研究生: |
邱威嵐 Wei-Lan Chiu |
---|---|
論文名稱: |
雙軸延伸聚丙烯膜之火焰處理研究 BOPP Biaxial-Oriented Polypropylene Films flame treatment research |
指導教授: |
邱顯堂
Hsien-Tang Chiu |
口試委員: |
李俊毅
Jiunn-Yih Lee 邱士軒 Shih-Hsuan Chiu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2007 |
畢業學年度: | 95 |
語文別: | 中文 |
論文頁數: | 120 |
中文關鍵詞: | 雙軸延伸 、聚丙烯膜 、火焰處理 、電暈處理 、電漿處理 、表面能 、接觸角 、官能基 、田口式 、層流火燄 、火焰結構 、表面處理度 、剝離強度 、水性壓克力 |
外文關鍵詞: | Polypropylene films, corona treatment, contact angle, functional group, BOPP, DOE, flame structure, laminar flame, treatment level, peal off strength, flame treatment |
相關次數: | 點閱:362 下載:4 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
BOPP 雙軸延伸膜是目前工業上作為包裝材料,印刷材料,電子材料極重要且產量最高的一種高分子薄膜。由於PP分子鍊上不具有極性,不容易於表面進行塗佈處理及印刷,是故有多種的表面處理方式可以進行,常見有化學方式,電漿方式,電暈方式,及本論文提及之火焰處理方式。火焰處理由於於高溫氣體燃燒過程中,碳氫化合物及氮氧,碳氧解離造成之自由基並於氣體流速及壓力下造成使用溫度活化PP表面並使自由基接枝於PP鍊上,使PP表面帶有極性,經由處理之具有極性的BOPP表面可易於使各種塗料附著而提高塗料之附著力及剝離強度。
火焰處理的過程中需要有許多的參數設定及參數選擇,因為控制參數及物料的選擇及種類影響處理效果甚大,以及經驗的累積之影響均會造成處理度及品質的改變。故長期的製程規劃規劃追蹤及DOE尋找最佳的處理條件成為生產製造上最大的難題。
本論文針對BOPP火焰處理過程中必須考慮的參數,進行一系列的探討及條件規劃,針對火焰處理造成的效果進行最佳化調控。
本論文希望將可作為火焰處理工作人員訓練手冊及教學之用,希望可以提供火焰處理專案工作人員於進行處理時最佳的參考依據及方向。
Bi-Orientation Polypropylene film is the dominating and important material as packaging, printing, electronic materials in the market and large volume in polymer filme production. As result in the polymer chain of PP does not have the special function group, it is difficult to coating and printing on its surface. So there are many kinds of treatment ways such as chemicals, corona, flame, and plasma treatment.
This essay mentions and research about flame treatment.
During the combustion of mixture gas, there are many free radical such as CH group compound, NO, CO, groups links on the PP chain because of the pressure and dynamic flow motions impact and temperature activate the PP surface. After treatment, the BOPP film has strong absorption ability for adhesive and increasing the peal of strength.
During the flame treatment, there many factors and parameters need to be considered. Experience and DOE tests design also should be involved.
II
This essay is focusing on the parameters research during the flame treatment and discussion about the factors find the route for optimization the flame treatment system to get the good recipe.
This essay could be the instruction and training guide for the flame treater operators and could be the reference for materials development.
3-5.參考文獻:
1.Surface Structure and Adhesive Properties of Bi axially
Oriented Polypropylene Film Grafted With
Poly(Acry1ic Amide) Using Corona Discharge ,JINGXIN LEI, GUANGJIAN HE, QIMAN LI, XIAOHONG LIN
Polymer engineering and science, May.2001, Vol.41.
