研究生: |
李美英 Liliana-Theresia |
---|---|
論文名稱: |
Composite Coating Performance on Bendable Cellulose-based Electrode for Supercapacitor Composite Coating Performance on Bendable Cellulose-based Electrode for Supercapacitor |
指導教授: |
今榮東洋子
Tokoyo Imae |
口試委員: |
氏原真樹
Masaki-Ujihara 蘇威年 Wei-Nien Su |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2019 |
畢業學年度: | 107 |
語文別: | 英文 |
論文頁數: | 63 |
中文關鍵詞: | 柔性電擊超級電容器 |
外文關鍵詞: | Composite Coating Performance on Bendable Cellulose-based Electrode for Supercapacitor |
相關次數: | 點閱:236 下載:0 |
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TEMPO(四甲基哌啶氧化物)氧化的奈米纖維(TOCNF)由從未乾燥的紙漿製備,藉由氧化還原反應和超聲處理。在TOCNF膜表面上塗覆還原的氧化石墨烯和聚苯胺的導電材料來製備柔性電極。
通過循環伏安法(CV)、恆電流充放電(GCD)和電化學阻抗(EIS),獲得三電極系統下的電化學數據在1MNaCl溶液中。將僅使用還原的氧化石墨烯(rGO-P0)塗覆的電極與塗覆有還原的氧化石墨烯和聚苯胺(rGO-P3)的電極進行比較。
rGO-P3的5mV /s掃描速率下的CV比電容明顯優於rGO-P0。同時,0.5 A / g的GCD比電容也表明rGO-P3特定電容高於rGO-P0。在運行3000次循環後,rGO-P0和rGO-P3的電容保持率分別為98.7%和98.1%(其初始比電容)。還對電極rGO-P3進行彎曲試驗,其中發現電容保持率為75.2%
In this thesis, I want to express my gratitude to a lot of people who helped me during the Master study.
Firstly, I would like to thank my supervisor for two years, Prof. Toyoko Imae. Thank you for accepting me as your student and giving me chance to work under your supervision. Without your support and advice, I may not reach this point where I stand today. It was not always easy, but I believe these two years have shaped me to a better person.
I also would like to thank my family, who has given me endless support for my study even if we are far apart. I learned to take responsibility for my own well-being and my decision to study far away from my home country. So I was able to gain strength and not give up until I can prove my decision was worth the struggles.
I want to thank my boyfriend, for his continuous cheer and support in times of grief and joy. Thank you for always being there.
My friends and roommates in room 407, thank you for moments of laughter and joy we have shared during these two years.
At last, I would like to appreciate laboratory members who have contributed in my two years study in NTUST. Thanks to Mark, Edo, Strong, Andree, Joe, Shannon, Erik, Mahmoud, Kukuh, Juwita, Kevin, Derek, Mule, and other members who have helped me in lab. For those who already graduated, I hope you can be successful in your future endeavors. For those who are still preparing to graduate, I hope you can finish on time and move on to bigger goals in your life.
1. Du Pasquier, A., Plitz, I., Menocal, S., and Amatucci, G., A comparative study of Li-ion battery, supercapacitor and nonaqueous asymmetric hybrid devices for automotive applications. Journal of Power Sources, 2003. 115(1): p. 171-178.
2. Pollet, B.G., I. Staffell, and J.L. Shang, Current status of hybrid, battery and fuel cell electric vehicles: From electrochemistry to market prospects. Electrochimica Acta, 2012. 84: p. 235-249.
3. Shukla, A.K., S. Sampath, and K. Vijayamohanan, Electrochemical supercapacitors: Energy storage beyond batteries. Current Science, 2000. 79(12): p. 1656-1661.
4. Kötz, R. and M. Carlen, Principles and applications of electrochemical capacitors. Electrochimica acta, 2000. 45(15-16): p. 2483-2498.
5. Simon, P. and Y. Gogotsi, Materials for electrochemical capacitors, in Nanoscience and Technology. 2009, Co-Published with Macmillan Publishers Ltd, UK. p. 320-329.
6. Wang, G., L. Zhang, and J. Zhang, A review of electrode materials for electrochemical supercapacitors. Chemical Society Reviews, 2012. 41(2): p. 797-828.
7. Burke, A., Ultracapacitors: why, how, and where is the technology. Journal of power sources, 2000. 91(1): p. 37-50.
8. Ji, H., Zhao, X., Qiao, Z., Jung, J., Zhu, Y., Lu, Y., Zhang, L.L., MacDonald, A.H., and Ruoff, R.S., Capacitance of carbon-based electrical double-layer capacitors. Nature communications, 2014. 5: p. 3317.
