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研究生: 林孟軒
Meng-xuan Lin
論文名稱: 雷射激發單晶螢光晶體發光行為之探討
Study of the Fluorescence Behavior of Single Crystal Phosphor Excited by Laser
指導教授: 李宗憲
Tsung-Xian Lee
口試委員: 李宗憲
馬仕信
蘇忠傑
學位類別: 碩士
Master
系所名稱: 應用科技學院 - 色彩與照明科技研究所
Graduate Institute of Color and Illumination Technology
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 60
中文關鍵詞: 藍光雷射二極體單晶螢光晶體熱淬滅布魯斯特角
外文關鍵詞: Blue laser diode, Single crystal phosphor, Thermal quenching, Brewster’s angle
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  • 多篇文獻指出,高功率藍光雷射激發螢光物質時,被照射區域會產生極高的溫度,使螢光物質發生熱淬滅現象,因此搭配雷射光源的螢光物質需要具備在高溫下還可保持一定的光轉換效率的特性,單晶螢光晶體就是其中一種具備以上特性的螢光物質之一。單晶螢光晶體具有極高的熱穩定性和光轉換效率,非常適合搭配高功率藍光雷射,在未來雷射白光照明應用扮演關鍵角色。然而單晶螢光晶體的折射率高於目前螢光粉封裝用的矽膠折射率,導致單晶螢光晶體的介面反射高於傳統螢光片,且單晶螢光晶體表面光滑、透明度高,使入射且未被吸收的藍光直接穿透而不會在內部發生散射,導致單晶螢光晶體的藍光光源利用率低於傳統螢光片。
    本論文針對單晶螢光晶體探討其轉換效率、光源利用率、溫度及不同入射面對螢光特性的影響,並提出利用布魯斯特角解決單晶螢光晶體因折射率過高導致的高反射率,經實驗後發現,此方法可有效的提升藍光雷射光源的利用率,將藍光光源的利用率提升至接近100%。


    More paper points out that high power blue laser diode excitation fluorescence material, illumination area will produce high temperature, thermal quenching phenomenon in the phosphor material, therefore with laser light source of phosphor material need to be at high temperatures can also maintain the characteristics of light conversion efficiency, the single crystal phosphor is one of the above characteristics of one of the phosphor material. Single crystal phosphor with high thermal stability and optical conversion efficiency are ideal for high-power blue lasers, which will play a key role in future laser white lighting applications. However single crystal phosphor refractive index is higher than the phosphor powder encapsulation of silicone refractive index, and lead to the single crystal phosphor interface reflection is higher than conventional fluorescence, and the single crystal phosphor surface is smooth, high transparency, the incidence and blue which are not absorbed directly through without scattering in internal, lead to the single crystal phosphor blue light utilization ratio is lower than traditional phosphor.
    This paper in view of the single crystal phosphor to explore its conversion efficiency, the utilization rate of light, temperature and the influence of different incident in the face of the fluorescence characteristics, and put forward by using brewster Angle to solve the single crystal phosphor of high reflectivity, as a result of high refractive index by experiment and found that this method can effectively improve the utilization rate of blue laser light source, will increase the utilization ratio of blue light to near 100%.

    中文摘要 i Abstract ii 致謝 iii 目錄 iv 圖目錄 vi 表目錄 ix 第一章 緒論 1 1.1 研究背景 1 1.2 研究動機及目的 3 1.3 論文大綱及架構 4 第二章 文獻探討 6 2.1 雷射白光照明 6 2.2 螢光粉熱淬滅現象 9 2.3 單晶螢光晶體的特性 14 第三章 單晶螢光晶體吸收轉換特性分析 19 3.1 單晶螢光晶體激發、發射光譜之量測 19 3.2 不同入射面對單晶螢光晶體吸收轉換特性的影響 21 3.3 不同入射面對單晶螢光晶體螢光特性的影響 23 第四章 單晶螢光晶體熱淬滅效應分析 29 4.1 溫度對單晶螢光晶體穿透及反射的影響 29 4.2 溫度對單晶螢光晶體激發效率的影響 33 第五章 雷射偏振效應入射單晶螢光晶體之特性分析 37 5.1 雷射偏振角度對單晶螢光晶體光源反射率的影響 37 5-2 雷射偏振角度對激發單晶螢光晶體的影響 40 第六章 結論 44 參考文獻 45

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    [24] FluoroMaxPlus,https://www.horiba.com/en_en/products/detail/action/show/Product/fluoromax-1576/
    [25] THORLABS-M100D, https://www.thorlabs.com/thorproduct.cfm?partnumber=PM100D
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