簡易檢索 / 詳目顯示

研究生: 池安妮
Anne Thymotie
論文名稱: 添加爐石粉與鹼性激發劑對卜特蘭水泥漿體與砂漿機械性質之影響
Effects of Ground Granulated Blast-Furnace Slag on Mechanical Properties of Portland Cement Blended Paste and Mortar Incorporating Alkaline Activator
指導教授: 張大鵬
Ta-Peng Chang
阮王英
Hoang-Anh Nguyen
口試委員: 黃然
鄭大偉
陳君弢
阮王英
Hoang-Anh Nguyen
張大鵬
Ta-Peng Chang
學位類別: 碩士
Master
系所名稱: 工程學院 - 營建工程系
Department of Civil and Construction Engineering
論文出版年: 2018
畢業學年度: 106
語文別: 英文
論文頁數: 137
中文關鍵詞: 高爐爐石粉抗壓強度鹼性激發劑水玻璃水泥漿砂漿
外文關鍵詞: GGBFS, compressive strength, alkaline activator, waterglass
相關次數: 點閱:233下載:1
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 使用高爐爐石粉以取代部分水泥,對水泥質材料之發展有許多益處,由本研究實驗結果得知,於28天齡期,固定水膠比為0.3,水泥漿與砂漿內添加水泥取代量10 %之高爐爐石粉,相較於控制組,抗壓強度可分別提升至82.25 MPa 及92.78 MPa。當爐石粉取代量達到50 %,介於28天齡期至56天齡期之抗壓強度發展較緩慢,且幾乎達到穩定值,,同時根據實驗數據,分析在於不同齡期時,不同水膠比與爐石粉取代量對硬固爐石水泥漿與砂漿抗壓強度發展之數學%預測公式。
    添加高爐爐石粉會減緩水泥與水之初期水化反應,使早期抗壓強度較低。本研究探討添加矽酸鈉(水玻璃)作為鹼性激發劑,增強爐石粉於水泥漿內之膠結能力,提升早期抗壓強度。實驗結果顯示,相較於一般水泥漿,添加5 %及10 %之矽酸鈉會降低抗壓強度,對機械性質有不利影響,水膠比0.3、0.4及0.5之水泥漿,當添加矽酸鈉10 %會分別降低抗壓強度7.5 %、47.2 %及24.8 %。相較於未添加鹼性激發劑之爐石水泥漿,添加矽酸鈉會降低漿體之抗壓強度,因此,以5%或10%矽酸鈉作為鹼性激發劑取代部份拌合水不適合用以增進爐石粉水泥漿體之卜無嵐反應,或改善早期強度。


    The use of ground granulated blast-furnace slag (GGBFS) as cement replacement has a lot of advantages. From experimental results, on w/b ratio of 0.3, at age of 28 days, the compressive strength of 10% GGBFS blended paste and mortar reached the values up to 82.25 MPa and 92.78 MPa, respectively. Cement substitution with GGBFS up to 50% led to similar or slightly higher strength at ages of 28 and 56 days as compared with that of the control sample. Based on the experimental data, the mathematical equation to predict the compressive strength of paste and mortar at ages of 28 and 56 days as a function of w/b and GGBFS percentage of OPC replacement has been proposed..
    Although the addition of GGBFS has many benefits, its initial lower hydration rate leads to lower early strength. Therefore, in this study, an attempt of using the sodium silicate (waterglass) as alkaline solution was carried out as chemical activator to promote the early strength of GGBFS blended paste. However, the incorporation of 5% and 10% of waterglass led to degradation of mechanical properties especially on compressive strength. Reduction of compressive strength of alkali-activated GGBFS blended paste with 10% waterglass was 7.5%, 47.2% and 24.8% for w/b of 0.3, 0.4, and 0.5, respectively, compared with the compressive strength of non-alkali-activated GGBFS blended paste. Thus, using 5% or 10% of sodium silicate to partially replace the mixing water is unable neither to enhance the pozzolanic reaction of blended paste nor to improve the early age strength.

