研究生: |
張瀚文 Han-Wen Chang |
---|---|
論文名稱: |
奈米級及次微米級核殼型橡膠添加劑、無機矽膠/有機高分子核殼型顆粒、及蒙特納石黏土對不飽和聚酯、乙烯基酯、及環氧樹脂之微觀型態結構、体積收縮、內部可染色性及機械性質之影響研究 Effects of nano-scale and submicron-scale core-shell rubber additives, inorganic silica gel/organic polymer core-shell particle, and montmorillonite clay on the cured sample morphology, volume shrinkage, internal pigmentability ,and mechanical properties for unsaturated polyester, vinyl ester, and epoxy resins |
指導教授: |
黃延吉
Yan-Jyi Huang |
口試委員: |
陳崇賢
none 邱文英 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2009 |
畢業學年度: | 97 |
語文別: | 中文 |
論文頁數: | 324 |
中文關鍵詞: | 環氧樹脂 、不飽和聚脂 、核殼型橡膠 、乙烯基酯樹脂 、環動半徑 、體積收縮 、內部可染色 |
外文關鍵詞: | volume shrinkage, montmorillonite (MMT), core-shell rubber(CSR), internal pigmentability, unsaturated polyester(UP), vinyl ester resin (VER), radius of gyration |
相關次數: | 點閱:630 下載:0 |
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本文之目的,乃探討三種特用添加劑,分別為:(1)奈米級及次微米級核殼型橡膠(core-shell rubber)添加劑(2)無機矽膠/有機高分子核殼型顆粒及(3)矽烷改質蒙特納石黏土(montmorillonite clay,MMT),其對苯乙烯/不飽和聚脂(或乙烯基酯)/特用添加劑三成份系統及環氧樹脂/硬化劑/特用添加劑三成份系統之之微觀型態結構、抗體積收縮特性及內部可染色性、機械性質等之影響。實驗之結果,吾人將配合苯乙烯/乙烯基脂樹脂/特用添加劑三成份系統在未反應前之相容性,x光散射分析、固化樣品之微觀結構、聚合固化後之反應轉化率及微孔洞體積分率等因素之整合性實驗測量結果加以解釋。
吾人也利用小角度X-ray散射儀(SAXS)測量不飽和聚酯(UP)及乙烯基酯(VER)之稀薄苯乙烯(St)溶液之散射強度,再根據Guinier Law計算不同UP及乙烯基酯(VER)之環動半徑(Radius of Gyration),而針對於St/VER/MMT三成份系統,為瞭解UP分子擴散至蒙特納石黏土(MMT)層間之難易程度。
The effects of two additives, including (1) nano- scale and submicron-scale core-shell rubber additive,(2) inorganic silica gel/organic polymer core-shell particle, and (3) montmorillonite clay, on the cured sample morphology, volume shrinkage characteristics and internal pigmentability, mechanical properties of the styrene(St)/ Vinyl ester resin (VER)/ additives ternary systems and Epoxy/curing agent /additive ternary systems after the cure have been investigated. The experimental results have been explained by integrated measurements combining phase characteristic of the St/VER/additive ternary system and Epoxy/curing agent /additive ternary systems before the cure, XRD analysis , cured sample morphology, final cure conversion, and volume fraction of microvoid generated during the cure by using DSC , SAXS , WAXS , SEM , TEM , OM and image analysis.
Also the scattering intensity of vinyl ester resin (VER) and unsaturated polyester (UP) with different structure in dilute styrene solution was measured by the method of small angle X-ray scattering (SAXS), and the radius of gyration of VER and the UP molecule can then be calculated by using the Guinier law.
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