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研究生: 梁浩熏
Hao-Hsun Liang
論文名稱: 彎曲型液晶分子之掺混與光電特性研究
The electro-optical properties of binary system of banana liquid crystals
指導教授: 李俊毅
Jiunn-Yih Lee
口試委員: 邱顯堂
Hsien-Tang Chiu
邱士軒
Shih-hsuan Chiu
戴華山
Hua-Shan Tai
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 91
中文關鍵詞: 反鐵電性B2相自發極化值應答速率
外文關鍵詞: antiferroelectric, spontaneous polariz
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本論文主要為摻混兩個彎曲型液晶分子並量測摻混後物性以及光電性質,化合物分別為:中心苯環4位置為氫取代具有B2相的1,3-Bis[4-(4-decyloxy- benzoyloxy)benzoyloxy] benzene (B-10) 以及中心苯環4位置氯取代具有向列相的 (2) 4-Chloro-1,3-bis[4-(4-decyloxybenzoyloxy)benzoyloxy]benzene(B-10-Cl)。將B-10-Cl掺混至B-10中掺混濃度為0%~100%。當掺混濃度為0%~60%時仍能維持住具有反鐵電性的B2相。掺混濃度為70%時為不具有光電特性的未知相X相。當掺混濃度達到80%~100%時,液晶相為向列相。
在光電性質測量方面,發現自發極化值隨著掺混濃度上升而下降,應答速率則隨著掺混濃度上升而上升。另外,印加高電場三角波時可觀察到focal conic texture及fan with stripes texture.


Binary system of two mesogens exhibited antiferroelectric B2 phase (B-10)and nematic phase (B-10-Cl) was investigated. These compounds were as 1,3-Bis[4-(4-decyloxy- benzoyloxy)benzoyloxy] benzene and 4-Chloro-1,3-bis[4-(4-decyloxybenzoyloxy)benzoyloxy]benzene。When doping the molar ratio of B-10-Cl is below 60%, B2 phase appears and identified by electro-optic experiment which applied triangular wave voltage and has two peaks of response current in half period. When doping the molar ratio of B-10 is 70%, exhibited an unknown mesophase ,X phase and have no current response. When doping the molar ratio of B-10 is above 70%, only possess directional nematic phase.
In the electro-optical experiment, we find that the spontaneous polarization value becomes larger but response time becomes smaller when the molar ratio of B-10-Cl rise. When apply high voltage of triangular wave, focal conic texture and fan with stripes texture were observation.

摘要………………………………………………………………………...………I ABSTRACT…………………………………………………………………….…II 目錄…………………………………………………………………………...…..III 圖索引………………………………………………………………………….....VI 第1章 諸論……………………………………………………………………...1 1-1液晶的發現 1 1-2液晶的分類…………………………………………………………………...3 1-2-1棒狀液晶相(Rod-like mesophases) 4 1-2-2盤狀液晶相(discotic mesophases) 8 1-3鐵電性(Ferroelectricity) 8 1-3-1 強誘電性液晶…………………………………………….................10 1-3-2 反強誘電性液晶………………………………………….................10 1-4 彎曲型液晶………………………………………………………………....13 1-4-1 B1 Phase 14 1-4-3 B2 Phase 15 1-4-3 B3 Phase 20 1-4-3 B4 Phase 21 1-4-3 B5 Phase 22 1-4-3 B6 Phase 24 1-4-3 B7 Phase 25 1-5 研究動機與目的…………………………………..…………………..........27 第2章 實驗方法................................................................................................29 2-1 實驗材料與設備…………………………………….………………….….29 2-1-1 實驗材料……………………………………….….………….….…29 2-2 實驗設備……………………………………………..……………….........30 2-3 cell製作流程………………………………….………………..…….…...31 2-4 液晶摻混………………………………………….……….……..…….......32 2-5 實驗製作流程圖…………………………………....……………..…….....33 2-6 相轉移溫度及紋理圖之觀察……………………….………….……….....34 2-6-1相轉移溫度………………………………………………………….34 2-6-2 外加電場對液晶相紋理圖之影響…………………..…….…....….35 2-7 自發極化值之測量……………………………………………..……….....36 2-8 應答時間之測量………………………………………………..……….…39 2-8-1 應答時間之測量— 明暗時間之測定…………………….…….....39 2-8-2應答速率之測量— 鐵電-鐵電切換時間之測定…………..........…41 第3章 結果與討論…………………………………………………………….42 3-1 彎曲型液晶分子之物性探討……………………….………………….….42 3-1-1相轉移溫度…………………………..……………………..……….42 3-1-2液晶相溫度範圍………………………………………………….....43 3-1-3 未施加電場之液晶紋理圖……………………………………..…..47 3-2 施加電場之液晶紋理圖…………………………………………..……….51 3-3 彎曲型液晶之電氣特性……………………….......................……………53 3-3-1 switching current curve………………………………………….…53 3-3-2 自發極化值與溫度關係…………….………………………....….57 3-3-3 自發極化值與電壓之關係……………………………….……...61 3-3-4 反應時間-鐵電態至鐵電態……………………………...….…...66 3-4 彎曲型液晶之光學特性-應答速率………………………………….….…71 第4章 結論……………………………………………………….……………76 第5章 未來展望…………………………………………………….…………77 參考文獻………………………………………………………..………….…....78

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