    Contents 摘要 i Abstract ii Personal Acknowledgements iii Contents iv List of Symbols and Abbreviations vi List of Tables viii List of Figures ix Chapter 1 Introduction 1 1.1 Background 1 1.2 Significance and research objectives 3 1.3 Research outlines 3 Chapter 2 Literature review 6 2.1 Ordinary Portland cement (OPC) 6 2.1.1 OPC as cementitious binder 6 2.1.2 Environmental impact of OPC production 9 2.2 Ground granulated blast-furnace slag (GGBFS) 10 2.2.1 GGBFS as supplementary cementitious material 10 2.2.2 Environmental impact of using GGBFS as supplementary cementitious material 13 2.3 Alkali-activated cementitious materials (AACMs) 13 2.4 Compressive strength prediction 16 Chapter 3 Experimental study 24 3.1 Materials 24 3.2 Mix proportion and curing 24 3.3 Test methods 26 3.3.1 Flowability (consistency of fresh mix) 26 3.3.2 Setting time 26 3.3.3 pH value 27 3.3.4 Compressive strength 28 3.3.5 Drying shrinkage 29 3.3.6 Dynamic elastic and shear modulus 29 3.3.7 Ultrasonic Pulse Velocity (UPV) 30 3.3.8 Scanning Electron Microscopy (SEM) 31 Chapter 4 Results and discussion 42 4.1 Fresh and hardened properties of OPC-GGBFS blended paste 42 4.1.1 Flowability of OPC-GGBFS blended paste 42 4.1.2 Setting time of OPC-GGBFS blended paste 42 4.1.3 pH value of OPC-GGBFS blended paste 43 4.1.4 Compressive strength of OPC-GGBFS blended paste 43 4.1.5 Drying shrinkage of OPC-GGBFS blended paste 46 4.1.6 Dynamic elastic and shear modulus of OPC-GGBFS blended paste 47 4.1.7 UPV results of OPC-GGBFS blended paste 49 4.1.8 Microstructure of OPC-GGBFS blended paste 49 4.2 Fresh and hardened properties of OPC-GGBFS blended mortar 50 4.2.1 Flowability of OPC-GGBFS blended mortar 50 4.2.2 Compressive strength of OPC-GGBFS blended mortar 51 4.2.3 Drying shrinkage of OPC-GGBFS blended mortar 52 4.2.4 Dynamic elastic and shear modulus of OPC-GGBFS blended mortar 53 4.2.5 UPV results of OPC-GGBFS blended mortar 55 4.3 Fresh and hardened properties of alkali-silicate-activated OPC-GGBFS blended paste 55 4.3.1 Flowability of alkali-silicate-activated OPC-GGBFS blended paste 55 4.3.2 Setting time of alkali-silicate-activated OPC-GGBFS blended paste 56 4.3.3 pH value of alkali-silicate-activated OPC-GGBFS blended paste 57 4.3.4 Compressive strength of alkali-silicate-activated OPC-GGBFS blended paste 58 4.3.5 Drying shrinkage of alkali-silicate-activated OPC-GGBFS blended paste 59 4.3.6 Dynamic elastic and shear modulus of alkali-silicate-activated OPC-GGBFS blended paste 59 4.3.7 UPV results of alkali-silicate-activated OPC-GGBFS blended paste 61 4.1.8 Microstructure of alkali-silicate-activated OPC-GGBFS blended paste 61 Chapter 5 Conclusions and suggestions 110 5.1 Conclusions 110 5.2 Suggestions 112 Acknowledgements 114 References 115

    [1]. GREEN BUILDING with CONCRETE. 2nd ed. Sustainable Design and Construction. 2016: Taylor & Francis Group. p. 10.
    [2]. Encyclopedia of Global Warming & Climate Change, S.G. Philander, Editor. 2008, SAGE. p. 363.
    [3]. Siddique, R. and Khan, M.I., Supplementary Cementing Materials. 2011. p. 121-122.
    [4]. Shariq, M., Prasad, J. and Abbas, H., Effect of GGBFS on age dependent static modulus of elasticity of concrete. Construction and Building Materials, 2013. 41: p. 411-418.
    [5]. Shariq, M., Prasad, J. and Abbas, H., Creep and drying shrinkage of concrete containing GGBFS. Cement and Concrete Composites, 2016. 68: p. 35-45.
