研究生: |
邱淑微 Shu-wei Chiu |
---|---|
論文名稱: |
奈米級及次微米級核殼型橡膠添加劑、無機矽膠/有機高分子核殼型顆粒及蒙特納石黏土對不飽和聚酯、乙烯基酯及環氧樹脂之聚合固化反應動力、玻璃轉移溫度、體積收縮、機械性質及微觀型態結構之影響研究 Effects of nano-scale and submicron-scale core-shell rubber additives, inorganic silica gel/organic polymer core-shell particle, and montmorillonite clay on the cure kinetics, glass transition temperatures, volume shrinkage, mechanical properties and cured sample morphology for unsaturated polyester, vinyl ester and epoxy resins |
指導教授: |
黃延吉
Yan-Jyi Huang |
口試委員: |
陳崇賢
Chorng-Shyan Chern 邱文英 Wen-Yen Chiu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2011 |
畢業學年度: | 99 |
語文別: | 中文 |
論文頁數: | 230 |
中文關鍵詞: | 蒙特納石黏土 、核殼型橡膠 、乙烯基樹脂 、環氧樹脂 、微觀型態結構 、反應動力 、體積收縮 、機械性質 、無機有機核殼型顆粒 、不飽和樹脂 |
外文關鍵詞: | core-shell rubber(CSR), montmorillonite (MMT), unsaturated polyester(UP), vinyl ester resin, epoxy resin, cure kinetics, volume shrinkage, mechanical properties |
相關次數: | 點閱:507 下載:0 |
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本文目的主要為探討三種特用添加劑,分別為:(1)奈米級及次微米級核殼型橡膠(core-shell rubber) (2)無機矽膠/有機高分子核殼型顆粒及(3)有機化改質蒙特納石黏土(Montmorillonite clay,MMT),其對苯乙烯/不飽和聚酯(或乙烯基酯)/特用添加劑三成份系統及環氧樹脂/硬化劑/特用添加劑三成份系統之反應前相容性,聚合固化反應動力,玻璃轉移溫度、微觀型態結構、抗體積收縮特性及機械性質等之影響研究。
本研究也利用小角度X-ray散射儀(SAXS)測量不飽和聚酯(UP)及乙烯基酯(VER)之稀薄苯乙烯(St)溶液之散射強度,再根據Guinier Law計算不同UP及乙烯基酯(VER)之環動半徑(Radius of Gyration),可用於St/UP(或VER)/MMT三成份系統,瞭解UP(或 VER)分子擴散至蒙特納石黏土(MMT)層間之難易程度。
The effects of four additives, including (1) nano- scale and submicron-scale core-shell rubber additive,(2) inorganic silica gel/organic polymer core-shell particle, (3) organic montmorillonite clay, on the cure kinetics, glass transition temperatures, cured sample morphology, volume shrinkage characteristics and mechanical properties of the Styrene(St)/ Unsaturated polyester (or Vinyl ester resin)/ additives ternary systems and Epoxy/curing agent /additive ternary systems after the cure have been investigated.
The experimental results have been explained by integrated measurements combining phase characteristic of the St/VER/additive ternary system and Epoxy/curing agent /additive ternary systems before the cure, final cure conversion, glass transition temperature, SAXS and WAXS analysis, cured sample morphology and Mechanical properties.
Also the scattering intensity of vinyl ester resin (VER) and unsaturated polyester (UP) with different structure in dilute styrene solution was measured by the method of small angle X-ray scattering (SAXS), and the radius of gyration of VER and the UP molecule can then be calculated by using the Guinier law.
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