研究生: |
Iqbaal Abdurrokhman Iqbaal - Abdurrokhman |
---|---|
論文名稱: |
含Good’s 緩衝劑離子液體[TBP][TAPS]雙成分混合物的熱物性質研究 Thermophysical Properties of Binary Mixtures Containing Good’s Buffer Ionic Liquid [TBP][TAPS] |
指導教授: |
李 明 哲
Ming-Jer Lee |
口試委員: |
陳 立 仁
Li-Jen Chen 陳 良 益 Liang-Yih Chen |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2016 |
畢業學年度: | 104 |
語文別: | 英文 |
論文頁數: | 107 |
外文關鍵詞: | [TBP][TAPS], Good's Buffer Ionic Liquid |
相關次數: | 點閱:191 下載:2 |
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A novel ionic liquid [TBP][TAPS] derived from basic hydroxide solution tetra-n-butylphosponium ([TBP][OH], 40 wt% in H2O) and Good’s biological buffer n-[tris(hydroxymethyl)]-3-amino-propanesulfonic acid has been synthesized by simple acid-base neutralization method.
The physical properties, including density, thermal expansion, apparent molar volume, viscosity, conductivity, and molar conductivity have been determined for the binary ionic solutions of [TBP][TAPS] with water, methanol, ethanol, 1-propanol, 2-propanol, or tert-butanol at temperatures from 283.15 K to 333.15 K under atmospheric pressure. Several correlative equations were used to fit the physical properties data. These models include a polynomial equation for density, the Vogel-Fulcher-Tammann equation for viscosity, and the Casteel-Amis equation for conductivity. The correlated results are satisfactory.
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