    [6]. Shariq, M., Prasad, J. and Masood, A., Studies in ultrasonic pulse velocity of concrete containing GGBFS. Construction and Building Materials, 2013. 40: p. 944-950.
    [7]. Shariq, M., Prasad, J. and Massod, A., Effect of GGBFS on time dependent compressive strength of concrete. Construction and Building Materials, 2010. 24: p. 1469-1478.
    [8]. New Technologies for Rural Development having Potential of Commercialisation. 2009: Allied Publishers Pvt. Ltd. p. 65.
    [9]. Cyr, M., Influence of supplementary cementitious materials (SCMs) on concrete durability, in Eco-efficient concrete. 2013, Woodhead Publishing Ltd. p. 153-197.
    [10]. Kirzan, D. and Zivanovic, B., Effects of dosage and modulus of water glass on early hydration of alkali-slag cements. Cement and Concrete Research, 2002. 32(8): p. 1181-1188.
    [11]. Cement, in Building Materials in Civil Engineering, H. Zhang, Editor. 2011. p. 46-80.
    [12]. ASTM C 150 Standard Specification for Portland Cement.
    [13]. Thomas, J. and Jennings, H., http://iti.northwestern.edu/cement/index.html, (Last accessed: 2017/11/26)
    [14]. Kosmatka, S.H., Kerkhoff, B. and Panarese, W.C., Design and Control of Concrete Mixtures. 14th ed. 2002. p. 43-47.
    [15]. Woodson, R.D., Concrete Materials, in Concrete Portable Handbook. 2012. p. 9-10.
    [16]. Sonebi, M., Ammar, Y. and Diederich, P., Sustainability of cement, concrete and cement replacement materials in construction, in Sustainability of Construction Materials. 2016. p. 371-396.
    [17]. Aïtcin, P.-C., Portland Cement, in Science and Technology of Concrete Admixtures. 2016, Elsevier. p. 27-51.
    [18]. Marchon, D. and Flatt, R.J., Mechanisms of cement hydration, in Science and Technology of Concrete Admixtures. 2016, Elsevier. p. 129-145.
    [19]. Weaver, W.S., Isabelle, H.L. and Williamson, F., A Study of Cement and Concrete Correlation. Journal of Testing and Evaluation, 1974.
    [20]. International Energy Agency World Business Council for Sustainable Development, Cement Technology Roadmap 2009: Carbon Emissions Reductions up to 2050, 2009.
    [21]. Igliński, B. and RomanBuczkowski, Development of cement industry in Poland - History, current state, ecological aspects. A review. Journal of Cleaner Production, 2017. 141: p. 702-720.
    [22]. Ali, M.B., Saidur, R. and Hossain, M.S., A review on emission analysis in cement industries. Renewable and Sustainable Energy Reviews, 2011. 15: p. 2252-2261.
    [23]. Abrams, D.A., Effect of Hydrated Lime and Other Powdered Admixtures in Concrete. Proceedings of the American Society for Testing Materials, 1920. 20.
    [24]. Malhotra, V.M., Pozzolanic and Cementitious Materials. 1996, Amsterdam: Gordon and Breach Publishers.
    [25]. Aïtcin, P.-C., Supplementary cementitious materials and blended cements, in Science and Technology of Concrete Admixtures. 2016, Elsevier. p. 53-73.
    [26]. Lee, H.-S. and Wan, X.-Y., Evaluation of compressive strength development and carbonation depth of high volume slag-blended concrete. Construction and Building Materials, 2016. 124: p. 45-54.
    [27]. Cyr, M., Lawrence, P. and Ringot, E., Mineral admixtures in mortars : Quantification of the physical effects of inert materials on short-term hydration. Cement and Concrete Research, 2005. 35: p. 719-730.
    [28]. Lawrence, P., Cyr, M. and Ringot, E., Mineral admixtures in mortars : Effect of inert materials on short-term hydration. Cement and Concrete Research, 2003. 33: p. 1939-1947.
    [29]. Glasser, F.P., Chemical, mineralogical, and microstructural changes occurring in hydrated slag-cement blends. Materials Science of Concrete, 1991. 2: p. 41-81.