2. Study of Diffusion and Sorption of Bis-(2-chloroethyl)sulfide
(SM) and Bis-(2-~hloroethyl)ether (OM) Through
Polypropylene (PP) and Biaxial-Oriented Polypropylene
(BOPP) Films by the FTIR-ATR Spectroscopic Method
RAJENDRA P. SEMWAL, SUSANTA BANERJEE, LAKHl R. CHAUHAN,
A.Diffusion and sulfur and oxygen mustards,August. 1995
3. Surface Degradation and Hydrophobic Recovery of
Polyolefins Treated by Air Corona and Nitrogen
Atmospheric Pressure Glow Discharge ,Se’bastien Guimond, Michael R. Wertheimer ,Wiley Intersience Received 6 February 2004
4. Surface physicochemistry of corona-discharge-treated
polypropylene film ,S Lesley-Ann O’Hare, Stuart Leadley and Bhukan Parbhoo, SURFACE AND INTERFACE ANALYSIS Surf. Interface Anal. 2002; 33: 335–342
5. Effect of vapor-flame treatment on plasma sprayed hydroxyapatite coatings, Tao Shunyan, Ji Heng, Ding Chuanxian
VAPOR-FLAME TREATMENT ON HA COATINGS
April 2000
6. Effects of Flame Treatment on Propylene-Ethylene
Copolymer Surfaces ,E. Sheng, I. Sutherland,D. M. Brewis and R. J. Heath ,SURFACE AND INTERFACE ANALYSIS, VOL. 19, 151-156 (1992)
7.Flame Dynamics and Structure Within Sub-Millimeter Combustors, Shaurya Prakash and Adrian D. Armijo Richard I. Masel, Mark A. Shannon ,AIChE Journal June 2007 Vol. 53, No. 6
8.Flame structure and NO emissions in gas combustion of low
calorific heating value, Jeong Park1,n,y, Jong-Geun Choi1, Sang-In Keel2 and Tae-Kweon Kirn INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2003; 27:1339–1361 (DOI: 10.1002/er.955)
9. Flame-retardant Treatment of some Tropical Timbers ,A. N. Eboatu, B. Garba and I. 0. Akpabio ,FIRE AND MATERIALS, VOL. 17,39-42 (1993)
10.Modeling Wet-Gas Annular/ Dispersed Flow
Through a Venturi ,M. van Werven and H. R. E. van Maanen, G. Ooms, B. J. Azzopardi, AIChE Journal June 2003 Vol. 49, No. 6 1391
11.Modification of Polypropylene Surfaces by Flame treatment
I. Sutherland, D. M. Brewis, R. J. Heath and E. Sheng
SURFACE AND INTERFACE ANALYSIS, VOL. 17, 507-510 (1991)
12.Numerical study on e!ect of CO2 addition in flame structure and
NOx formation of CH4 -air counterfow di!usion flames
C. E. Lee1,*, S. R. Lee1, J. W. Han1 and J. Park2
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
2001; 25:343 -354
13. Numerical study on flame structure and NO formation in
CH4–O2–N2 counterflow diffusion flame diluted with H2O
Dong-Jin Hwang1, Jong-Wook Choi1, Jeong Park1,n,y, Sang-In Keel2, Chang-Bo Ch3 and Dong-Soon Noh4
INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Int. J. Energy Res. 2004; 28:1255–1267
14. Numerical study on flame structure in H2–O2/CO2
laminar flames,Jeong Park1,n,y, Sang-In Keel2, Sung-Hoon Shim2 and Dong-Soon Noh3 , INTERNATIONAL JOURNAL OF ENERGY RESEARCH ,Int. J. Energy Res. 2003; 27:639–652 (DOI: 10.1002/er.902)
15. On a Mechanical Model of the Bopp-Podolsky Potential ,H.GUHTHER,Annalen der Phvsik. 7. Folge, Band 33, Heft 6, 1976, S. 448-454
16. Oxygen Plasma Treatment of Sisal Fibers and Polypropylene: Effects on Mechanical Properties of Composites, ELISETE COUTO', ING HWIE TAN, NICOLE DEMARQUEITE, JOSE CLAUD, CARASCH1, and ALCIDES,POLYMER ENGINEERING AND SCIENCE, APRIL 2002, Vol. 42, No. 4
17. Performance of Small Herschel-Tjpe Venturi Tubes, P. L. WALKER, JR., R. J. FORESTI, JR., F. RUSINKO, JR., and B. W. McCORMICK ,Vol. 1, No. 1 A.1.Ch.E. Journal Page 125~128
18. Plasma-Induced Surface Modification and Enhancement of Polypropylene Surface,N. V. Bhat, D. J. Upadhyay BHAT AND UPADHYAY , December. 2001
19. Box, Hunter, Hunter(1978):Statistics for Experimenters
20. 智昱材料股份有限公司:聚丙烯原料之特性 : p1 ~p25
21. Glow Discharge Processes Sputtering and plasma Etching
22. Plasma Chemistry , 復漢出版社
23.高分子物性,明文書局
24.界面科學,復文書局
25.界面活性劑的原理與應用,高立圖書
26. 2004 中 華 印 刷 科 技 年 報
27. 印刷藝術2005年第5期刊
28. 印刷藝術 2003年第11期刊
29. 田口式最佳化之品質工程,高立圖書