研究生: |
戴智為 Jhih-Wei Dai |
---|---|
論文名稱: |
天然橡膠與丁腈橡膠對於氫氧化四甲基銨抗滲透性的研究 The Permeation of Tetramethyl Ammonium Hydroxide Through Natural Rubber and Nitrile Glove Materials |
指導教授: |
蘇清淵
Ching-Iuan Su |
口試委員: |
張振平
Jhen-Ping Jhang 楊銘乾 Ming-Chien Yang 王英靖 Ying-Jing Wang |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2009 |
畢業學年度: | 97 |
語文別: | 中文 |
論文頁數: | 81 |
中文關鍵詞: | 抗滲透性 、防護材料 、氫氧化四甲基銨 |
外文關鍵詞: | Protective materials, Permeability resistance, TMAH |
相關次數: | 點閱:274 下載:1 |
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氫氧化四甲基銨 (Tetramethyl Ammonium Hydroxide, TMAH)目前大量使用在半導體與光電等高科技產業中。本研究主要目的為,探討橡膠防護材料對TMAH的抗滲透防護性能的影響。
研究結果發現,NR防護手套與Nitrile防護手套對低濃度2.38%TMAH防護性能明顯優於高濃度25%TMAH;環境溫度23℃下,NR防護手套和Nitrile防護手套對濃度25%TMAH平均破出時間分別為90.93分鐘及801.67分鐘,而在環境溫度達35℃下,NR防護手套與Nitrile防護手套破出時間平均下降24%和43%,溫度升高顯然使橡膠防護手套之防護效能有相當程度下降的情形;採用雙層橡膠防護手套情況下,在環境溫度23℃時,雙層NR防護手套對濃度25%TMAH平均破出時間長達1592.8分鐘;橡膠材料浸水後則會影響橡膠材料抗滲透性質,使破出時間減少,特別值得注意的是, Nitrile防護手套材料放置於外層搭配NR防護手套材料放置於內層(Nitrile / NR)之平均破出時間長達2033.2分鐘,兩種橡膠防護手套穿戴順序正確則能有效阻隔TMAH滲透性,此為本研究最佳結果。
At present, Tetramethyl Ammonium Hydroxide (TMAH) has been used in large amounts in high-tech industries, such as semiconductor industry and optoelectronics industry. This study aimed to discuss the permeation prevention performance of rubber protective materials against TMAH.
The results indicated that, the protective performances of NR protective glove and Nitrile protective glove are better against low-concentration 2.38% TMAH than against high-concentration 25% TMAH. When the ambient temperature is 23℃, the average breakthrough times of NR protective glove and Nitrile protective glove against 25% TMAH are 90.93 minutes and 801.67 minutes respectively; when the ambient temperature reaches 35℃, the average breakthrough times fall by 24% and 43% respectively; therefore, the temperature rise degenerates the protective effect to a considerable extent. If double-layer gloves are used, when the ambient temperature is 23℃, the average breakthrough time against 25% TMAH is as long as 1,592.8 minutes. After being dipped in water, the permeation prevention performance of rubber materials may be affected so that the breakthrough time becomes less. It is important to note that the average breakthrough time reaches 2,033.2 minutes for the combination with Nitrile protective gloves outside and NR gloves inside. The correct arrangement of the two kinds of protective gloves can effectively prevent the permeation of TMAH. This is the best result achieved in this study.
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