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研究生: 邱威嵐
Wei-Lan Chiu
論文名稱: 雙軸延伸聚丙烯膜之火焰處理研究
BOPP Biaxial-Oriented Polypropylene Films flame treatment research
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 李俊毅
Jiunn-Yih Lee
邱士軒
Shih-Hsuan Chiu
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2007
畢業學年度: 95
語文別: 中文
論文頁數: 120
中文關鍵詞: 雙軸延伸聚丙烯膜火焰處理電暈處理電漿處理表面能接觸角官能基田口式層流火燄火焰結構表面處理度剝離強度水性壓克力
外文關鍵詞: Polypropylene films, corona treatment, contact angle, functional group, BOPP, DOE, flame structure, laminar flame, treatment level, peal off strength, flame treatment
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  • BOPP 雙軸延伸膜是目前工業上作為包裝材料,印刷材料,電子材料極重要且產量最高的一種高分子薄膜。由於PP分子鍊上不具有極性,不容易於表面進行塗佈處理及印刷,是故有多種的表面處理方式可以進行,常見有化學方式,電漿方式,電暈方式,及本論文提及之火焰處理方式。火焰處理由於於高溫氣體燃燒過程中,碳氫化合物及氮氧,碳氧解離造成之自由基並於氣體流速及壓力下造成使用溫度活化PP表面並使自由基接枝於PP鍊上,使PP表面帶有極性,經由處理之具有極性的BOPP表面可易於使各種塗料附著而提高塗料之附著力及剝離強度。
    火焰處理的過程中需要有許多的參數設定及參數選擇,因為控制參數及物料的選擇及種類影響處理效果甚大,以及經驗的累積之影響均會造成處理度及品質的改變。故長期的製程規劃規劃追蹤及DOE尋找最佳的處理條件成為生產製造上最大的難題。
    本論文針對BOPP火焰處理過程中必須考慮的參數,進行一系列的探討及條件規劃,針對火焰處理造成的效果進行最佳化調控。
    本論文希望將可作為火焰處理工作人員訓練手冊及教學之用,希望可以提供火焰處理專案工作人員於進行處理時最佳的參考依據及方向。


    Bi-Orientation Polypropylene film is the dominating and important material as packaging, printing, electronic materials in the market and large volume in polymer filme production. As result in the polymer chain of PP does not have the special function group, it is difficult to coating and printing on its surface. So there are many kinds of treatment ways such as chemicals, corona, flame, and plasma treatment.
    This essay mentions and research about flame treatment.
    During the combustion of mixture gas, there are many free radical such as CH group compound, NO, CO, groups links on the PP chain because of the pressure and dynamic flow motions impact and temperature activate the PP surface. After treatment, the BOPP film has strong absorption ability for adhesive and increasing the peal of strength.
    During the flame treatment, there many factors and parameters need to be considered. Experience and DOE tests design also should be involved.
    II
    This essay is focusing on the parameters research during the flame treatment and discussion about the factors find the route for optimization the flame treatment system to get the good recipe.
    This essay could be the instruction and training guide for the flame treater operators and could be the reference for materials development.

    目錄 摘要 ………………………………………………………… I Abstract …………………………………………………… II 致謝 ………………………………………………………… IV 目錄 ………………………………………………………… V 圖索引 ……………………………………………………… VII 表索引 ……………………………………………………… VIII 第一章 序論 …………………………………………… 1 第二章 相關理論及文獻回顧 …………………………… 3 2.1 BOPP 雙軸延伸膜簡介及表面處理機構 …………… 3 2.1-1 PP高分子特性及BOPP 膜特性說明………… 3 2.1-2 BOPP雙軸延伸之高分子物性理論…………… 6 2.1-3高分子表面處理比較…………………………… 11 2.1-4 高分子表面處理之應用及塗佈技術…………… 17 2.1-5界面之接觸角對於附著力……………………… 23 2.2 高分子表面火焰處理…………………………………… 27 2.2-1 火焰的架構理論及特性…………………………… 27 2.2-2 火焰於高分子表面上產生的特殊效應…………… 29 2.2-3 火焰處理後的表面物理及化學特性……………… 31 2.2-4 義大利ESSE CI 火焰處理設備…………………… 33 2.2-5 燃燒過程產生之自由基基團可於表面造成的效果… 35 2.2-6 燃燒氣體的流體力學………………………………… 36 2.2-7 流量與燃燒溫度……………………………………… 37 2.2-8 壓力及定壓系統……………………………………… 38 2.2-9 膜之捲取速度之相對速度…………………………… 39 2.2-10 熱及冷卻………………………………………………40 2.2-11 火焰與冷卻BOPP 平面之相對關係及火焰型態…… 41 第三章 BOPP 雙軸延伸聚丙烯膜火焰處理研究………………… 74 3.1 研究目的及前言…………………………………………… 74 3.2 BOPP 實驗品項………………………………………………75 3.2 化學藥品及使用之瓦斯氣體……………………………… 76 3.3 製程規劃及實驗…………………………………………… 78 3.3-1.DOE 製程最佳化與變因數…………………………… 78 3.3-2 BOPP 膜於設備上的運轉速度及處理度的關係………79 3.3-3甲烷混和氣溫度相對比較及最佳處理溫度點…………80 3.3-4混和氣流量變化及處理度變化…………………………81 3.3-5火焰與膜面品質相對比較及最佳化處理………………82 3.3-6火焰與膜面間隙相對比較及間隙校正…………………83 3.3-7 燃氣壓力造成之影響 ……………………………… 84 3.3-8冷卻輪冷卻溫度相對比較…………………………… 86 3.4 膜面處理效果鑑定………………………………………… 87 3.4-1 ASTM處理度鑑定………………………………………87 3.4-2 接觸角分析及時效追蹤……………………………… 88 3.4-3 光學顯微鏡之微表面檢視…………………………… 89 3.4-4 AFM原子力顯微鏡表面分析……………………………90 3.4-5 處理後之膜面塗佈及硬化處理……………………… 92 3.4-5 FTIR 官能基檢驗及判讀………………………………93 3.4-6 傳統剝離測試及剝離強度測試……………………… 94 3.5 參考文獻…………………………………………………114 第四章 結論………………………………………………………118

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