9. Lazzari, M., F. Soavi, and M. Mastragostino, High voltage, asymmetric EDLCs based on xerogel carbon and hydrophobic IL electrolytes. Journal of Power Sources, 2008. 178(1): p. 490-496.
10. Arbizzani, C., M. Mastragostino, and F. Soavi, New trends in electrochemical supercapacitors. Journal of power sources, 2001. 100(1-2): p. 164-170.
11. Qu, D. and H. Shi, Studies of activated carbons used in double-layer capacitors. Journal of Power Sources, 1998. 74(1): p. 99-107.
12. Chen, X., R. Paul, and L. Dai, Carbon-based supercapacitors for efficient energy storage. National Science Review, 2017. 4(3): p. 453-489.
13. Ryu, K.S., Kim, K.M., Park, N.G., Park, Y.J., and Chang, S.H., Symmetric redox supercapacitor with conducting polyaniline electrodes. Journal of Power Sources, 2002. 103(2): p. 305-309.
14. Wang, Y., Y. Song, and Y. Xia, Electrochemical capacitors: mechanism, materials, systems, characterization and applications. Chemical Society Reviews, 2016. 45(21): p. 5925-5950.
15. Yoon, Y., K. Lee, and H. Lee, Low-dimensional carbon and MXene-based electrochemical capacitor electrodes. Nanotechnology, 2016. 27(17): p. 172001.
16. Pushparaj, V.L., Shaijumon, M.M., Kumar, A., Murugesan, S., Ci, L., Vajtai, R., Linhardt, R.J., Nalamasu, O., and Ajayan, P.M., Flexible energy storage devices based on nanocomposite paper. Proceedings of the National Academy of Sciences, 2007. 104(34): p. 13574-13577.
17. Kaempgen, M., Chan, C.K., Ma, J., Cui, Y., and Gruner, G., Printable thin film supercapacitors using single-walled carbon nanotubes. Nano letters, 2009. 9(5): p. 1872-1876.
18. Rezanezhad, S., N. Nazanezhad, and G. Asadpur, Isolation of nanocellulose from rice waste via ultrasonication. Journal of Lignocellulose, 2013. 2(1).
19. Gao, K., Shao, Z., Wu, X., Wang, X., Li, J., Zhang, Y., Wang, W., and Wang, F., Cellulose nanofibers/reduced graphene oxide flexible transparent conductive paper. Carbohydrate polymers, 2013. 97(1): p. 243-251.
20. Zhu, H., Fang, Z., Preston, C., Li, Y., and Hu, L., Transparent paper: fabrications, properties, and device applications. Energy & Environmental Science, 2014. 7(1): p. 269-287.
21. Unnikrishnan, B., Wu, C.W., Chen, I.W.P., Chang, H.T., Lin, C.H., and Huang, C.C., Carbon dot-mediated synthesis of manganese oxide decorated graphene nanosheets for supercapacitor application. ACS Sustainable Chemistry & Engineering, 2016. 4(6): p. 3008-3016.
22. Liu, W., Li, C., Ren, Y., Sun, X., Pan, W., Li, Y., Wang, J., and Wang, W., Carbon dots: surface engineering and applications. Journal of Materials Chemistry B, 2016. 4(35): p. 5772-5788.
23. Zhang, X., Wang, J., Liu, J., Wu, J., Chen, H., and Bi, H., Design and preparation of a ternary composite of graphene oxide/carbon dots/polypyrrole for supercapacitor application: Importance and unique role of carbon dots. Carbon, 2017. 115: p. 134-146.
24. Yin, S., Goldovsky, Y., Herzberg, M., Liu, L., Sun, H., Zhang, Y., Meng, F., Cao, X., Sun, D.D., and Chen, H., Functional Free‐Standing Graphene Honeycomb Films. Advanced Functional Materials, 2013. 23(23): p. 2972-2978.
25. Stenger-Smith, J.D., Webber, C.K., Anderson, N., Chafin, A.P., Zong, K., and Reynolds, J.R., Poly (3, 4-alkylenedioxythiophene)-based supercapacitors using ionic liquids as supporting electrolytes. Journal of the Electrochemical Society, 2002. 149(8): p. A973-A977.
26. Nikolou, M., Dyer, A.L., Steckler, T.T., Donoghue, E.P., Wu, Z., Heston, N.C., Rinzler, A.G., Tanner, D.B., and Reynolds, J.R., Dual n-and p-type dopable electrochromic devices employing transparent carbon nanotube electrodes. Chemistry of Materials, 2009. 21(22): p. 5539-5547.
