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研究生: 王柏勛
Bo-Xun Wang
論文名稱: 新型聚苯醚材料合成及物性探討
Synthesis of New Polyphenylene Ether Materials and Study of Their Properties
指導教授: 何郡軒
Jinn-Hsuan Ho
口試委員: 戴龑
Yian Tai
陳銘崇
Ming-Chong Chen
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 74
中文關鍵詞: 聚苯醚銅箔基板熱穩定性加工性介電性質
外文關鍵詞: polyether resin, bisphenol
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  • 摘要 I Abstract II 目錄 III 表目錄 V 流程圖目錄 VI 圖目錄 VII 第一章 緒論 1 1-1 前言 1 1-2 文獻回顧 2 1-3 研究動機 6 第二章 實驗 7 2-1 實驗儀器 7 2-2 儀器原理 8 2-2.1核磁共振儀(NMR) 8 2-2.2熱重分析儀(TGA) 9 2-2.3示差掃描熱分析儀(DSC) 10 2-2.4凝膠滲透層析儀(GPC) 11 2-2.5高解析質譜分析儀(HR MS) 12 2-3 儀器量測方法 13 2-3.1熱重分析儀(TGA)量測方法 13 2-3.2示差掃描熱分析儀(DSC) 量測方法 14 2-3.3凝膠滲透層析儀(GPC) 量測方法 16 2-4 實驗藥品與溶劑 17 2-4.1實驗用藥品 17 2-4.2實驗用溶劑 18 2-5 化合物結構、分子式及分子量 19 2-6 聚苯醚之合成 20 2-6.1聚苯醚合成步驟 20 2-6.2聚苯醚樣品外觀 25 第三章 結果與討論 26 3-1 寡聚物之合成與探討 26 3-1.1決定寡聚物合成之反應性問題(通氣/反應時間/反應比例/進料時間) 26 3-1.2 NMR光譜解析 37 3-2 樣品分子量分析 42 3-2.1 溶解度分析 46 3-2.2 溶解度分析 48 3-3 熱重分析儀(Thermogravimetric analysis,TGA)分析 49 3-3.1 各樣品之TGA分析 49 3-3.2 不同分子量樣品之TGA分析 51 3-4 示差掃瞄熱分析儀(Differential Scaning Calorimeter,DSC)分析 56 3-5 介電性質測試 59 3-6 綜合分析 60 第四章 結論 61 4-1 結論 61 4-2 未來展望 52 第五章 參考文獻 63

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