金屬玻璃具有優異的機械性質，各方面之應用深具潛力，然國內對金屬玻璃之基礎研究卻十分的欠缺，主要集中在多元金屬玻璃合金之機械性質探討等應用面，特別在金屬玻璃區域判定，更是乏人問津。本研究以熱力學計算方式(CALPHAD)，將相圖之計算原理應用在金屬玻璃形成區域之預測，首先建構該系統正確合理之熱力學資料庫，確認該熱力學資料庫符合實驗數據等各種物理性質(如相平衡圖、生成焓或活度等)，再利用metastable相圖概念預測金屬玻璃形成區域。因Cu基合金成本較低且Cu基與Zr基皆具有不錯的玻璃形成能力與寬廣之過冷液相區，對於工業應用具有利用價值，因此本研究探討Ag-Al-Cu-Zr四元合金系統及其所屬三元系統之金屬玻璃形成區，盼對學術界有所貢獻，再者，透過熱力學參數計算，預測出可能形成金屬玻璃之合金組成成分，再依據此組成成分進行合金配製及實驗確認，而不必配製整個系統之所有組成，可以大大節省人力物力，縮短該系統之金屬玻璃研究，對於工業界之應用也是一大利基。

Bulk metallic glasses (BMGs) have excellent potentials for various applications due to their excellent mechanical properties. But the fundamental investigations of metallic glasses are scarce in Taiwan, most of which are focusing on mechanical tests. The determination of metallic glass formation region was not studied ever. Therefore, the main purpose of this study focuses on the prediction of formation of metallic glasses by means of thermodynamic calculation, which is commonly used in the CALPHAD field. First of all, it is necessary to establish a reasonably correct thermodynamic dataset, which is consistant with experimental reusutls, such as phase equilibria, enthalpy of formation or activities of liquid or solid. Then the related metastable phase diagrams of binary or ternary systems could be introduced and drawn to predict formation of metallic glasses regions. The Cu-based alloys are inexpersive, and Zr- and Cu-based alloys have promising ability to form amorphous metallic glasses due to their wide range of the supercooled liquid region. Those alloys are favorable for application in industries. In this study, the Ag-Al-Cu-Zr quaternary and subternary systems are investigated thermodynamically to determine the formation of metallic glasses regions. Furthermore, once formation compositions of metallic glasses were predicted correctly, only few alloy samples were needed to be verified experimentally. Thus the expense and time of metallic glasses research woul be largly eliminated. Also the application of metallic glasses would be promoted and accepted in industries.

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