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研究生: 伍哲漢
Che-Han Wu
論文名稱: 常壓電漿於聚二甲基矽氧烷接枝複合型高分子載體薄膜
Study of plasma-grafted composite polymer as carrier film on polydimethylsiloxane via atmospheric pressure plasma
指導教授: 郭俞麟
Yu-Lin Kuo
口試委員: 游進陽
Chin-Yang Yu
宮甫辰
Fu-Chen Kung
廖淑娟
Shu-Chuan Liao
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 107
中文關鍵詞: 常壓大氣電漿噴束電漿聚合親水性老化效應HEMA精油
外文關鍵詞: APPJ, plasma polymerization, hydrophilicity, aging effect, HEMA, essential oil
相關次數: 點閱:230下載:0
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中文摘要 I Abstract II 致謝 III 總目錄 IV 圖目錄 VII 表目錄 XI 第一章 緒論 1 1.1 前言 1 1.2 研究動機 3 第二章 文獻回顧 5 2.1 高分子工程材料 5 2.1.1天然聚合物 5 2.1.2合成聚合物 5 2.1.3高分子的分類 6 2.1.4 塑膠類 6 2.1.5 PDMS定性分析 9 2.1.6 矽膠透過表面改質後之特性 11 2.2 高分子貼合機制 12 2.2.1表面接枝聚合法 13 2.2.2電漿聚合 13 2.2.3 Ultraviolet/Ozone(UVO)表面處理 14 2.2.4化學表面處理 15 2.3材料表面改質之應用 16 2.3.1抗菌改質 16 2.3.2親水性改質 17 2.3.3抗腐與磨耗性改質 17 2.3.4生醫功能性分子之固定 18 2.3.5超疏水改質 18 2.4表面性質 19 2.4.1接觸角 19 2.4.2表面自由能 20 2.5 電漿簡介 22 2.5.1電漿原理與反應機制 23 2.5.2 電漿分類 25 2.5.3電漿系統分類 26 2.5.4電漿氣體效應 28 2.5.5 電漿表面改質 30 2.5.6電漿改質之應用 33 2.6 精油介紹 39 2.6.1 精油萃取 39 2.6.2 化學成分 41 第三章 實驗方法 43 3.1實驗總覽 43 3.2實驗製程 44 3.2.1 實驗材料介紹 44 3.2.2 實驗儀器介紹 44 3.3儀器設備程序 45 3.3.1常壓電漿系統 45 3.3.2接觸角量測儀 49 3.3.3 光學放射頻譜儀 50 3.3.4 傅立葉轉換紅外線光譜儀 52 3.3.5 場發射掃描式電子顯微鏡 53 3.3.6 百格測試 55 3.3.7 熱重分析 56 3.3.8 白光干涉儀 57 3.4薄膜製備 58 3.4.1 薄膜之前驅物製備 58 3.4.2 試片之清洗 58 3.4.3 電漿前處理 59 3.4.4 薄膜塗佈 59 3.4.5 載體薄膜之聚合 59 3.4.6 載體薄膜與精油之結合 59 3.5 薄膜性質測定 60 3.5.1 水接觸角之量測 60 3.5.2 遠程紅外光普測量 60 3.5.3 抗氧化測定 60 第四章 實驗結果討論 61 4.1常壓電漿性質分析 61 4.1.1電漿物種分析 61 4.1.2材料表面分析 65 4.1.3電漿之於基材表面升溫分析 66 4.1.4電漿改質於基材表面親水性分析 67 4.1.5電漿改質於基材表面時效性量測 71 4.1.6自由基數目測定 73 4.2薄膜分析 75 4.2.1薄膜FTIR檢測 75 4.2.1.1電漿表面改質成效 75 4.2.1.2載體薄膜於表面貼附狀況 77 4.2.1.3 載體薄膜內之蛋白質變性情況 79 4.2.1.4 不同Zein濃度之薄膜化學性質探討 79 4.2.2薄膜表面極性測試 81 4.2.2.1載體薄膜之水接觸角與表面能 81 4.2.2.2載體薄膜聚合程度 83 4.2.2.3載體薄膜與精油貼附能力 86 4.2.2.4 載體薄膜之時效測定 91 4.2.3薄膜表面形貌 92 4.2.3.1 SEM表形貌測定 92 4.2.3.2 白光干涉儀之測定 97 4.2.4薄膜機械性質測定 101 4.2.5抗氧化性質測定 102 第五章 結論與未來展望 105 5.1實驗結論 105 5.2未來展望 106 第六章 參考文獻 107

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