富鎳層狀材料因為擁有極高比電容量(~220 mAhg-1)的特性，近十年來受到廣泛的研究。但因其有許多的缺點，如熱穩定性差、易與電解液產生副反應、電容量衰退快等，使其始終無法商業化運用於實際生活中。
本研究主要進行雙層包覆，一為藉由乾式包覆工法-機械式包覆，將鈮酸鋰包覆於富鎳材料粉體表面，形成一穩定金屬氧化物層(人工固態電解質界面)，將富鎳材料與電解液隔絕，藉以減少副反應的產生與過渡金屬離子的溶出，以提升粉體的界面穩定性及充放電穩定性。二為運用新型耐熱高分子聚合物，雙馬來醯亞胺與三聚硫氰酸包覆在富鎳材料粉體第二層，使電池在熱失控情況下可以聚合形成斷路，增加電池的安全性。本研究將比較單一製程包覆之樣品、雙層包覆之樣品與未改質前粉體之結構及電化學性能差異。
本研究先進行機械式包覆，將不同比例與不同時間的鈮酸鋰包覆在二次粒子表面，在增加最少阻抗的情況下，得到最佳的穩定性，並在雙重包覆的情況下進行高溫阻抗分析，觀察雙層包覆的電池是否會因為高分子聚合，使阻抗增加，達到增加安全性的作用。
本研究發現，經過鈮酸鋰與耐熱高分子雙層包覆的粉體，在高速率充放電(0.5 C)下有很好的穩定度，循環100圈後電容量為持率還能有49.4%，比改質前之樣品高出26個百分點，且在高溫下阻抗也因為聚合物的聚合而大量增加，使安全性得以提高。

Nickel rich cathode materials are highly researching for recent decade due to its high capacity ~220 mAhg-1. However, owing to the many drawbacks, like poor thermal stability, side reaction with electrolyte and capacity fading.
In this study, double-layered coating is mainly carried out. First part is to coat a metal oxide on the nickel-rich material powder with a dry coating method, Mechanofusion, to form an artificial solid electrolyte interface The nickel rich materials are isolated from the electrolyte to reduce the generation of side reactions and the dissolution of the transition metal ions to improve the stability of interphase and charge/discharge stability of the powder. Second layered, to use the heat-resistant polymer, bismaleimide and tripolythiocyanate, to coat on the nickel rich cathode material powder so that the battery can be polymerized to form an close circuit in the case of thermal runaway, increasing the safety of the battery. This study will compare the structure and electrochemical performance of a single process coated sample, a double coated sample and a non-modified powder.
In the results and discussion, the mechanofusion is first applied to coat the surface of the secondary particles with different ratio and different time of LiNbO3, and the best stability was obtained with the least impedance increase, and in the case of double-layeredcoating. Perform high-temperature impedance analysis to see if the double-coated battery will increase the impedance due to polymer polymerization, which will increase the safety.
The study found that the powder coated by LiNbO3 and double coated by heat resistant polymer has good stability at high C rate (0.5C) and the capacity can be maintained 49.4% after 100 cycles, it’s better than pristine sample. The impedence is also greatly increased at the high temperature due to the polymerization of the polymer so that the safety also improved.

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