簡易檢索 / 詳目顯示

研究生: 楊家睿
Jia-Ruei Yang
論文名稱: 藉由靜電自組裝兩性離子做為界面修飾層應用於可撓式奈米摩擦發電機
Electrostatically Self-assembled Zwitterion as Surface Modification Layer for Flexible Triboelectric Nanogenerator
指導教授: 張志宇
Chih-Yu Chang
口試委員: 林宗宏
Zong-Hong Lin
胡孝光
Shiaw-Guang Hu
許昕
Hsin Hsiu
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 85
中文關鍵詞: 奈米摩擦發電機界面修飾層靜電自組裝兩性離子
外文關鍵詞: triboelectric nanogenerator, surface modification layer, electrostatic self-assembly, zwitterionic molecule
相關次數: 點閱:238下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報


致謝 I 摘要 II Abstract III 圖目錄 VII 表目錄 XIII 第一章 緒論 1 1.1 前言 1 1.2 研究動機與目的 5 第二章 文獻回顧 6 2.1 奈米摩擦發電機發展簡介 6 2.2可撓式奈米摩擦發電機 11 2.3 奈米摩擦發電機作用機制 14 2.4 表面改質應用於奈米摩擦發電機 16 2.4.1 物理表面改質方法 17 2.4.2 化學表面改質方法 18 2.5 兩性離子薄膜簡介 24 第三章 實驗步驟與分析 26 3.1 實驗設計 26 3.2 元件製備 27 3.2.1 材料準備 27 3.2.2 基板清洗流程 27 3.2.3 PDMS薄膜製備流程及鹼處理 28 3.2.4 PEDOT:PSS 電極製備流程 28 3.2.5 靜電自組裝界面修飾層製備流程 28 3.2.6 奈米摩擦發電機元件分析與量測 29 第四章 實驗結果與討論 30 4.1 NDSB-195修飾PDMS成效 30 4.1.1 NDSB-195修飾PDMS表面化學表徵 30 4.1.2 NDSB-195 修飾 PDMS薄膜元件電性測量 31 4.1.3 NDSB-195 修飾 PDMS薄膜表面形貌分析 37 4.1.4 NDSB-195 修飾 PDMS薄膜表面電性分析 40 4.2 NDSB-195 修飾PEDOT:PSS電極成效 42 4.2.1 NDSB-195 修飾 PEDOT:PSS電極元件電性測量 42 4.2.2 NDSB-195 修飾 PEDOT:PSS電極表面形貌分析 47 4.2.3 NDSB-195 修飾 PEDOT:PSS電極表面電性分析 49 4.3 基於NDSB-195修飾PDMS和PEDOT:PSS元件電性測量及應用 51 4.4 元件穩定度測試 57 第五章 結論 60 參考文獻 61

[1] M. Burhan, R. A. Rehman, B. Khan, and B.-S. Kim, "IoT Elements, Layered Architectures and Security Issues: A Comprehensive Survey," Sensors, vol. 18, no. 9, p. 2796, 2018.
[2] S. Chen, H. Xu, D. Liu, B. Hu, and H. Wang, "A Vision of IoT: Applications, Challenges, and Opportunities With China Perspective," IEEE Internet of Things Journal, vol. 1, no. 4, pp. 349-359, 2014.
[3] T. G. Stavropoulos, A. Papastergiou, L. Mpaltadoros, S. Nikolopoulos, and I. Kompatsiaris, "IoT Wearable Sensors and Devices in Elderly Care: A Literature Review," Sensors, vol. 20, no. 10, p. 2826, 2020.
[4] W.-G. Kim, D.-W. Kim, I.-W. Tcho, J.-K. Kim, M.-S. Kim, and Y.-K. Choi, "Triboelectric Nanogenerator: Structure, Mechanism, and Applications," ACS Nano, vol. 15, no. 1, pp. 258-287, 2021/01/26 2021.
[5] Z. L. Wang, "On Maxwell's displacement current for energy and sensors: the origin of nanogenerators," Materials Today, vol. 20, no. 2, pp. 74-82, 2017/03/01/ 2017.
[6] Q. Shi, T. He, and C. Lee, "More than energy harvesting – Combining triboelectric nanogenerator and flexible electronics technology for enabling novel micro-/nano-systems," Nano Energy, vol. 57, pp. 851-871, 2019/03/01/ 2019.
