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研究生: 楊沛蓉
Pei-Jung Yang
論文名稱: 以聯苯和對 – 三聯苯作為骨架製備新的雙碘銨鹽與四碘銨鹽化合物及其光譜鑑定方法研究
Study on the Synthesis of New Diammonium Iodide and Tetraammonium Iodide Salts With Biphenyl and Para-Terphenyl Frameworks and Their Spectroscopic Identification Methods
指導教授: 何郡軒
Jinn-Hsuan Ho
口試委員: 戴龑
Yian Tai
邱昱誠
Yu-Cheng Chiu
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 157
中文關鍵詞: 碘銨鹽化合物雙碘銨鹽四碘銨鹽鑑定方法氫碘酸
外文關鍵詞: Ammonium Compounds, Diammonium Iodide Salts, Tetraammonium Iodide Salts, Analytical Techniques, Hydriodic Acid
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  • 摘要 I Abstract II 誌謝 III 目錄 IV 化合物代號索引 VIII (Series 1) VIII (Series 2) IX 圖目錄 X 表目錄 XII 流程圖目錄 XIII 附錄目錄 XIV 第一章 緒論 1 1.1 前言 1 1.2 文獻回顧 2 1.2.1 使用銨鹽化合物為材料的相關應用文獻 2 1.2.2 碘銨鹽於有機 – 無機鈣鈦礦太陽能電池的應用 4 1.3 研究動機 6 第二章 實驗部分 7 2.1 實驗原理 7 2.1.1 鈴木反應(Suzuki reaction) 7 2.1.2 Boc Protection and Deprotection 8 2.1.3 Protonation 10 2.2 實驗儀器 11 2.3 儀器原理 13 2.3.1 核磁共振儀 13 2.3.2 質譜分析法 13 2.3.3 傅立葉紅外線光譜 14 2.3.4 X光單晶繞射分析儀 14 2.4 儀器量測方法 15 2.4.1 FTIR 15 2.5 實驗藥品與溶劑 16 2.5.1 實驗所使用之藥品 16 2.5.2 實驗所使用之溶劑 18 2.6 化合物結構、分子式及分子量與命名 20 2.7 合成步驟簡圖 24 2.7.1 以聯苯骨架為核心之銨鹽前驅物合成路徑 24 2.7.2 以對 – 三聯苯骨架為核心之銨鹽前驅物合成路徑 25 2.7.3 以聯苯骨架為核心合成碘銨鹽之路徑 26 2.7.4 以對 – 三聯苯骨架為核心合成碘銨鹽之路徑 27 2.8 化合物合成步驟 28 2.8.1 合成胺基的聯苯 28 2.8.2 合成硝基的對 – 三聯苯系列 32 2.8.3 合成胺基的對 – 三聯苯化合物系列 34 2.8.4 合成含保護基的對 – 三聯苯化合物 36 2.8.5 合成碘銨鹽結構 39 第三章 結果與討論 46 3.1 聯苯衍生物的製備與產物鑑定 46 3.1.1 製備聯苯和對 – 三聯苯為骨架的胺基化合物 46 3.1.2 製備含保護基對 – 三聯苯化合物 48 3.1.3 去質子化反應製備聯苯胺 49 3.1.4 聯苯和對 – 三聯苯為骨架的胺基化合物產物鑑定 50 3.1.4.1 [1,1':4',1''-terphenyl]-2,2''-diamine (TP2DA) 之1H-NMR產物鑑定 50 3.1.4.2 [1,1'-biphenyl]-3,3'-diamine (BP3DA) 之1H-NMR產物鑑定 52 3.1.4.3 [1,1':4',1''-terphenyl]-3,3'',4,4''-tetraamine (TP34TA) 之1H-NMR產物鑑定 53 3.2 製備聯苯和對 – 三聯苯碘銨鹽衍生物 55 3.3 反應結果討論 57 3.4 聯苯和對 – 三聯苯為骨架的銨鹽化合物產物鑑定 59 3.4.1 以聯苯為骨架的銨鹽化合物產物鑑定 59 3.4.1.1 [1,1'-biphenyl]-3,3'-diaminium iodide (BP3DAI) 之產物鑑定 59 3.4.1.2 [1,1'-biphenyl]-3,3',4,4'-tetraaminium iodide (BP34TAI) 之產物鑑定 62 3.4.2 以對 – 三聯苯為骨架的的銨鹽化合物產物鑑定 66 3.4.2.1 [1,1':4',1''-terphenyl]-4,4''-diaminium iodide (TP4DAI) 之產物鑑定 66 3.4.2.2 [1,1':4',1''-terphenyl]-3,3'',4,4''-tetraaminium iodide (TP34TAI)之產物鑑定 69 3.5 FTIR光譜分析 73 3.5.1 3,3’- primary amine salts之IR光譜分析 74 3.5.2 4,4’- primary amine salts之IR光譜分析 77 3.5.3 2,2’- primary amine salts之IR光譜分析 79 3.5.4 3,3’,4,4’- primary amine salts之IR光譜分析 81 3.6 X光單晶繞射分析 83 第四章 結論 85 4.1 結論 85 4.2 未來展望 86 第五章 參考文獻 87 附錄 90

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    全文公開日期 2028/08/23 (國家圖書館:臺灣博碩士論文系統)
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