    [30]. Schneider, M., Romer, M., Tschudin, M. and Bolio, H., Sustainable cement production - present and future. Cement and Concrete Research, 2011. 41: p. 642-650.
    [31]. Verbeck, G.J. and Helmuth, R.H., Structures and physical properties of hardened cement paste, in 5th International Symposium on the Chemistry of Cement. 1968.
    [32]. Gao, J.M., Qian, C.X., Liu, H.F., Wang, B. and Li, L., ITZ microstructure of concrete containing GGBS. Cement and Concrete Research, 2005. 35: p. 1299-1304.
    [33]. Sajedi, F. and Razak, H.A., The effect of chemical activators on early strength of ordinary Portland cement-slag mortars. Construction and Building Materials, 2010. 24: p. 1944-1951.
    [34]. Pacheco-Torgal, F., Castro-Gomes, J. and Jalali, S., Tungsten mine waste geopolymeric binder: Preliminary hydration products investigations. Construction and Building Materials, 2009. 23(1): p. 200-209.
    [35]. Pacheco-Torgal, F., JoãoCastro-Gomes and Jalali, S., Alkali-activated binders: A review. Part 2. About materials and binders manufacture. Construction and Building Materials, 2008. 22(7): p. 1315-1322.
    [36]. Palomo, A., Grutzeck, M.W. and Blanco, M.T., Alkali-activated fly ashes: A cement for the future. Cement and Concrete Research, 1999. 29(8): p. 1323-1329.
    [37]. Yip, C.K., Lukey, G.C. and Deventer, J.S.J.v., The coexistence of geopolymeric gel and calcium silicate hydrate at the early stage of alkaline activation. Cement and Concrete Research, 2005. 35(9): p. 1688-1697.
    [38]. Cheng, A., Huang, R., Wu, J.-K. and Chen, C.-H., Influence of GGBFS on durability and corrosion behavior of reinforced concrete. Materials Chemistry and Physics, 2005. 93: p. 202-211.
    [39]. Teng, S., Lim, T.Y.D. and Divsholi, B.S., Durability and mechanical properties of high strength concrete incorporating ultra fine Ground Granulated Blast-furnace Slag. Construction and Building Materials, 2013. 20: p. 875-881.
    [40]. Uzal, B., Properties of concrete with high-volume pozzolans, in Eco-Efficient Concrete. 2013, Woodhead Publishing Limited. p. 138-152.
    [41]. Crossin, E., The greenhouse gas implications of using ground granulated blast furnace slag as a cement substitute. Journal of Cleaner Production, 2015. 95: p. 101-108.
    [42]. Wang, H.Y., The effects of elevated temperature on cement paste containing GGBFS. Cement and Concrete Composites, 2008. 30: p. 992-999.
    [43]. Mangat, P. and Lambert, P., Sustainability of alkali-activated cementitious materials and geopolymers, in Sustainability of Construction Materials. 2016. p. 459-476.
    [44]. Zhang, Z., Li, L., Ma, X. and Wang, H., Compositional, microstructural and mechanical properties of ambient condition cured alkali-activated cement. Construction and Building Materials, 2016. 113: p. 237-245.
    [45]. Pacheco-Torgal, F., Castro-Gomes, J. and Jalali, S., Investigations on mix design of tungsten mine waste geopolymeric binder. Construction and Building Materials, 2008. 22: p. 1939-1949.
    [46]. Zivica, V., Effectiveness of new silica fume alkali activator. Cement and Concrete Composites, 2006. 28: p. 21-25.
    [47]. Provis, J.L. and Bernal, S.A., Geopolymers and Related Alkali-Activated Materials. Annual Review of Materials Research, 2014. 44: p. 299-327.
    [48]. Shi, C., Jiménez, A.F. and Palomo, A., New cements for the 21st century: The pursuit of an alternative to Portland cement. Cement and Concrete Research, 2011. 41: p. 750-763.
    [49]. Fernández-Jiménez, A., Garcia-Lodeiro, I. and Palomo, A., Alkali-activated based concrete, in Eco-efficient concrete. 2013. p. 440-443.
    [50]. Angulo-Ramírez, D.E., Gutiérrez, R.M.d. and Puertas, F., Alkali-activated Portland blast-furnace slag cement: Mechanical properties and hydration. Construction and Building Materials, 2017. 140: p. 119-128.