[7] C. Wu, A. C. Wang, W. Ding, H. Guo, and Z. L. Wang, "Triboelectric Nanogenerator: A Foundation of the Energy for the New Era," Advanced Energy Materials, vol. 9, no. 1, p. 1802906, 2019/01/01 2019.
[8] C. Han, C. Zhang, W. Tang, X. Li, and Z. L. Wang, "High power triboelectric nanogenerator based on printed circuit board (PCB) technology," Nano Research, vol. 8, no. 3, pp. 722-730, 2015/03/01 2015.
[9] H. Wang, M. Han, Y. Song, and H. Zhang, "Design, manufacturing and applications of wearable triboelectric nanogenerators," Nano Energy, vol. 81, p. 105627, 2021/03/01/ 2021.
[10] Y. Zhou, W. Deng, J. Xu, and J. Chen, "Engineering Materials at the Nanoscale for Triboelectric Nanogenerators," Cell Reports Physical Science, vol. 1, no. 8, p. 100142, 2020/08/26/ 2020.
[11] J. Chen and Z. L. Wang, "Reviving Vibration Energy Harvesting and Self-Powered Sensing by a Triboelectric Nanogenerator," Joule, vol. 1, no. 3, pp. 480-521, 2017/11/15/ 2017.
[12] J.-R. Yang, C.-J. Lee, and C.-Y. Chang, "An electrostatically self-assembled fluorinated molecule as a surface modification layer for a high-performance and stable triboelectric nanogenerator," Journal of Materials Chemistry A, 10.1039/D0TA11596G vol. 9, no. 7, pp. 4230-4239, 2021.
[13] F.-R. Fan, Z.-Q. Tian, and Z. Lin Wang, "Flexible triboelectric generator," Nano Energy, vol. 1, no. 2, pp. 328-334, 2012/03/01/ 2012.
[14] J. Luo and Z. L. Wang, "Recent progress of triboelectric nanogenerators: From fundamental theory to practical applications," EcoMat, vol. 2, no. 4, p. e12059, 2020/12/01 2020.
[15] Z. L. Wang, "Triboelectric nanogenerators as new energy technology and self-powered sensors – Principles, problems and perspectives," Faraday Discussions, 10.1039/C4FD00159A vol. 176, no. 0, pp. 447-458, 2014.
[16] F. Yi et al., "A highly shape-adaptive, stretchable design based on conductive liquid for energy harvesting and self-powered biomechanical monitoring," Science Advances, vol. 2, no. 6, p. e1501624, 2016.
[17] H. Ouyang et al., "Symbiotic cardiac pacemaker," Nature Communications, vol. 10, no. 1, p. 1821, 2019/04/23 2019.
[18] X. Pu et al., "Ultrastretchable, transparent triboelectric nanogenerator as electronic skin for biomechanical energy harvesting and tactile sensing," Science Advances, vol. 3, no. 5, p. e1700015, 2017.
[19] H. Ouyang et al., "Self-Powered Pulse Sensor for Antidiastole of Cardiovascular Disease," Advanced Materials, vol. 29, no. 40, p. 1703456, 2017/10/01 2017.
[20] Z.-H. Lin et al., "A Self-Powered Triboelectric Nanosensor for Mercury Ion Detection," Angewandte Chemie International Edition, vol. 52, no. 19, pp. 5065-5069, 2013/05/03 2013.
[21] S. Wang et al., "Ultrasensitive flexible self-powered ammonia sensor based on triboelectric nanogenerator at room temperature," Nano Energy, vol. 51, pp. 231-240, 2018/09/01/ 2018.
[22] J. Qian and X. Jing, "Wind-driven hybridized triboelectric-electromagnetic nanogenerator and solar cell as a sustainable power unit for self-powered natural disaster monitoring sensor networks," Nano Energy, vol. 52, pp. 78-87, 2018/10/01/ 2018.
[23] H. Guo et al., "A highly sensitive, self-powered triboelectric auditory sensor for social robotics and hearing aids," Science Robotics, vol. 3, no. 20, p. eaat2516, 2018.
[24] C.-H. Chen, P.-W. Lee, Y.-H. Tsao, and Z.-H. Lin, "Utilization of self-powered electrochemical systems: Metallic nanoparticle synthesis and lactate detection," Nano Energy, vol. 42, pp. 241-248, 2017/12/01/ 2017.
