含氟側基之聚苯并咪唑之合成與特性及在高溫型質子交換膜燃料電池之應用

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研究生：	洪曉薇 Hsiao-Wei Hung
論文名稱：	含氟側基之聚苯并咪唑之合成與特性及在高溫型質子交換膜燃料電池之應用 Synthesis and Properties of Fluorine-containing Polybenzimidazole for High Temperature Proton Exchange Membrane Fuel Cell Applications
指導教授：	陳志堅 Jyh-Chien Chen
口試委員:	陳志堅 Jyh-Chien Chen 王英靖 Ing-JingWang 游進陽 Chin-Yang Yu
學位類別：	碩士 Master
系所名稱：	工程學院 - 材料科學與工程系 Department of Materials Science and Engineering
論文出版年：	2018
畢業學年度：	106
語文別：	中文
論文頁數：	90
中文關鍵詞：	四胺、聚苯并咪唑、質子交換膜燃料電池、質子傳導率
外文關鍵詞：	tetraamine, polybenzimidazole, proton exchange membrane fuel cell, proton conductivity
相關次數：	點閱：335 下載：0
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本研究合成新型四胺單體並與二酸聚合出聚苯并咪唑P1。P1之固有黏度(inherent viscosity)為2.1dL/g，且成功以溶液澆鑄法塗佈成可饒式的薄膜。P1展現出良好的熱化學穩定性。P1 薄膜在室溫下浸泡於不同濃度的磷酸(75、 65、 55 %)後展現出良好的PU。P1薄膜未摻雜磷酸時，拉伸強度為72.4 MPa。P1薄膜在160 ℃下進行全電池測試，比m-PBI 的 573 mW/cm2還高，證實聚苯并咪唑P1 薄膜可應用於質子交換膜燃料電池。

A novel tetraamine was synthesized via several steps. Novel polybenzimidazoles P1 was prepared
from OBA and monomer (7). The structures of all compounds and P1 were characterized by 1H-NMR. The inherent viscosity of P1, measured in methanesulfonic acid at 35 ℃ and 0.2 g/dL, was 2.1 dL/g, respectively. P1 could be prepared as transparent, flexible, and tough membrane by solution casting. P1 show
outstanding thermal stability. When P1 membrane was immersed in different concentrations of phosphoric acid (75, 65 and 55 %) at room temperature, we could obtain P1 membrane with phosphoric acid uptake (PU, %), respectively. For single fuel cell test at 160 ℃, the peak power density of P1 is higher than thatof m-PBI at 291% PU (573 mW/cm2). It shows that P1 is promising proton exchange membranes for HT-PEMFC applications.

中文摘要........................................................................................................................ I
ABSTRACT ................................................................................................................. II
致謝............................................................................................................................. III
目錄............................................................................................................................. IV
FIGURE 索引 ........................................................................................................... VI
SCHEME 索引 ...................................................................................................... VIII
TABLE 索引 ............................................................................................................. IX
第一章 緒論............................................................................................................ 1
1.1 前言............................................................................................................ 1
1.2 燃料電池分類............................................................................................ 2
1.3 PEMFC 簡介 ............................................................................................. 6
1.3.1 PEMFC 之發電原理 ................................................................................. 6
1.3.2 PEMFC 之結構 ......................................................................................... 7
1.3.3 PEMFC 介紹 ........................................................................................... 10
1.3.4 HT-PEMFC 介紹 ..................................................................................... 12
第二章 PBI 文獻回顧 .......................................................................................... 14
2.1 聚苯并咪唑的簡介.................................................................................. 14
2.2 聚苯并咪唑之聚合方法.......................................................................... 19
2.3 聚苯并咪唑薄膜之製備.......................................................................... 21
2.4 磷酸摻雜聚苯并咪唑.............................................................................. 23
2.5 聚苯并咪唑的氧化安定性...................................................................... 27
2.6 含氟聚苯并咪唑...................................................................................... 30
2.7 研究動機與目的...................................................................................... 33
第三章 實驗.......................................................................................................... 35
3.1 實驗儀器.................................................................................................. 35
3.2 實驗藥品.................................................................................................. 36
3.3 單體合成.................................................................................................. 38
3.4 新型聚苯并咪唑之聚合.......................................................................... 42
3.5 聚苯并咪唑薄膜之製備方法.................................................................. 43
第四章 結果與討論 ............................................................................................. 45
4.1 單體合成與表徵...................................................................................... 45
V
4.2 聚苯并咪唑之合成.................................................................................. 53
4.3 聚苯并咪唑之氫核磁共振圖譜及紅外線光譜...................................... 56
4.4 聚苯并咪唑之分子量與溶解度.............................................................. 58
4.5 聚苯并咪唑之熱學性質.......................................................................... 60
4.6 聚苯并咪唑之氧化安定性與吸水率...................................................... 62
4.7 聚苯并咪唑之磷酸摻雜能力.................................................................. 65
4.8 聚苯并咪唑之機械強度及尺寸安定性.................................................. 67
4.9 質子傳導率測試...................................................................................... 69
第五章 結論.......................................................................................................... 76
參考文獻...................................................................................................................... 77
                                

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全文公開日期 2023/08/29 (校內網路)
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