本研究以建立本土化矽灰混凝土配比技術為目標，利用矽灰之微奈米尺寸特性作為填塞料，並採用飛灰與爐石粉之本土化卜作嵐摻料作為微米孔填塞及取代部分水泥之用；粗、細粒料級配依據規範共建立25種不同粒料級配尺度，利用理想級配曲線（富勒曲線，Fuller’s Curve）之理論式計算各級配混合料之組成比例，同時配合緻密配比設計邏輯推導矽灰混凝土材料計算方程式，並由公式中找出共同函數，建立矽灰混凝土配比簡化模式及其相應資料庫，以提升配比設計之便捷性；本研究配比資料庫組合共計2,750種，涵蓋目前工程性質需求範圍。另外，為了具體掌控矽灰混凝土配比技術資料庫之品質資訊，本研究分別就新拌、硬固、耐久性質作試驗驗證與分析；同時，改變溫度、濕度與風速，模擬5種環境場，探討不同環境狀態對矽灰混凝土之影響，以完整詮釋矽灰混凝土特性。研究結果顯示，理論配比模式以矽灰、飛灰、細粒料與粗粒料四種混合級配材料進行組構，使混合料級配範圍可由毫米級、微米級延伸至奈米級，而且粒料級配架構與混合比例不會改變，可提升混凝土粒料架構緻密性；同時，採用三種卜作嵐材料可降低水泥量與矽灰量，材料成本相對較便宜。在性質驗證上，藉由卜作嵐材料的物理緻密填塞效應與本身化學強化反應，結果顯示理論配比可降低混凝土水化尖峰溫度，早期強度雖略低，但晚期強度成長高，並且有良好的超音波速品質、抗硫酸鹽侵蝕能力與抗滲透性，以及能有效降低塑性收縮裂縫發生。然而，改變環境條件下，理論配比因採用大量的卜作嵐材料與較少的用漿量，在濕度愈低或有風速條件時，水泥與卜作嵐材料無法持續水化與卜作嵐反應，對於抗壓強度、超音波速與抗滲透性等硬固性質影響最大；而提高環境溫度，可提升混凝土早期強度，使塑性裂縫指數降低，但長期強度成長有限。

The goal of this study is to establish a mixture proportioning technology for localized silica fume concrete. The micrometer and nanometer scale characteristics of silica fume have led to its use as filler. Local pozzolanic admixtures, such as fly ash and slag powder are also used as micro scale pore fillers and partial replacements of cement, respectively. According to standards, 25 various aggregate gradations are established for coarse and fine aggregate grades. Theoretical mixture based on the ideal gradation curve (Fuller’s Curve) is used to calculate the blend ratio of granulate materials. After that the densified mixture design algorithm (DMDA) is applied to determine the proportion of silica fume concrete. Common functions derived from theoretical equations are used to establish a simplified mixture proportioning model for silica fume concrete and a relevant database to enhance the convenience design of the concrete mixture is set up. 2,750 mixture combinations are built up in the mixture database cover the whole range of current required engineering property. Besides, to better control the quality information in the silica fume concrete mixture technology database, validation tests and analyses on properties of new mixture, hardened characteristics and durability are conducted. Additionally, five conditions of ambient field types were simulated through the changes of temperature, humidity and wind speed to investigate the effect that various environmental conditions on the property of silica fume concrete and to fully characterize the performance of silica fume concrete. The results show that constructed theoretical mixture proportioning model with four types of graded materials, i.e., silica fume, fly ash, fine aggregate and coarse aggregates, extends the mixture gradation range from a millimeter/micrometer scale to a nanometer scale without altering the aggregate grading structure and mix proportions that enhances the density of the aggregate structure of concrete. Additionally, using three-phase pozzolanic materials can significantly reduce the amount of cement paste and silica fume, and will reduce the material cost. In property validations, the theoretical mixture proportion can accordingly reduce the peak temperature during concrete hydration due to less cement used. Although early strength is slightly low, the strength definitely will increase in later stages, accompanied with high ultrasonic pulse velocity, sulfate resistance, and impermeability. This also effectively lowers the occurrence of plastic shrinkage cracks. When environmental conditions change, because theoretical gradation uses significant amounts of pozzolanic materials and less paste, the cement and pozzolanic materials cannot sustain reactions under low humidity or wind speed conditions. This has the greatest effect on the hardened properties of compressive strength, ultrasonic pulse velocity, and impermeability. Raising the ambient temperature increases the early strength of concrete and reduces the plastic cracking index but limited long term strength development.

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