研究生: |
蕭淳 Chun Hsiao |
---|---|
論文名稱: |
奈米金棒/奈米碳材混成材料於表面增強拉曼散射之應用 Fabrication of Gold Nanorods/Nanocarbon Materials Hybrids for Use as Dynamic Surface-Enhanced Raman Scattering Substrates |
指導教授: |
邱智瑋
Chih-Wei Chiu |
口試委員: |
孫亞賢
Ya-Sen Sun 劉定宇 Ting-Yu Liu 鄭智嘉 Chih-Chia Cheng |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2019 |
畢業學年度: | 107 |
語文別: | 中文 |
論文頁數: | 91 |
中文關鍵詞: | 奈米金棒 、氧化石墨烯 、奈米碳管 、碳黑 、表面增強拉曼散射 |
外文關鍵詞: | Gold nanorods, Graphene oxide, Carbon nanotubes, Carbon black, Surface-enhanced Raman Scattering |
相關次數: | 點閱:306 下載:0 |
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本研究是利用晶種成長法製備出不同長徑比的奈米金棒(AuNRs)結合不同維度的奈米碳材料,分別為氧化石墨烯(GO)、改質奈米碳管(CNT-COOH)、改質碳黑(OCB),應用於表面增強拉曼散射(Surface Enhanced Raman Scattering, SERS)。奈米分散的原理是以十六烷基三甲基溴化銨(cetyltrimethylammonium bromide, CTAB)包覆穩定AuNRs,且AuNRs表面帶正電,會因靜電吸引力而吸附在帶負電的奈米碳材料上,形成AuNRs/奈米碳材複合物,此奈米混成材料具有良好的光學穿透性且能提高對於偵測物的接觸面積,可作為高靈敏度表面增強拉曼散射基材,並比較AuNRs結合不同維度奈米碳材料於SERS上之訊號差異。實驗結果可以由紫外-可見光譜儀(Ultraviolet-visible spectroscopy, UV-Vis)及穿透式電子顯微鏡(Transmission Electron Microscope, TEM)來確認AuNRs穩定且均勻的吸附在奈米碳材料上,於SERS上的結果顯示,AuNRs/GO複合物之增強訊號最好,因GO為二維奈米材料其厚度小於5 nm,故吸附在GO上的AuNRs可以產生良好的3D熱點效應。在SERS檢測中,對於染料分子Rhodamine 6G(R6G)的增強因子(Enhancement Factor, EF)為1×107,偵測極限為10-8M,達到很好的增強效果。進一步用於D-SERS上,由於D-SERS是檢測樣品由濕到乾的過程,因此在溶劑蒸發的過程中,會自發的形成大量的3D熱點,進而使SERS訊號大大的提升,從實驗結果顯示,AuNRs/GO複合物於D-SERS上之訊號增強效果最好,對於染料分子Rhodamine 6G(R6G)的增強因子(Enhancement Factor, EF)為1.1×108,偵測極限為10-9M,因此,AuNRs/GO複合物作為SERS的分子感測元件上擁有極高的靈敏度,非常適合在水質及環境中的單分子進行快速檢測。
In this study, Gold nanorods (AuNRs) with different aspect ratios were prepared by seed-mediated growth method combined with different dimensions of nanocarbon materials (graphene oxide, carbon nanotubes, carbon black) for surface-enhanced Raman scattering (SERS). The principle of nanodispersion is to stabilize AuNRs with cetyltrimethylammonium bromide (CTAB), and the surface of AuNRs is positively charged, which will adsorb on negatively charged nanocarbon materials to form AuNRs/nanocarbon materials due to electrostatic attraction. This nano-mixed material has good optical penetration and can improve the contact area with the detector. It can be used as a high-sensitivity surface-enhanced Raman scattering substrate. We compared the signal differences between AuNRs and nanocarbon materials of different dimensions on SERS. The experimental results can be confirmed by Ultraviolet-visible spectroscopy (UV-Vis) and Transmission Electron Microscope (TEM) to confirm the stable and uniform adsorption of AuNRs on nanocarbon materials. The results on SERS show the AuNRs/GO complex has the best enhancement signal. Since GO is a two-dimensional nanomaterial with a thickness of less than 5 nm, the AuNRs adsorbed on GO can produce a good 3D hot junction effect. In the SERS test, the enhancement factor (EF) for the dye molecule Rhodamine 6G (R6G) is 1×107, and the limit of detection is 10-8M, which achieves a good enhancement effect. Further used on D-SERS, since D-SERS is a process for detecting samples from wet to dry, a large number of 3D hot spots are spontaneously formed during the evaporation of the solvent, thereby greatly improving the SERS signal. The experimental results show that the AuNRs/GO complex has the best signal enhancement effect on D-SERS. The enhancement factor (EF) for the dye molecule Rhodamine 6G (R6G) is 1.1×108, and the detection limit is 10-9M. Therefore, the AuNRs/GO complex acts as SERS's molecular sensing components are extremely sensitive and are ideal for rapid detection of single molecules in water and the environment.
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