[25] H. Zhang, Y. Yang, T.-C. Hou, Y. Su, C. Hu, and Z. L. Wang, "Triboelectric nanogenerator built inside clothes for self-powered glucose biosensors," Nano Energy, vol. 2, no. 5, pp. 1019-1024, 2013/09/01/ 2013.
[26] Z. Wen et al., "A Wrinkled PEDOT:PSS Film Based Stretchable and Transparent Triboelectric Nanogenerator for Wearable Energy Harvesters and Active Motion Sensors," Advanced Functional Materials, vol. 28, no. 37, p. 1803684, 2018/09/01 2018.
[27] H. Chen, Y. Xu, J. Zhang, W. Wu, and G. Song, "Enhanced stretchable graphene-based triboelectric nanogenerator via control of surface nanostructure," Nano Energy, vol. 58, pp. 304-311, 2019.
[28] G. Zhao et al., "Transparent and stretchable triboelectric nanogenerator for self-powered tactile sensing," Nano Energy, vol. 59, pp. 302-310, 2019/05/01/ 2019.
[29] S. Kim et al., "Transparent Flexible Graphene Triboelectric Nanogenerators," Advanced Materials, vol. 26, no. 23, pp. 3918-3925, 2014/06/01 2014.
[30] J. Yang et al., "Surface Engineering of Graphene Composite Transparent Electrodes for High-Performance Flexible Triboelectric Nanogenerators and Self-Powered Sensors," ACS Applied Materials & Interfaces, vol. 9, no. 41, pp. 36017-36025, 2017/10/18 2017.
[31] K. Dong et al., "A Stretchable Yarn Embedded Triboelectric Nanogenerator as Electronic Skin for Biomechanical Energy Harvesting and Multifunctional Pressure Sensing," Advanced Materials, vol. 30, no. 43, p. 1804944, 2018/10/01 2018.
[32] J. Sun et al., "Self-healable, stretchable, transparent triboelectric nanogenerators as soft power sources," ACS Nano, vol. 12, no. 6, pp. 6147-6155, 2018.
[33] K. S. Novoselov et al., "Electric Field Effect in Atomically Thin Carbon Films," Science, vol. 306, no. 5696, p. 666, 2004.
[34] S. Niu and Z. L. Wang, "Theoretical systems of triboelectric nanogenerators," Nano Energy, vol. 14, pp. 161-192, 2015/05/01/ 2015.
[35] S. Kim, J. Ha, and J.-B. Kim, "The effect of dielectric constant and work function on triboelectric nanogenerators: Analytical and numerical study," Integrated Ferroelectrics, vol. 176, no. 1, pp. 251-256, 2016/11/21 2016.
[36] J. Chen et al., "Enhancing Performance of Triboelectric Nanogenerator by Filling High Dielectric Nanoparticles into Sponge PDMS Film," ACS Applied Materials & Interfaces, vol. 8, no. 1, pp. 736-744, 2016/01/13 2016.
[37] F.-R. Fan, L. Lin, G. Zhu, W. Wu, R. Zhang, and Z. L. Wang, "Transparent Triboelectric Nanogenerators and Self-Powered Pressure Sensors Based on Micropatterned Plastic Films," Nano Letters, vol. 12, no. 6, pp. 3109-3114, 2012/06/13 2012.
[38] G. Song et al., "Molecularly Engineered Surface Triboelectric Nanogenerator by Self-Assembled Monolayers (METS)," Chemistry of Materials, vol. 27, no. 13, pp. 4749-4755, 2015/07/14 2015.
[39] K.-E. Byun et al., "Control of Triboelectrification by Engineering Surface Dipole and Surface Electronic State," ACS Applied Materials & Interfaces, vol. 8, no. 28, pp. 18519-18525, 2016/07/20 2016.
[40] S.-H. Shin et al., "Formation of Triboelectric Series via Atomic-Level Surface Functionalization for Triboelectric Energy Harvesting," ACS Nano, vol. 11, no. 6, pp. 6131-6138, 2017/06/27 2017.
[41] C.-C. Wang and C.-Y. Chang, "Enhanced output performance and stability of triboelectric nanogenerators by employing silane-based self-assembled monolayers," Journal of Materials Chemistry C, 10.1039/D0TC00041H vol. 8, no. 13, pp. 4542-4548, 2020.
