本研究由主鏈與側鏈上具有金剛烷之磷酸鹽單體與二醛，聚合出
一系列含金剛烷之PPV 高分子。含金剛烷之PPV 高分子其數目平均
分子量(Mn)範圍在2274∼3976 之間，這些含金剛烷之PPV 高分子對
於一般有機溶劑具有好的溶解度，可溶於N-Methyl-2-pyrrolidone
(NMP)、o-chlorophenol、m-cresol、N,N'-dimethylacetamide (DMAc)、
tetrahydrofuran(THF)、cyclohexanone 與chloroform 等溶劑，而它們的
的10％熱重損失之溫度範圍在366∼430 ℃，也顯示所有高分子雖然
含脂肪族金剛烷基團，仍維持好的熱安定性。
經由UV-vis 光譜顯示，含金剛烷之PPV 高分子在溶液狀態下之
最大吸收波長在240∼276 nm 之間；在薄膜的狀態下，相較於溶液的
狀態，有些許紅移的產生。經由UV 起始吸收波長(λonset)所得之能隙
(Eg)範圍在2.86∼3.50 eV 之間。經由PL 光譜顯示，P1 在溶液的狀
態下，可發出波長為490 nm 之藍光；P4 在薄膜的狀態下可以發出波
長為460 nm 之藍光。
最後，藉由循環伏安計量法(CV)探討電化學性質，發現含金剛烷
之PPV 高分子之HOMO 能階範圍在-6.01∼-5.54 eV；LUMO 能階在
-3.15∼-2.04 eV 之間。

A new series of adamantane-based poly(phenylene vinylene) were
synthesized by reacting of adamantane-containing phosphonium salt with
two dialdehydes which contained carbazole and trifluoromethyl unit.
Those polymers had number-average molecular weight(Mn) of 2274∼
3976. Most of the polymers possessed good solubility in common organic
solvents such as N-Methyl-2-pyrrolidone(NMP), o-chlorophenol,
m-cresol, N,N'-dimethylacetamide(DMAc), tetrahydrofuran(THF),
cyclohexanone and chloroform. The temperatures of the polymers at 10％
weight loss in nitrogen ranged from 366∼430℃ and revealed that all the
polymers had good thermal stability by introducing adamantly group in
polymer main chain and side chain.
In the UV-vis spectra, those polymers had strong absorption bands
from 240∼276 nm in solution state and the absorption bands in the solid
state were slightly red-shifted comparing to the solution state. The energy
band gaps(Eg) of the polymers calculated from the onset absorption
wavelength of UV spectra in solution state were in the range from 2.86∼
3.50 eV. In the photoluminescence spectra, P1 exhibited blue emission at
490 nm in solution state and P4 emitted blue light at 460 nm in solid
state.
In addition, cyclic voltammetry(CV) was employed to investigate the
electrochemical behaviors of polymer synthesized. The results showed
that the HOMO and LUMO energy levels of the polymers are in the
range from -6.01∼-5.54 eV and -3.15∼-2.04 eV, respectively.

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