.3.2 聚醯亞胺之無電鍍鎳 6 1.3.2.1 無電鍍鎳簡介 6 1.3.2.2 無電鍍鎳溶液 6 1.3.2.3 無電電鍍文獻回顧 8 1.3.3 聚醯亞胺與含氮基團 12 1.4 4,4’-ODA為起始物之聚醯亞胺 17 1.5 研究動機 18 二、實驗 19 2.1 實驗藥品 19 2.2 實驗設備及儀器 21 2.3 單體合成 22 2.4 高分子之合成以及薄膜製備 27 三、結果與討論 28 3.1 單體的合成 28 3.1.1 5-Bromo-2,2'-bipyridine (3)之合成與性質表徵 29 3.1.2 2,2’-Bipyridin-5-ylboronic acid (4)之合成與性質表徵 32 3.1.3 2,2’-Bis(2,2’-bipyridinyl)-4,4’-dinitrodiphenylether (5)之合成與性質表徵 35 3.1.4 2,2'-Bis(2,2’-bipyridinyl)-4,4'-oxydianiline (6)之合成與性質表徵 41 3.2 高分子的合成與表徵 44 3.3 聚醯亞胺之分子量與溶解度 46 3.4聚醯亞胺之紅外光光譜(FT-IR) 48 3.5 聚醯亞胺之熱性質 49 四、結論 54 參考文獻 55

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