27. Jiang, Z., Zhao, X., Tian, X., Luo, L., Fang, J., Gao, H., and Jiang, Z.J., Hydrothermal synthesis of boron and nitrogen codoped hollow graphene microspheres with enhanced electrocatalytic activity for oxygen reduction reaction. ACS applied materials & interfaces, 2015. 7(34): p. 19398-19407.
28. Wang, M., Wang, J., Hou, Y., Shi, D., Wexler, D., Poynton, S.D., Slade, R.C.T., Zhang, W., Liu, H., and Chen, J., N-doped crumpled graphene derived from vapor phase deposition of PPy on graphene aerogel as an efficient oxygen reduction reaction electrocatalyst. ACS applied materials & interfaces, 2015. 7(13): p. 7066-7072.
29. Snook, G.A., P. Kao, and A.S. Best, Conducting-polymer-based supercapacitor devices and electrodes. Journal of Power Sources, 2011. 196(1): p. 1-12.
30. Chandrakanthi, N. and M. Careem, Thermal stability of polyaniline. Polymer Bulletin, 2000. 44(1): p. 101-108.
31. Hu, X., Johannesson, L., Murgovski, N., and Egardt, B., Longevity-conscious dimensioning and power management of the hybrid energy storage system in a fuel cell hybrid electric bus. Applied Energy, 2015. 137: p. 913-924.
32. Jillek, W. and W. Yung, Embedded components in printed circuit boards: a processing technology review. The International Journal of Advanced Manufacturing Technology, 2005. 25(3-4): p. 350-360.
33. Thounthong, P., S. Rael, and B. Davat, Energy management of fuel cell/battery/supercapacitor hybrid power source for vehicle applications. Journal of Power Sources, 2009. 193(1): p. 376-385.
34. Pay, S. and Y. Baghzouz. Effectiveness of battery-supercapacitor combination in electric vehicles. in Power Tech Conference Proceedings, 2003 IEEE Bologna. 2003. IEEE.
35. Shahparnia, S. and O.M. Ramahi, Electromagnetic interference (EMI) reduction from printed circuit boards (PCB) using electromagnetic bandgap structures. IEEE Transactions on Electromagnetic Compatibility, 2004. 46(4): p. 580-587.
36. Poulin, G., E. Sarraute, and F. Costa, Generation of electrical energy for portable devices: Comparative study of an electromagnetic and a piezoelectric system. Sensors and Actuators A: physical, 2004. 116(3): p. 461-471.
37. Beidaghi, M. and Y. Gogotsi, Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors. Energy & Environmental Science, 2014. 7(3): p. 867-884.
38. Ibrahim, K.A., Synthesis and characterization of polyaniline and poly(aniline-co-o-nitroaniline) using vibrational spectroscopy. Arabian Journal of Chemistry, 2017. 10: p. S2668-S2674.
39. Yu, A., V. Chabot, and J. Zhang, Electrochemical supercapacitors for energy storage and delivery: fundamentals and applications. 2013: CRC Press.
40. Manikandan, M., Dhanuskodi, S., Maheswari, N., Muralidharan, G., Revathi, C., Kumar, R.T.R., and Rao, G.M., High performance supercapacitor and non-enzymatic hydrogen peroxide sensor based on tellurium nanoparticles. Sensing and Bio-Sensing Research, 2017. 13: p. 40-48.
41. Conway, B.E., Electrochemical supercapacitors: scientific fundamentals and technological applications. 2013: Springer Science & Business Media.
42. Senthilkumar, S.T., Selvan, R.K., Lee, Y.S., and Melo, J.S., Electric double layer capacitor and its improved specific capacitance using redox additive electrolyte. Journal of Materials Chemistry A, 2013. 1(4): p. 1086-1095.
43. Xing, Z., Xing, Z., Ju, Z., Zhao, Y., Wan, J., Zhu, Y., Qiang, Y., and Qian, Y., One-pot hydrothermal synthesis of Nitrogen-doped graphene as high-performance anode materials for lithium ion batteries. Scientific reports, 2016. 6: p. 26146.
44. Li, Y., Zhang, B.P., Zhao, J.X., Ge, Z.H., Zhao, X.K., and Zou, L., ZnO/carbon quantum dots heterostructure with enhanced photocatalytic properties. Applied Surface Science, 2013. 279: p. 367-373.