    [51]. Atiş, C.D., Bilim, C., Celik, O. and Karahan, O., Influence of activator on the strength and drying shrinkage of alkali-activated slag mortar. Construction and Building Materials, 2009. 23: p. 548-555.
    [52]. Haha, M.B., Saout, G.L., Winnefeld, F. and Lothenbach, B., Influence of activator type on hydration kinetics, hydrate assemblage and microstructural development of alkali activated blast-furnace slags. Cement and Concrete Research, 2011. 41: p. 301-310.
    [53]. Shi, C., Krivenko, P.V. and Roy, D., Alkali-activated cements and concretes. 2006, Abingdon, UK: Taylor & Francis.
    [54]. Fernández-Jiménez, A., Cementos de escorias activadas alcalinamante: influencia de las variables y modelización del proceso. 2000, Universidad Autónoma de Madrid.
    [55]. Glukhovsky, V.D., Soil Silicate Articles and Structure (Gruntosilikatnye vyroby I konstruktsii). Ed. Budivelnyk Publisher, Kiev, 1967.
    [56]. Glukhovsky, V.D., Ancient, modern and future concretes, in First International Conference Alkaline Cements and Concretes. 1994: Kiev, Ukraine.
    [57]. Krivenko, P.V., Alkaline cements, in First International Conference Alkaline Cements and Concretes. 1994: Kiev, Ukraine.
    [58]. Garcia-Lodeiro, I., Palomo, A. and Fernández-Jiménez, A., An overview of the chemistry of alkali-activated cement-based binders, in Handbook of Alkali-Activated Cements, Mortars, and Concretes. 2015. p. 19-47.
    [59]. Abrams, D.A., Design of Concrete Mixtures. 1919, Chicago: Structural Materials Research Laboratory.
    [60]. ACI 211.1 Standard Practice for Selecting Proportions for Normal, Heavyweight, and Mass Concrete.
    [61]. Dewar, J.D., Computer modelling of concrete mixtures. 1999, London: Taylor & Francis. p. 68.
    [62]. Tennis, P. and Bhatty, J. Characteristics of Portland and Blended Cements: Results of a Survey of Manufacturers. in Proceedings of the 46th IEEE-IAS/PCA Cement Industry Technical Conference. 2006. Phoenix, Arizona.
    [63]. Un, H. and Baradan, B., The effect of curing temperature and relative humidity on the strength development of Portland cement mortar Scientific Research and Essays, 2011. 6: p. 2504-2511.
    [64]. ASTM C 1437 Standard Test Method for Flow of Hydraulic Cement Mortar.
    [65]. ASTM C191 Standard Test Methods for Time of Setting of Hydraulic Cement by Vicat Needle. 2013. p. 8.
    [66]. Deschner, F., et al., Hydration of Portland cement with high replacement by siliceous fly ash. Cement and Concrete Research, 2012. 42(10): p. 1389-1400.
    [67]. Behnood, A., Tittelboom, K.V. and Belie, N.D., Methods for measuring pH in concrete: A review. Construction and Building Materials, 2016. 105: p. 176-188.
    [68]. Yousefieh, N., Joshaghani, A., Hajibandeh, E. and Shekarchi, M., Influence of fibers on drying shrinkage in restrained concrete. Construction and Building Materials, 2017. 148: p. 833-845.
    [69]. Banthia, N., Yan, C. and Mindess, S., Restrained shrinkage cracking in fiber reinforced concrete: a novel test technique. Cement and Concrete Research, 1996. 26(1): p. 9-14.
    [70]. in ASTM C 157 Standard Test Method for Length Change of Hardened Hydraulic-Cement Mortar and Concrete.
    [71]. Brooks, J.J., Concrete and Masonry Movements. 2015. p. 78.
    [72]. Jurowski, K. and Grezeszczyk, S., The influence of concrete composition on Young's modulus. Procedia Engineering, 2015. 108: p. 584-591.
    [73]. RFDA Basic, http://www.imce.eu/, (Last accessed: Dec 16, 2017)
    [74]. Aggelis, D.G., Mpalaskas, A.C. and Matikas, T.E., Acoustic monitoring for the evaluation of concrete structures and materials, in Acoustic Emission and Related Non-Destructuve Evaluation Techniques in the Fracture Mehcanics of Concrete. 2015.
