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研究生: 劉鐘順
Chung-shun Liu
論文名稱: 幾丁聚醣的抗菌與吸濕複合機能之研究
Antimicrobial activity and water absorbency of chitosan finished fabrics
指導教授: 楊銘乾
Ming-Chien Yang
口試委員: 黃茂全
mau-chuan huang
顏明雄
Meng-shung Yen
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 70
中文關鍵詞: 幾丁聚醣吸濕效果抗菌效果
外文關鍵詞: chitosan, antimicrobial, water absorbency
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本論文以幾丁聚醣對化纖織物之整理加工(pad-dry-curing),檢討改良其抗菌性與吸濕性複合機能的最適化加工條件。本研究中首先以幾丁質(chitin)為原材料,以濃鹼液NaOH(50%)於高溫下加熱處理,不同時間(1hr∼8hrs)下,可得到去乙醯度75∼95%之幾丁聚醣(chitosan)。進而探討不同去乙醯度之幾丁聚醣(chitosan),在不同濃度範圍(0.02--.0.10%)下,對加工織物抗菌性與吸濕性之影響。
自製幾丁聚醣(chitosan)的性質,測定包括:(1)利用傅立葉轉換紅外線光譜儀分析(FTIR):測定薄膜胺基含量(2)利用ESCA電子光譜,分析薄膜表面的碳「C」、氮「N」、氧「O」含量。(3)利用元素分析,測試碳「C」、氮「N」、氧「O」、氫「H」含量。(4)利用膠體滴定法(colloid titration)測定幾丁聚醣的去乙醯度( degree of deacetylation)。(5)利用黏度與分子量的關係【Mark-Houwink equation】求得平均分子量。
在織物加工應用方面,上述所得之幾丁聚醣(chitosan),係以壓吸方式進行加工(pad-dry-curing),結果顯示織物之抗菌性隨幾丁聚醣濃度增加而增大,並隨去乙醯度增加而增強。紡織品之吸濕性,亦隨幾丁聚醣濃度增加而增加。但隨去乙醯度增加而降低。
綜合以上結果,當幾丁聚醣之去乙醯度80%,分子量45kDa以下時,可得到一個同時兼具抗菌、吸濕之複合機能加工織物。


This study is to investigate the effect of chitosan on the antimicrobial activity and water absorbency for the textiles finishing application.
Chitin was treated with NaOH 50%(wt) at 100℃ for different intervals (1hr—8hrs) to deacetylate into chitosan. The resulting chitosan was
characterized including FTIR spectroscopy, Electron Spectroscopy for Chemical Analysis (ESCA),Elemental analysis (EA),colloid titration test to evaluate the degree of deacetylation and viscosity average molecular weight (MV) measurement.Moreover, the resulting chitosan was then finished onto polyester and polyamide fabrics via the pad-dry-curing process.
The results show that the deacetylation increased,while the MV decreased with the alkali treating time.the deacetylation was confirmed by the FTIR, EA and ESCA results .By finishing with chitosan ,PET and Nylon fabrics exhibited antimicrobial activity against Staphylococcus aureus and the water absorbency was greatly improved. Furthermore ,to test the washing durability of the fabrics treated with the chitosan . The results indicated that the antimicrobial activity was disappeared after five washing cycles.

摘要……………………………………………………………………………1 Abstract………………………………………………………………………...2 誌謝……………………………………………………………………………3 目錄……………………………………………………………………………4 圖表索引……………………………………………………………………7 壹、緒論………………………………………………………………………..9 1-1 前言………………………………………………………………...9 1-2 動機………………………………………………………………...10 貳、文獻回顧…………………………………….……………………………11 2-1 發展背景……………………………………………………………...11 2-2 幾丁質與幾丁聚醣…………………………………………………….13 2-3 幾丁質的特性………………………………………………………...15 2-4 幾丁質的結構與特性………………………………………………...15 2-5幾丁聚醣的結構與特性……………………………………………...17 2-6 鹼液法製備幾丁聚醣……………………………………………….18 2-7去乙醯度的測定-紅外光譜分析法………………………………...21 2-8應用與趨勢…………………………………………………………..22 2-9纖維的吸濕平衡……..………………….………………………..25 2-9-1纖維吸濕與時間的關係……………………………..……………..25 2-9-2纖維回潮率與相對濕度間的關係………………………………...25 2-9-3纖維的吸濕機制……………………………………………………..27 2-9-4親水性合成纖維……………………………………………………..29 2-9-4-1合成纖維親水化的原理………..……………………….………..30 2-9-4-2合成纖維親水化的方法……………………………… …………..30 2-10抗菌加工原理……………………………………………………..32 2-10-1衛生加工之發展…………………………………………………..32 2-10-2微生物的種類與生長的因素………………………………...……..34 2-10-3微生物的生長因素…………………………………………...…….36 2-10-4抗菌劑之殺菌機構………………………………..………………..37 參、實驗方法…………………………………………………..…………….40 3-1 實驗材料與設備……………………………………………………….40 3-1-1 實驗材料……………………….…………………………………….40 3-1-2實驗設備……………………………………………………………40 3-2.實驗步驟與方法……………………………………………………….41 3-2-1 試片製作…………………………………………………………….41 3-2-2傅立葉轉換紅外線光譜儀分析(FTIR)……..……………………….41 3-2-3 化學分析電子譜(Electron Spectroscopy for Chemical Analysis)...41 3-2-4元素分析(Elemental Analysis , EA) …………………………………42 3-2-5 幾丁聚醣去乙醯度的測定( degree of deacetylation)……………. 42 3-2-6 黏度平均分子量的測定…………………………………………...42 3-2-7 接觸角測試:contact angle measurement……….………………….43 3-2-8 織物加工方法………………………………………………………..43 3-2-9 加工織物之水洗試驗標準:JIS L0217………………….………….44 3-2-10(a)抗菌試驗標準:AATCC test method 147-1998……………….44 3-2-10(b)抗菌試驗標準:AATCC test method 100-1998………………...45 3-2-11吸濕試驗標準:AATCC test method 79-2000……………………….45 肆、結果與討論……………………………………………………………….47 4-1傅立葉轉換紅外線光譜儀分析(FTIR):…………………………….47 4-2 薄膜吸濕測定………………………………………………………48 4-3 膠體滴定法(colloid titration):去乙醯度測定…………………………49 4-4 平均分子量測定……………………………………………………….50 4-5元素分析(Elemental Analysis , EA)………………………………..51 4-6化學分析電子譜(ESCA)…………………………………………….52 4-7 幾丁聚醣對紡織品整理加工的吸濕性與抗菌性評估………….53 4-7-1紡織品吸濕性……………………………………………….53 4-7-2紡織品抗菌性………………………………………………….57 伍、結論………………………………………………………………………66 參考文獻………………………………………………………………………67

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