Biodiesel production from insect｜國立臺灣科技大學博碩士論文系統

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研究生：	Nguyen Hoang Chinh Nguyen Hoang Chinh
論文名稱：	Biodiesel production from insect Biodiesel production from insect
指導教授：	王復民 Fu-Ming Wang
口試委員:	王復民 Fu-Ming Wang 蘇家弘 Chia-Hung Su 蘇清源 Ching-Yuan Su 傅俊中 Chun-Chong Fu 謝建國 Chien-Kuo Hsieh
學位類別：	博士 Doctor
系所名稱：	應用科技學院 - 應用科技研究所 Graduate Institute of Applied Science and Technology
論文出版年：	2019
畢業學年度：	108
語文別：	英文
論文頁數：	98
中文關鍵詞：	黑水虻幼蟲、生質柴油、昆蟲、回應曲面法、轉酯化反應
外文關鍵詞：	Black soldier fly larvae, Biodiesel, Insect, Response surface methodology, Transesterification
相關次數：	點閱：253 下載：0
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上一筆

Abstract    iii
Acknowledgement     v
Abbreviations     ix
List of Tables     x
List of Figures    xi
Chapter 1. Introduction     1
1. Black soldier fly    1
2. Fat potential of BSFL for biodiesel synthesis    1
3. Processes for biodiesel production from insects    3
4. Research innovation    5
Chapter 2. Literature Review    6
1. Biodiesel production    6
2. Feedstocks for biodiesel production    6
2.1. Edible oils    7
2.2. Non-edible oils    9
2.2.1. Non-edible vegetable oils    9
2.2.2. Animal fat     9
2.2.3. Waste cooking oil    10
2.2.4. Microbial oils    11
2.2.4.1. Fungal lipid    11
2.2.4.2. Yeast lipid    11
2.2.4.3. Bacterial lipid    12
2.2.4.4. Microalgae oil    12
2.2.5. Insect fat    13
3. Technology for biodiesel production    14
3.1. Pyrolysis    14
3.2. Micro-emulsification    15
3.3. Dilution/blending      15
3.4. Transesterification/esterification    15
3.4.1. Non-catalytic transesterification    18
3.4.1.1. Supercritical transesterification    18
3.4.1.2. Biox co-solvent transesterification    18
3.4.2. Catalytic transesterification    19
3.4.2.1. Homogeneous alkali-catalyzed transesterification    19
3.4.2.2. Homogeneous acid-catalyzed transesterification    20
3.4.2.3. Heterogeneous alkali-catalyzed transesterification    20
3.4.2.4. Heterogeneous acid-catalyzed transesterification    22
3.4.2.5. Enzyme-catalyzed transesterification    23
3.4.2.6. Microwave-assisted transesterification    24
3.4.2.7. Ultrasound-assisted transesterification    24
4. Benefits and limitations of biodiesel    26
Chapter 3. Materials and Methods    28
1. Materials      28
2. Insect species and cultivation conditions    28
3. Experimental procedure for lipase-catalyzed transesterification of BSFL fat with methanol for biodiesel synthesis    28
3.1. Fat extraction    28
3.2. Optimization of transesterification using RSM      28
4. Experimental procedure for lipase-catalyzed interesterification of BSFL fat with methyl acetate for biodiesel synthesis    29
4.1. Effect of different acyl acceptors on biodiesel production    29
4.2. Optimization of interesterification using RSM      29
5. Experimental procedure for direct transesterification of BSFL biomass for biodiesel synthesis using acetone as a cosolvent    30
5.1. Effect of co-solvent on direct transesterification    30
5.2. Effect of reaction factors on direct transesterification    30
6. Experimental procedure for direct transesterification of BSFL biomass for biodiesel synthesis using DBU as a solvent and catalyst    30
6.1. Direct transesterification    30
6.2. Reusability of DBU    31
7. Analysis    31
Chapter 4. Results and Discussion    33
1. Lipase-catalyzed transesterification of black soldier fly larvae fat with methanol for biodiesel synthesis    33
1.1. Characteristics of BSFL fat      33
1.2. RSM model development      33
1.3. Combined effect of reaction factors on reaction    36
1.4. Obtaining optimal reaction conditions    38
1.5. Conclusions       38
2. Lipase-catalyzed interesterification of black soldier fly larvae fat with methyl acetate for biodiesel synthesis    39
2.1. Influence of different acyl acceptors on biodiesel synthesis    39
2.2. RSM model development    40
2.3. Mutual effect of reaction factors on biodiesel yield    42
2.4. Determination of optimal reaction conditions    45
2.5. The economic feasibility of BSFL biodiesel    45
2.6. Conclusions    46
3. Direct transesterification of black soldier fly larvae biomass for biodiesel production using acetone as a cosolvent    47
3.1. Effect of cosolvent on direct transesterification    47
3.2. Influences of reaction factors on biodiesel yield    48
3.3. Comparison with conventional production method      52
3.4. Conclusions    53
4. Direct transesterification of black soldier fly larvae biomass for biodiesel production using DBU as a solvent and catalyst    53
4.1. Effect of DBU amount      53
4.2. Effect of methanol amount    54
4.3. Effect of temperature      55
4.4. Effect of reaction time    56
4.5. Reusability of DBU    56
4.6. Comparison with other studies      57
4.7. Conclusions      58
5. Fatty acid profiles of BSFL biodiesel    58
6. Properties of BSFL biodiesel      60
Chapter 5. Summary    62
References    63

                                

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