大宗的氮氧化物氣體常經由化石燃料電氣廠與焚化廠的製程中排出，大部分對於此類氮氧化物的去除乃採用濕式吸收處理，於是出口煙道氣洗滌器設計、操作最佳化、洗滌液物理或化學吸收反應之研究有其必要性。
本研究為探討一種創新的超重力旋轉填充床/臭氧氧化/過氧化氫氧化程序，臭氧對不溶性一氧化氮與二氧化氮有很高的反應效率，進一步反應為溶解性佳的五氧化二氮，有效提高氮氧化物的處理效率，再於超重力旋轉填充床內將氮氧化物吸收為硝酸。臭氧與超重力旋轉填充床程序去除氮氧化物效率在本研究發現為85-99%。在另一系統過氧化氫與旋轉填充床去除氮氧化物程序，過氧化氫洗滌液可有效提升一氧化氮的去除，其效果為75-87%.
旋轉填充床反應器的特色是以離心的方式使液膜變薄或液滴變小，以增加氣液接觸面積進而提升質傳與反應為最終產物硝酸。以不同操作參數(臭氧濃度、過氧化氫濃度、氮氧化物濃度、旋轉填充床轉速、液氣化、水洗液pH值)，對旋轉填充床氧化吸收程序反應動力加以探討，了解各反應因子對整體反應之影響。同時驗證超重力旋轉填充床處理氮氧化物之最佳條件，作為將來設計超重力旋轉填充床/臭氧反應器之參考依據。在本研究中亦發現吸收速率將會隨著轉速的提高與氣液比的降低而提高且在中性與鹼性溶液下有較佳的吸收效果，然而一氧化氮在過氧化氫水溶液的吸收效果在pH=11下卻漸漸的不明顯。

This study is focused on the application of an innovative O3/RPB (Rotating Packed Bed) and H2O2/RPB process to the treatment of NOx in the gas streams. Ozone and NOx in the gas stream were injected into a gas phase reactor. Ozone rapidly reacts with insoluble NO and NO2 molecules to form soluble N2O5. The mixed gas from the gas phase reactor is then flows into a RPB reactor. NOx removal efficiencies of 85-99% were obtained for O3/RPB process. In another system,using hydrogen peroxide scrubbing process also showed to be viable to enhance the performance of the absorption system. NOx removal efficiencies of 75-87% were obtained for H2O2/RPB process.
The oxidation-absorption process in rotating packed bed will be studied under various operating conditions including O3 concentration , H2O2 concentration, NO concentration , rotating speed, liquid/gas ratio and solution pH. Gas-liquid mass transfer and aqueous phase reaction will be discussed and the optimum experimental conditions will also be determined. For example, the absorption rate was greatly affected by the rotor speed for experiments conducted at lower gas/liquid flow rate ratio. The absorption of nitric oxide was favored to occur in neutral and alkaline solutions; however, the absorption rate of nitric oxide in H2O2 solution for experiment conducted at pH 11 was found to be mitigated.

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