    [75]. ASTM C 597 Standard Test Method for Pulse Velocity Through Concrete.
    [76]. Nguyen, H.-A., Engineering Properties and Durability of Self-Compacting Concrete with No-Cement Eco-Binder Made from Ternary Recycling Industrial By-Products, in Civil and Construction Engineering. 2016, National Taiwan University of Science and Technology.
    [77]. Suresh, D. and Nagaraju, K., Ground Granulated Blast Slag (GGBS) in Concrete - A Review. IOSR Journal of Mechanical and Civil Engineering 2015. 12(4): p. 76-82.
    [78]. Gao, X., Yang, Y. and Deng, H., Utilization of beet molasses as a grinding aid in blended cements. Construction and Building Materials, 2011. 25(9): p. 3782-3789.
    [79]. User Guidelines for Waste and Byproduct Materials in Pavement Construction, https://www.fhwa.dot.gov/publications/research/infrastructure/structures/97148/bfs1.cfm, (Last accessed: 5 January 2018)
    [80]. Sengul, O. and Tasdemir, M.A., Compressive Strength and Rapid Chloride Permeability of Concretes with Ground Fly Ash and Slag. Journal of Materials in Civil Engineering, 2009. 21(9): p. 494-501.
    [81]. Lim, S.N. and Wee, T.H., Autogenous shrinkage of ground-granulated blast furnace slag concrete. ACI Material Journal, 2000. 5: p. 587-593.
    [82]. Franus, W., Panek, R. and Wdowin, M., SEM Investigation of Microstructures in Hydration Products of Portland Cement. 2014.
    [83]. Cho, B.S., Lee, H.H. and Choi, Y.C., Effects of aluminate rich slag on compressive strength, drying shrinkage and microstructure of blast furnace slag cement. Construction and Building Materials, 2017. 140: p. 293-300.
    [84]. ASTM C 109/C 109M Standard Test Method for Compressive Strength of Hydraulic Cement Mortars.
    [85]. Zhang, Z., Zhang, B. and Yan, P., Comparative study of effect of raw and densified silica fume in the paste, mortar and concrete. Construction and Building Materials, 2016. 105: p. 82-93.
    [86]. Chern, J.-C. and Chan, Y.-W., Deformations of concretes made with blast-furnace slag cement and ordinary portland cement. ACI Materials Journal, 1989. 86(4): p. 372-382.
    [87]. Wilk, D., Bratasz, Ł. and Kozłowski, R., Shrinkage cracking in Roman cement pastes and mortars. Cement and Concrete Research, 2013. 53: p. 168-175.
    [88]. Bilim, C. and Atis, C.D., Alkali activation of mortars containing different replacement levels of ground granulated blast furnace slag. Construction and Building Materials, 2012. 29: p. 708-712.
    [89]. Bakharev, T., Sanjayan, J. and Cheng, Y., Alkali activation of Australian slag cements. Cement and Concrete Research, 1999. 29: p. 113-120.
    [90]. Way, S. and Shayan, A., Early hydration of a portland cement in water and sodium hydroxide solutions: composition of solutions and nature of solid phases. Cement and Concrete Research, 1989. 19: p. 759-769.
    [91]. Alexander, K. and Davis, C., Effect of alkali on the strength of Portland cement paste. Australian Journal of Applied Science, 1960. 11: p. 146-156.
    [92]. Ye, H. and Radlinska, A., Shrinkage mechanisms of alkali-activated slag. Cement and Concrete Research, 2016. 88: p. 126-135.
    [93]. Djayaprabha, H.S., Chang, T.-P., Shih, J.-Y. and Chen, C.-T., Mechanical properties and microstructural analysis of slag based cementitious binder with calcined dolomite as an activator. Construction and Building Materials, 2017. 150: p. 345-354.
    [94]. Smaoui, N., Berube, M.A., Fournier, B., Bissonnette, B. and Durand, B., Effects of alkali addition on the mechanical properties and durability of concrete. Cement and Concrete Research, 2005. 35: p. 203-212.

    QR CODE