本研究係以聚乙二醇(Polyethylene glycol, PEG)、乙烯基三乙氧基矽烷 (Vinyltriethoxy silane, VTES)及N-乙烯基吡咯烷酮(N-Vinylpyrrolidone, NVP)為原料合成一系列PEG系共聚物，產物內容包含PEG/VTES及PEG/PVP等兩種共聚物。合成之PEG/VTES共聚物具有良好的界面性質，包括降低表面張力能力、良好的濕潤性及低起泡性等，可用於織物之防止污染。PEG/PVP共聚物為使用具生物可降解性之原料合成，PEG/PVP共聚物之加入使染液整體之Zeta電位值降低及粒徑增大。一系列PEG系共聚物加入染液後會使UV之λmax產生位移且吸光度下降，證明PEG系共聚物與染料間會產生相互作用而形成複合體，且具有脫色效果。

In this study, a series of polyethylene glycol copolymers were prepared by the reaction of combining polyethylene glycol (PEG), Vinyltriethoxy silane (VTES) and N-Vinylpyrrolidone (NVP). One of these polyethylene glycol copolymers is PEG/VTES copolymers, and the other is PEG/PVP copolymers. PEG/VTES copolymers exhibited excellent surface activities, wetting power, as well as low foaming. Consequently, the application of a series of PEG/VTES copolymers can make cotton fabrics stain-resistant. PEG/PVP copolymers are products of biodegradable material polymerizations. The addition of copolymers reduced the overall Zeta potential of the dye and increased the particle sizes. The series of polyethylene glycol copolymers and dyes interacted, as the copolymer enabled shifts of the dyesλmax of UV, reduces the absorbance, which proofs that polyethylene glycol copolymers and dyes can be interactive and foams complex with dye-decolorization function.

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