[42] Y.-H. Cheng, C.-J. Lee, and C.-Y. Chang, "Achieving High Power Density and Long-Term Stable Flexible Triboelectric Nanogenerators through Surface Functionalization of High Work-Function Electrode with Cationic Thiol-Based Self-Assembled Monolayer," Advanced Materials Technologies, vol. 6, no. 3, p. 2000985, 2021/03/01 2021.
[43] B. K. Yun et al., "Base-treated polydimethylsiloxane surfaces as enhanced triboelectric nanogenerators," Nano Energy, vol. 15, pp. 523-529, 2015/07/01/ 2015.
[44] S. Wang et al., "Maximum Surface Charge Density for Triboelectric Nanogenerators Achieved by Ionized-Air Injection: Methodology and Theoretical Understanding," Advanced Materials, vol. 26, no. 39, pp. 6720-6728, 2014/10/01 2014.
[45] S. Li et al., "Manipulating the triboelectric surface charge density of polymers by low-energy helium ion irradiation/implantation," Energy & Environmental Science, 10.1039/C9EE03307F vol. 13, no. 3, pp. 896-907, 2020.
[46] J. B. Schlenoff, "Zwitteration: coating surfaces with zwitterionic functionality to reduce nonspecific adsorption," (in eng), Langmuir : the ACS journal of surfaces and colloids, vol. 30, no. 32, pp. 9625-9636, 2014.
[47] S. Chen, L. Li, C. Zhao, and J. Zheng, "Surface hydration: Principles and applications toward low-fouling/nonfouling biomaterials," Polymer, vol. 51, no. 23, pp. 5283-5293, 2010/10/29/ 2010.
[48] Z. Liu et al., "Poly(ionic liquid) hydrogel-based anti-freezing ionic skin for a soft robotic gripper," Materials Horizons, 10.1039/C9MH01688K vol. 7, no. 3, pp. 919-927, 2020.
[49] L. Sun et al., "Ionogel-based, highly stretchable, transparent, durable triboelectric nanogenerators for energy harvesting and motion sensing over a wide temperature range," Nano Energy, vol. 63, p. 103847, 2019/09/01/ 2019.
[50] D. Cai, A. Neyer, R. Kuckuk, and H. M. Heise, "Raman, mid-infrared, near-infrared and ultraviolet–visible spectroscopy of PDMS silicone rubber for characterization of polymer optical waveguide materials," Journal of Molecular Structure, vol. 976, no. 1, pp. 274-281, 2010/07/15/ 2010.
[51] S. Bilgin, M. Isik, E. Yilgor, and I. Yilgor, "Hydrophilization of silicone–urea copolymer surfaces by UV/ozone: Influence of PDMS molecular weight on surface oxidation and hydrophobic recovery," Polymer, vol. 54, no. 25, pp. 6665-6675, 2013/11/27/ 2013.
[52] Y. Fan, N. Migliore, P. Raffa, R. K. Bose, and F. Picchioni, "Synthesis of Zwitterionic Copolymers via Copper-Mediated Aqueous Living Radical Grafting Polymerization on Starch," Polymers, vol. 11, no. 2, 2019.
[53] Y. Dimitriev, V. Dimitrov, M. Arnaudov, and D. Topalov, "IR-spectral study of vanadate vitreous systems," Journal of Non-Crystalline Solids, vol. 57, no. 1, pp. 147-156, 1983/08/01/ 1983.
[54] T. Haldar and S. Bagchi, "Electrostatic Interactions Are Key to C═O n-π* Shifts: An Experimental Proof," The Journal of Physical Chemistry Letters, vol. 7, no. 12, pp. 2270-2275, 2016/06/16 2016.
[55] X. Fan et al., "PEDOT:PSS for Flexible and Stretchable Electronics: Modifications, Strategies, and Applications," Advanced Science, vol. 6, no. 19, p. 1900813, 2019/10/01 2019.
[56] R. M. Vedovatte, M. C. Saccardo, E. L. Costa, and C. E. Cava, "PEDOT:PSS post-treated by DMSO using spin coating, roll-to-roll and immersion: a comparative study," Journal of Materials Science: Materials in Electronics, vol. 31, no. 1, pp. 317-323, 2020/01/01 2020.
[57] A. Šutka, M. Timusk, J. Metsik, J. Ruža, M. Knite, and U. Mäeorg, "PEDOT electrodes for triboelectric generator devices," Organic Electronics, vol. 51, pp. 446-451, 2017/12/01/ 2017.
[58] J. Shi et al., "A liquid PEDOT:PSS electrode-based stretchable triboelectric nanogenerator for a portable self-charging power source," Nanoscale, 10.1039/C9NR01271K vol. 11, no. 15, pp. 7513-7519, 2019.
[59] I. Lee, G. W. Kim, M. Yang, and T.-S. Kim, "Simultaneously Enhancing the Cohesion and Electrical Conductivity of PEDOT:PSS Conductive Polymer Films using DMSO Additives," ACS Applied Materials & Interfaces, vol. 8, no. 1, pp. 302-310, 2016/01/13 2016.
[60] S.-I. Na et al., "Evolution of nanomorphology and anisotropic conductivity in solvent-modified PEDOT:PSS films for polymeric anodes of polymer solar cells," Journal of Materials Chemistry, 10.1039/B915756E vol. 19, no. 47, pp. 9045-9053, 2009.
[61] T.-R. Chou, S.-H. Chen, Y.-T. Chiang, Y.-T. Lin, and C.-Y. Chao, "Highly conductive PEDOT:PSS films by post-treatment with dimethyl sulfoxide for ITO-free liquid crystal display," Journal of Materials Chemistry C, 10.1039/C5TC00276A vol. 3, no. 15, pp. 3760-3766, 2015.
[62] A. Ahmed et al., "Toward High-Performance Triboelectric Nanogenerators by Engineering Interfaces at the Nanoscale: Looking into the Future Research Roadmap," Advanced Materials Technologies, vol. 5, no. 11, p. 2000520, 2020/11/01 2020.
[63] C.-Y. Chang et al., "Achieving high efficiency and improved stability in large-area ITO-free perovskite solar cells with thiol-functionalized self-assembled monolayers," Journal of Materials Chemistry A, 10.1039/C6TA02581A vol. 4, no. 20, pp. 7903-7913, 2016.
[64] X.-S. Zhang, M.-D. Han, B. Meng, and H.-X. Zhang, "High performance triboelectric nanogenerators based on large-scale mass-fabrication technologies," Nano Energy, vol. 11, pp. 304-322, 2015/01/01/ 2015.
[65] B. Meng, "Fabrication of Triboelectric Nanogenerators," Flexible Stretchable Triboelectric Nanogenerator Devices: Toward Self‐powered Systems, pp. 41-57, 2019.
[66] Y.-H. Chiao et al., "Zwitterion Co-Polymer PEI-SBMA Nanofiltration Membrane Modified by Fast Second Interfacial Polymerization," Polymers, vol. 12, no. 2, 2020.
[67] T.-H. Chang et al., "Protein-based contact electrification and its uses for mechanical energy harvesting and humidity detecting," Nano Energy, vol. 21, pp. 238-246, 2016/03/01/ 2016.
[68] A. Schella, S. Herminghaus, and M. Schröter, "Influence of humidity on tribo-electric charging and segregation in shaken granular media," Soft Matter, 10.1039/C6SM02041K vol. 13, no. 2, pp. 394-401, 2017.
[69] K. Kawano, R. Pacios, D. Poplavskyy, J. Nelson, D. D. C. Bradley, and J. R. Durrant, "Degradation of organic solar cells due to air exposure," Solar Energy Materials and Solar Cells, vol. 90, no. 20, pp. 3520-3530, 2006/12/15/ 2006.
[70] A. M. Nardes, M. Kemerink, M. M. de Kok, E. Vinken, K. Maturova, and R. A. J. Janssen, "Conductivity, work function, and environmental stability of PEDOT:PSS thin films treated with sorbitol," Organic Electronics, vol. 9, no. 5, pp. 727-734, 2008/10/01/ 2008.
[71] W. Xu, M.-C. Wong, and J. Hao, "Strategies and progress on improving robustness and reliability of triboelectric nanogenerators," Nano Energy, vol. 55, pp. 203-215, 2019/01/01/ 2019.

無法下載圖示 全文公開日期 2026/09/22 (校內網路)
全文公開日期 2026/09/22 (校外網路)
全文公開日期 2026/09/22 (國家圖書館:臺灣博碩士論文系統)
QR CODE